大兴安岭中段塔尔气地区流纹岩年龄、地球化学特征及其地质意义

塔尔气地区位于大兴安岭主脊中段,晚中生代广泛发育一套玄武岩、安山岩、英安岩、流纹岩及相应火山碎屑岩的岩石组合。以流纹岩为研究对象,进行了LA-ICP-MS锆石U-Pb年龄、岩石地球化学研究。测年结果显示,流纹岩形成于132±2Ma(MSWD=1.5,2σ),属早白垩世中期。岩石地球化学特征表明,流纹岩属于典型的弱过铝质高钾钙碱系列岩石,具有高硅(71.6%~77%)、富碱(Na2O+K2O=7.94%~9.64%)且富钾(K2O=4.5%~5.46%)的特征;轻、重稀土元素分馏明显,具中等Eu负异常(δEu=0.22~0.7),亏损高场强元素Nb、Ta、P、Ti,相对富Th、U、Zr、Hf,富集大离子亲石元素K、Rb,相对贫Ba、Sr,显示A型流纹岩特征。岩浆源区与硬质砂岩相似,具有较高的锆饱和温度,可能为地壳部分熔融的产物,形成于后碰撞伸展的大地构造环境。     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

泥石流排导结构耦合磨损随机过程建模及分析

泥石流排导结构对于减轻泥石流对周围建筑物的损毁起到了显著作用,但目前大多数排导结构难以抵御泥石流的强烈侵蚀磨损和周围环境恶劣时伴随产生的腐蚀磨损。首先,通过分析泥石流排导结构侵蚀和腐蚀磨损机理,应用相关磨损量计算公式,提出了考虑侵蚀和腐蚀的泥石流排导结构耦合磨损计算公式。然后,以此为基础,针对磨损过程的动态性和随机性,建立了泥石流排导结构耦合磨损随机过程模型,推导了任意时刻磨损量的分布函数,实现了评估泥石流排导结构的动态可靠性和概率失效时间。最后,通过具体算例分析验证了模型的实用性,可为今后泥石流排导结构的磨损定量评估提供理论参考。     

海岛型城市水资源利用及其承载力对比研究

以新加坡、香港、厦门、舟山为例,根据国民经济和社会发展指标、用水总量及用水量构成、产业用水量、人口经济规模与水资源承载力等相关数据和指标,对水资源利用管理进行分析和对比,对远期水资源利用及其对经济发展的承载力进行预测;分析了海岛型城市与内陆型城市水资源利用的差异,对舟山群岛新区的水资源利用及承栽力所面临的挑战提出了相应的对策和建议。     

有色示踪剂模拟槽实验图像分析法

图像分析法是处理有色示踪剂模拟槽实验结果的常用方法之一。本文以食用亮蓝为示踪剂,从污染物的检测精度和污染羽描绘的准确度两个方面将图像分析法与传统取样法进行对比,并利用Matlab编程对模拟槽内的污染物贮存质量进行定量计算。结果表明,与传统取样法结果相比：图像分析法的检测精度可提高1个数量级;污染羽的描绘准确度至少可提高3%左右,在实验所设置的非均质条件下可提高17%左右。利用自行编制的Matlab程序对本实验模拟槽内贮存亮蓝质量进行计算可得,当剖分格数为3 700²（1 369万）时,亮蓝贮存质量的计算值最接近实测值,最小误差仅为0.5%。综合来讲,图像分析法是一种准确度高、空间分辨率高的信息采集和处理手段,可实现对非均质地层中有色示踪剂运移过程更为精细的描述。     

江西省小龙钨矿深部地球化学找矿远景预测

运用岩石地球化学找矿方法预测了小龙钨矿区深部Ｃｕ、Ａｇ、Ｗ矿化富集规律及其找矿远景。认为矿区南涪７、１１勘探线八中段以下存在Ｃｕ、Ａｇ、Ｗ矿体可能;北部０勘探线六中段Ｃｕ、Ａｇ晕已收敛,深部存在Ｃｕ、Ａｇ矿体可能性不大,而Ｗ的强度和规模在八中段以下呈显著增大趋势,深部可能存在Ｗ矿体,为矿区深部部署坑道工程提供了准确的地球化学依据。     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

渤海湾巨葛庄贝壳堤与下伏泥层有孔虫组合的海面变化意义

根据巨葛庄贝壳堤及下伏泥层的有孔虫研究,讨论了贝壳堤底板和下伏泥层各类沉积环境的海面意义,以此作为海面标志点重建的古海面误差范围为±0.225~±0.625m。结合该贝壳堤底板和下伏泥层顶板的年龄数据,重建了3900~3300cal BP时的海面高度为-2.955~-2.715m。     

鄂尔多斯早古生代古构造

用野外露头剖面、钻井剖面和地震剖面相结合的综合研究方法,首先用人工合成记录结合11口井的VSP资料,对鄂尔多斯下古生界进行层位标定。在此基础上,对鄂尔多斯全区下古生界371条共长15 683 km的地震剖面进行了重新处理和地层解释,这大大提高了解释精度。以此为基础,把鄂尔多斯下古生界划分为5个地层单位,即寒武系中下部、寒武系中上部及冶里组和亮甲山组、马家沟群下部、马家沟群上部、平凉组和背锅山组,并作出了它们的等厚图。从这些等厚图可以看出：前4个地质时期的古构造格局为“一隆三凹”,即西缘凹陷、南缘凹陷和东缘凹陷(或东部凹陷)呈“U”形从西南东三面包围着一个中部隆起。最后一个地质时期的古构造格局为“一隆二凹”,即西缘凹陷和南缘凹陷呈“L”形镶嵌在一个巨大的鄂尔多斯隆起的西缘和南缘。到奥陶纪末,鄂尔多斯全区以及整个华北地台均变为隆起区,从而结束了鄂尔多斯隆起和凹陷并存的历史。     

冀北麻粒岩系变质峰期水活度、氧逸度及其化学位变化--以太平寨-娄子山地区为例

脱水反应的热力学计算确定本区太古宙麻粒岩系变质峰期水活度很低,太平寨地区富铝片麻岩和紫苏黑云片麻岩麻粒岩中aH 2O值一般均在0.10～0.20之间,娄子山地区相对稍高,一般为0.15～0.25.全区峰期氧逸度lgfO2在-8～-14之间.(μH2O/XBt Mg)和(μO2/XBtMg)系数平均值太平寨地区分别为- 0.293和-1.60,娄子山地区分别为-0.364和-1.42.全区aH2O很低,同一地区上述各种数值相当均匀,不同地区则有一定差异,这些特征与"碳质变质"机理相符,说明峰期水活度可能受深源CO2流渗透的控制,属于外部缓冲性质.