Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer     

The lower marine to lower freshwater Molasse transition in the northern Alpine foreland basin (Oligocene; central Switzerland–south Germany): age and geodynamic implications

The Wilhelmine Alpe section near Immenstadt (Allgäu, south Germany), which represents one of the best continuously exposed outcrops within the northern Alpine foreland basin, has been analyzed for magnetostratigraphic and palynostratigraphic signals. The section comprises the marine-to-terrestrial transition from Lower Marine (UMM) to Lower Freshwater Molasse (USM) sediments. Based on the correlation of the local magnetic pattern with the geomagnetic polarity timescale (GPTS) and palynostratigraphic data, an age of about 31 Ma is suggested for the UMM–USM transition in the Wilhelmine Alpe section. A comparison with coeval magnetostratigraphic sections from central and eastern Switzerland indicates that the regression of the UMM sea along the southern margin of the Molasse basin occurred strongly heterochronously between 31.5 and 30 Ma. The heterochroneity is attributed to the deposition of fan-delta and alluvial fan sediments which document that the overall marine conditions during the UMM were accompanied by strong clastic input derived from the rising Alps. This clastic contribution had a much stronger influence on the depositional pattern than previously thought.     

Lippmann Diagrams: Theory and Application to Carbonate Systems

Since 1980 when F. Lippmann's seminal paper appeared, ourunderstanding of solubility equilibria involving ionic solidsolutions has been advanced by theoretical considerations as wellas careful experimental studies designed to determine excess Gibbsfunctions. A unified theory of solid-solution aqueous-solutionequilibria as well as the thermodynamic background of thephenomenon of ``stoichiometric saturation' are reviewed.It is shown that Lippmann diagrams effectively summarize thethermodynamic basis of solid-solute aqueous-solution equilibria ofsparingly soluble metal carbonate systems. Clearly, the predictivepower of these diagrams may be limited due to kineticrestrictions. Only when dissolution and precipitation areessentially reversible, favourable conditions to synthesizehomogeneous solid phases can be derived from studies of equilibria.     

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Meeresoptische Messungen während schwerer Stürme auf der Forschungsplattform “Nordsee” vom 14. November bis zum 8. Dezember 1980

Ocean Dynamics - Meeresoptische Messungen auf der Forschungsplattform “Nordsee” haben gezeigt, daß dort während schwerer Stürme, hauptsächlich durch den Einfluß...     

A method to determine crystallization temperatures of hydrated crystals by intracrystalline oxygen isotope effects

The fractionation of the oxygen isotopes between water molecules from different sites in CuSO₄ · 5H₂O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed.     

First- and second-order adaptation to natural hazards and extreme events in the context of climate change

This paper deals with coping and adaptation processes to natural hazards and (potential) climate change impacts. