Empirical ocean-color algorithms to retrieve chlorophyll-a, total suspended matter, and colored dissolved organic matter absorption coefficient in the Yellow and East China Seas

A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag₄₄₀). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for T_Chl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (T_Chl2i in case-2 waters), T_TSM (regionally tuned Tassan??s TSM algorithm), and T_ag440 or C_ag440 (regionally tuned Tassan??s or Carder??s ag₄₄₀ algorithm) were able to retrieve Chl-a, TSM, and ag₄₄₀ with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, T_Chl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. T_Chl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified T_Chl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw₅₅₅) > 2 mW cm^?2 ??m^?1 sr^?1 (T_Chl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from T_Chl2s (for case-2 waters) to MOC_Chl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag₄₄₀ using SeaWiFS Rrs, we recommend empirical algorithms for T_TSM (pre-SeaWiFS-modified form) and MT_ag440 or MC_ag440 (SeaWiFS Rrs-modified forms of T_ag440 or C_ag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.     

Diets of Steller sea lions off the coast of Hokkaido,Japan: An inter‐decadal and geographic comparison

Inter‐decadal and geographic variations in the diets of Steller sea lion, Eumetopias jubatus, were examined based on the contents of 408 stomachs collected from coastal areas around Hokkaido Island during the periods 1994–1998 and 2005–2012. The most important prey species in the 1990s were gadid fishes (walleye pollock [Gadus chalcogrammus], Pacific cod [Gadus microcephalus] and saffron cod [Eleginus gracilis]). The frequency of occurrence and gravimetric contribution of gadids decreased in the 2000s latter period at three study sites (Rausu, Shakotan and Rebun) and were replaced by Okhotsk Atka mackerel (Pleurogrammus azonus) and smooth lumpsucker (Aptocyclus ventricosus). However, analysis based on gravimetric composition indicated that the dietary diversity of prey showed only a slight inter‐decadal difference, reflecting the wide diversity of prey ingested during both study periods. These results indicate that Steller sea lions along the Hokkaido coast are opportunistic feeders that utilize a wide variety of prey, and appear to feed mainly upon prey that is easily obtained.     

Ocean Color Satellite Imagery and Shipboard Measurements of Chlorophyll a and Suspended Particulate Matter Distribution in the East China Sea

Satellite-derived ocean color data of Coastal Zone Color Scanner (CZCS) on board the Nimbus-7 and Ocean Color and Temperature Scanner (OCTS) on board the Advanced Earth Observing Satellite (ADEOS) are jointly used with historical in situ data to examine seasonal and spatial distributions of chlorophyll a (Chl-a) and suspended particulate matter (SPM) concentrations in the East China Sea. Ocean color imagery showed that Chl-a concentrations on the continental shelf were higher than those of the Kuroshio area throughout the year. Satellite-derived Chl-a concentrations are generally in good accordance with historical in situ values during spring through autumn (although no shipboard in situ measurement was conducted at nearshore areas). In contrast, ocean color imagery in winter indicated high Chl-a concentrations (4–10 mg m^–3) on the continental shelf where bottom depth was less than 50 m when surface water was turbid (2–72 g m^–3 of SPM at surface), while historical in situ values were usually less than 1 mg m^–3. This suggests that resuspended bottom sediment due to wind-driven mixing and winter cooling is responsible for the noticeable overestimation of satellite-derived Chl-a concentrations. The algorithm for ocean color needs to be improved urgently for turbid water.     

Dynamics of pelagic variables in two contrasting coastal systems in the western Hokkaido coast off Otaru port,Japan

Human impact on adjacent coastal waters, leading to alteration in nutritional environment and hence affecting phytoplankton biomass (Chlorophyll a), will probably be enhanced by the nearby presence of ports. The main goal of this study is to assess the influence of nearby presence of port on phytoplankton biomass build-up and the physical–chemical environmental characteristics in two contrasting coastal systems (Otaru port, S-IN and an exposed coastal area, S-OUT) in the western Hokkaido coast off Otaru port, Japan. Sampling was conducted on “bi-weekly and monthly” basis during the period of September 2006–December 2007 and data comprising 11 pelagic variables were obtained. In most instance, phytoplankton biomass, nutrients' (NH₄, NO₃, PO₄, and Si(OH)₄) concentrations and nutrients' molar ratios were higher at the Otaru port location. Physical parameters (temperature, salinity, hydrogen ion concentration (pH), photosynthetically active radiation (PAR) and dissolved oxygen, (DO)) were not significantly different (P > 0.05) between the two locations. With the exception of salinity, pH and DIC, all variables measured showed significant variation (P < 0.05) with season. While the coefficient of variation (CV) of physical parameters and phytoplankton biomass were relatively higher in Otaru port location (S-IN), the exposed coastal location (S-OUT) showed a higher variation in chemical parameters. Other variables showed different patterns between the two locations. We conclude that ports, due to its activities and restricted circulation favour high nutrient loading and phytoplankton biomass build-up in adjacent coastal systems, thus, suggesting the need for continuous field observation data in order to advance our knowledge on possible future human impact on coastal environment and the need to monitor and control port activities.     

