Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Energetic Particles Observed in the CUSP Region During a Storm Recovery Phase

In this paper we report energetic ion behavior and its composition variations observed by the Cluster/RAPID instrument when the spacecraft was travelling in the high latitude magnetospheric boundary region on the day of the 31 March, 2001, strongest magnetic storm in the past 50 years. The Dst index reached −360 nT at about 09:00 UT. During its early recovery phase, large amounts of oxygen and helium ions were observed; the ratio of oxygen to hydrogen in the RAPID energy range reached as high as 250%, which suggests that the observed energetic particles might be of magnetospheric origin. The observations further show that enhanced energetic electron fluxes are confined in a very narrow region, while protons have occupied a larger region, and heavy ions have been observed in an even larger region. The flux of energetic electrons show a slight enhancement in a region where the magnetic field magnitude is around zero. These observed energetic ions could be quasi-trapped by the current sheet in the stagnation region of the cusp.     

Assessment of the Geochemical Background and Anthropogenic Load by Bioaccumulation of Microelements in Fish

Comparative characteristic of several microelements (Ni, Cu, Sr, Al, Zn, Co, Mn, Pb, Cd, Hg, As) found in fish (case study of breams in the Volga basin reservoirs) is presented. Regularities of accumulation of these elements in fish depending on their concentration in the water are analyzed. Main disturbances in fish caused by the accumulation of microelements in their organs and tissues are considered.