Geological development of Jabal al Akhdar,Libya

The northern Cyrenaic headland situated north of 32 degrees latitude between Benghází and Tubruq was subject of a geological mapping. This paper draws attention to the results of this geological survey concerning Upper Cretaceous and Tertiary facies development, paleogeography, tectonic and geomorphologic evolution.The essential part of the investigated area corresponds to Jabal al Akhdar (Green Mountains), a gently uparched plateau built of Upper Cretaceous and Tertiary sediments (mostly limestones, subordinate dolomites and marls). These sediments were deposited at the southern margin of the Tethys sea and were moderately folded, mainly during the intra-Senonian (pre-Campanian) and early Ypresian intervals.From Middle Eocene till Middle Miocene, the area was subject to a slight warping followed by oscillating transgressions of a shallow sea.The youngest tectonic movements resulted in a gentle doming of the area associated with downfaulting of certain zones. Some prominent faults revealed rejuvenated activity, partly with movement inversion. Deep faulting probably controlled the paleogeographic and tectonic development of certain zones.The present gross geomorphology of Jabal al Akhdar roughly corresponds to its final uparching dated after the Middle Miocene. Topographic evolution of the northern slope of the mountains has been importantly influenced by marine erosion. Two broad littoral terraces bordered by cliffs were formed successively.

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Zusammenfassung Die nördliche Cyrenaica nördlich des 32. Breitengrades, zwischen Benghazi und Tobruk, wurde geologisch kartiert. Ergebnisse dieser Aufnahmen sind unten wiedergegeben und umfassen die fazielle Entwicklung der Oberkreide und des Tertiär sowie die paläogeographische, tektonische und geomorphologische Entwicklung.Der wesentliche Teil des untersuchten Gebietes liegt im Djebel el Akhdar. Er repräsentiert ein herausgehobenes Plateau, das sich aus Oberkreide und Tertiärsedimenten (meistens Kalke, untergeordnet Dolomite und Mergel) zusammensetzt. Diese Sedimente wurden am Südrand der Tethys abgelagert und sind vorwiegend während des Senon (Prä-Campan) und frühen Ypresien schwach verfaltet worden.Vom mittleren Eozän bis ins mittlere Miozän wurde das Gebiet teilweise gehoben und von oszillierenden Transgressionen einer Flachsee erfaßt.Die jüngsten tektonischen Bewegungen führten zu einer domartigen Aufwölbung und zu Bruchtektonik entlang bestimmter Zonen. Dabei wurden markante Störungen mehrfach regeneriert, wobei auch inverse Bewegungen nachgewiesen werden konnten. Tiefgreifende Lineamente kontrollierten wahrscheinlich die paläogeographische Situation wie auch die tektonische Entwicklung entlang bestimmter Zonen.Die augenblickliche geomorphologische Ausgestaltung des Djebel el Akhdar korrespondiert mit der zuletzt stattgefundenen Aufwölbung nach dem mittleren Miozän. Die topographische Entwicklung seines nördlichen Randes ist weitgehend beeinflußt durch marine Erosionen. Zwei breite Küstenterrassen — durch Steilküsten begrenzt — haben sich dabei sukzessive herausgebildet.

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Résumé La Cyrénaique septentrionale au Nord du 32ème parallèle, entre Benghazi et Tobrouk, a été l'objet d'un lever géologique. Les résultats donnés ici concernent le développement des facies au Crétacé supérieur et au Tertiaire, ainsi que l'évolution paléogéographique, tectonique et géomorphologique.La plus grande partie du territoire se trouve dans le Djebel el Akhdar, plateau soulevé composé de sédiments du Crétacé supérieur et du Tertiaire (la plupart des calcaires, plus rarement des dolomites et des marnes). Ces sédiments se sont déposés dans la bordure meridionale de la Téthys et furent faiblement plissés principalement au cours du Sénonien (Précampanien) et au début de l'Yprésien.De l'Eocène moyen au Miocène moyen, cette région fut en partie soulevée et soumise à des transgressions oscillatives de mer peu profonde.Les mouvements tectoniques les plus récents ont eu pour conséquence un faible bombement de la région accompagné d'affaissements de certaines zones le long de failles. Certaines failles importantes ont rejoué plusieurs fois, partiellement avec inversion de mouvement. Des failles profondes ont influencé l'évolution paléogéographique et tectonique de certaines zones.La géomorphologie générale actuelle du Djebel el Akhdar correspond grosso-modo a son bombement final d'après le Miocène moyen. L'évolution topographique du versant septentrional de la chaîne a été influencée d'une façon importante par des érosions marines. Il s'est formé successivement deux terraces littorales bordées de falaises.