Lower Cd/P ratio in settling particles than in surface seawater in the Okinawa Trough

The characteristics of the ratios between cadmium (Cd) and phosphorus (P) in settling particles collected from the Okinawa Trough in the East China Sea were examined using a sediment trap, moored at a depth of 811 m for one year. The Cd/P ratios varied within a narrow range throughout the year, in spite of the large seasonal change in the total dry mass, Cd, and P fluxes. The average Cd/P ratio of settling particles was 0.062 (nmol/μmol), which was obviously lower than that of surface seawater around the study site (0.16). This lower ratio in the Okinawa Trough particles collected using the 811 m-moored trap certainly reflected the mixture of biologically produced organic matter around the study site and other components that were mainly transported as lateral flux from the shelf edge and slope area of the East China Sea.     

Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Influences of the snow cover on landslide displacement in winter period: a case study in a heavy snowfall area of Japan

The displacement of a relatively small reactivated landslide in a snowy area in Japan was monitored over a long period. The displacement rate of the landslide, which was approximately of 20 mm d^?1 before the formation of snow cover, decelerated drastically during the continuous snow cover period every winter period. Possible causes included reduction in the amount of water that reached the ground surface (MR: meltwater and/or rainwater) and increase in snow load. Given that the actual displacement of the landslide was far below the predicted value based on the relationship between landslide displacement and MR immediately before the continuous snow cover period, the deceleration of landslide displacement was more likely attributable to the increase in snow load than to the reduction in MR. An investigation of the link between snow load and landslide displacement showed a negative logarithmic relationship. A dynamic analysis based on the limit equilibrium method showed that snow load increases the effective normal stress and the stability of a landslide in which the mean inclination angle of the slip surface is smaller than the internal friction angle. The stability of the actual slope was also analyzed by conducting soil tests on samples collected at the site and using the resultant parameters. The analysis also showed that the increase in snow load increases the safety factor and reduces the landslide displacement. The displacement of a relatively small landslide that has a shallow slip surface was found to be greatly influenced by snow cover.     

第三部分海陆对比300000年以来的海平面变化

对于海岸演化,海平面变化是最重要的控制因素之一。300000年以来海平面历史的建立,对于理解中、晚第四纪年代学,海岸演化对现代海岸特征的影响和测量沿海地区第四纪新构造运动都是特别重要的。这个专题讨论会的目的就是根据新发展的测年手段和具有不同构造特征的各种沿海地带地貌和地质的调查,建立海平面波动的年代和幅度以     

Concentrations of 137Cs, 90Sr, 108m Ag, 239+240 Pu and atom ratio of 240Pu/239Pu in tanner crabs, Chionoecetes japonicus and Chionoecetes opilio collected around Japan

The anthropogenic radionuclides, ¹³⁷Cs, ⁹⁰Sr, ^108mAg, ^239+240Pu, were measured in two Chionoecetes species, red queen crab (Chionoecetes japonicus) and snow crab (Chionoecetes opilio) collected around Japan during 1996–2007. There was no increase in the concentrations of these radionuclides and no large variation of the atom ratio of ²⁴⁰Pu/²³⁹Pu during this research period. These results indicated that the source of the radionuclides was not the radioactive wastes dumped by the former USSR and Russia and originated from past nuclear weapon tests. The higher atom ratio in the crab species than that from global fallout would be contributed by the Pacific Proving Grounds close-in fallout. The variability of the concentration of radionuclides in the crab species would result from the variability of the composition and quantity in the diet. However, the decrease in the concentration of radionuclides with sampling depth would depend on the concentration in the seawater and diet.