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Isotopic U-Pb ages of monazites and zircons from the crust-mantle transition and adjacent units of the ivrea and ceneri zones (Southern Alps,Italy)

The Ivrea zone forms a part of the Southern Alps and is composed of basic rocks interfingered with granulite facies acidic rocks. According to geophysical evidence, this zone represents the transition between crust and uplifted and overthrusted mantle. Towards the Ceneri zone the metamorphic grade changes to amphibolite facies. Paragneisses, migmatites and anatectic gneisses dominate, within which postmetamorphic granites occur. Concordant monazite U-Pb ages of 275+2 m.y. were obtained from paragneisses of the Ivrea zone. The apparent zircon ages are discordant indicating a minimum age of 1900 m.y. for the oldest population and an apparent lead loss of 99 to 85 % about 285–300 m.y. ago. The zircons show features such as rounded habitus, low trace element contents and well ordered crystal lattices characteristic for detrital, recrystallised populations. Monazite from the neighbouring Ceneri zone migmatite yielded concordant U-Pb ages at 295±5 m.y. The discordant zircon age pattern indicates a time of formation of 450 m.y., similar to other newly formed zircons in anatectic rocks of the Ceneri zone, and an episodic or continuous lead loss at, or until 300 m.y. ago. The majority of the zircons are euhedral and have elevated trace element contents, features typical for zircons formed in the present-day host rocks. Concordant, 295±5 m.y. old monazite dates the formation of the postmetamorphic Mont' Orfano granite. Again zircon fractions yielded discordant ages, pointing in contrast to the above discordancies to a recent or continuous lead loss. The concordant ages of the monazites demonstrate the usefulness of this mineral for dating purposes in metamorphic and granitic rocks and contrast with the discordant age patterns of all zircon suites. From the general agreement between the monazite ages and the time of lead loss inferred from the zircon age patterns as well as from the geological relationships of the rocks and their metamorphic grade it is concluded that 295±5 m.y. is the minimum age for the regional granulite to upper amphibolite facies metamorphism of the Ivrea zone and that the uplift and overthrust of the upper mantle started prior to 295 m.y. ago, and that the basic rocks of the Ivrea zone are synmetamorphic intrusions. The decrease from 310–320 m.y. to 170–200 m.y. of the K-Ar and Rb-Sr mineral ages from the Ceneri towards the Ivrea zone is accompanied by decreases from 450 m.y. to 295 m.y. and on to 275 m.y. in the U-Pb ages of monazites. The zircon age pattern also shows a decrease from 450 m.y. to approximately 300 m.y. The main lowering of the ages occurs approximately at the petrographic boundary between the two zones and is related to the Hercynian uplift and overthrust of the mantle which may have started as early as 450 m.y. ago. The Insubric line which terminates the Ivrea zone towards the North must therefore be of pre-Alpine age, or a precursor of the Insubric line must have existed at the time of the mantle uplift.     

Noble gas investigations of lunar rocks 10017 and 10071

The noble gases He, Ne, Ar, Kr and Xe and also K and Ba were measured in the Apollo 11 igneous rocks 10017 and 10071, and in an ilmenite and two feldspar concentrates separated from rock 10071. Whole rock K/Ar ages of rocks 10017 and 10071 are (2350 ± 60) × 10⁶ yr and (2880 ± 60) × 10⁶ yr, respectively. The two feldspar concentrates of rock 10071 have distinctly higher ages: (3260 ± 60) × 10⁶ yr and (3350 ± 70) × 10⁶ yr. These ages are still 10 per cent lower than the Rb/Sr age obtained by Papanastassiouet al. (1970) and some Ar⁴⁰ diffusion loss must have occurred even in the relatively coarse-grained feldspar.The relative abundance patterns of spallation Ne, Ar, Kr and Xe are in agreement with the ratios predicted from meteoritic production rates. However, diffusion loss of spallation He³ is evident in the whole rock samples, and even more in the feldspar concentrates. The ilmenite shows little or no diffusion loss. The isotopic composition of spallation Kr and Xe is similar to the one observed in meteorites. Small, systematic differences in the spallation Kr spectra of rocks 10017 and 10071 are due to variations in the irradiation hardness (shielding). The Kr spallation spectra in the mineral concentrates are different from the whole rock spectra and also show individual variations, reflecting the differences in target element composition. The relative abundance of cosmic ray produced Xe¹³¹ differs by nearly 50 per cent in the two rocks. The other Xe isotopes show no variations of similar magnitude. The origin of the Xe¹³¹ yield variability is discussed.Kr⁸¹ was measured in all the samples investigated. The Kr⁸¹/Kr exposure ages of rocks 10017 and 10071 are (480 ± 25) × 10⁶ yr and (350 ± 15) × 10⁶ yr, respectively. Exposure ages derived from spallation Ne²¹, Ar³⁸, Kr⁸³ and Xe¹²⁶ are essentially in agreement with the Kr⁸¹/Kr ages. The age of rock 10071 might be somewhat low because of a possible recent exposure of our sample to solar flare particles.     

The journal Communications in Numerical Methods in Engineering with Biomedical Applications becomes the International Journal for Numerical Methods in Biomedical Engineering (IJNMBE) from 1st January 2010

Communications in Numerical Methods in Engineering, founded by Roland W. Lewis in 1985, will change its title to the ‘International Journal for Numerical Methods in Biomedical Engineering’ and has a revised Aims and Scope. Copyright © 2009 John Wiley & Sons, Ltd.     

Barents Sea upstream events impact the properties of Atlantic water inflow into the Arctic Ocean: Evidence from 2005 to 2006 downstream observations

Inflow of Atlantic water (AW) from Fram Strait and the Barents Sea into the Arctic Ocean conditions the intermediate (100–1000 m) waters of the Arctic Ocean Eurasian margins. While over the Siberian margin the Fram Strait AW branch (FSBW) has exhibited continuous dramatic warming beginning in 2004, the tendency of the Barents Sea AW branch (BSBW) has remained poorly known. Here we document the contrary cooling tendency of the BSBW through the analysis of observational data collected from the icebreaker Kapitan Dranitsyn over the continental slope of the Eurasian Basin in 2005 and 2006. The CTD data from the R.V. Polarstern cruise in 1995 were used as a reference point for evaluating external atmospheric and sea-ice forcing and oxygen isotope analysis. Our data show that in 2006 the BSBW core was saltier (by ～0.037), cooler (by ～0.41 °C), denser (by ～0.04 kg/m³), deeper (by 150–200 m), and relatively better ventilated (by 7–8 μmol/kg of dissolved oxygen, or by 1.1–1.7% of saturation) compared with 2005. We hypothesize that the shift of the meridional wind from off-shore to on-shore direction during the BSBW translation through the Barents and northern Kara seas results in longer surface residence time for the BSBW sampled in 2006 compared with samples from 2005. The cooler, more saline, and better-ventilated BSBW sampled in 2006 may result from longer upstream translation through the Barents and northern Kara seas where the BSBW was modified by sea-ice formation and interaction with atmosphere. The data for stable oxygen isotopes from 1995 and 2006 reveals amplified brine modification of the BSBW core sampled downstream in 2006, which supports the assumption of an increased upstream residence time as indicated by wind patterns and dissolved oxygen values.     

Formal subdivision of the Holocene Series/Epoch: a Discussion Paper by a Working Group of INTIMATE (Integration of ice‐core,marine and terrestrial records) and the Subcommission on Quaternary Stratigraphy (International Commission on Stratigraphy)

This discussion paper, by a Working Group of INTIMATE (Integration of ice‐core, marine and terrestrial records) and the Subcommision on Quaternary Stratigraphy (SQS) of the International Commission on Stratigraphy (ICS), considers the prospects for a formal subdivision of the Holocene Series/Epoch. Although previous attempts to subdivide the Holocene have proved inconclusive, recent developments in Quaternary stratigraphy, notably the definition of the Pleistocene–Holocene boundary and the emergence of formal subdivisions of the Pleistocene Series/Epoch, mean that it may be timely to revisit this matter. The Quaternary literature reveals a widespread but variable informal usage of a tripartite division of the Holocene (‘early’, ‘middle’ or ‘mid’, and ‘late’), and we argue that this de facto subdivision should now be formalized to ensure consistency in stratigraphic terminology. We propose an Early–Middle Holocene Boundary at 8200 a BP and a Middle–Late Holocene Boundary at 4200 a BP, each of which is linked to a Global Stratotype Section and Point (GSSP). Should the proposal find a broad measure of support from the Quaternary community, a submission will be made to the International Union of Geological Sciences (IUGS), via the SQS and the ICS, for formal ratification of this subdivision of the Holocene Series/Epoch. Copyright © 2012 John Wiley & Sons, Ltd.     

Quality control and homogeneity of Turkish precipitation data

Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.     

Determination of the orientation of 29Si chemical shift tensors using rotorsynchronized MAS NMR of single crystals: forsterite (Mg2SiO4)

A novel approach is presented to determine both the main axis values and the orientation of ²⁹Si chemical shift tensors using slow rotation of single crystals at the magic angle (MAS). Provided that the MAS frequency is less than the chemical shift anisotropy and that the radiofrequency (r.f.) pulse excitation is rotorsynchronized the single crystal MAS spectra consist of a mixture of absorptive and dispersive line shape contributions to each MAS sideband. Changing systematically the timing of the r.f. excitation with respect to the rotor position a set of spectra is obtained which allows a precise determination of the chemical shift tensors and their orientations with respect to the crystal axis system despite MAS. This method offers both large resolution enhancement and a considerable time saving, in comparison to the traditional determination of chemical shift tensors, where the angular dependence of the resonance frequency at three orthogonal crystal orientations is measured. Both methods are compared using forsterite as test sample.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.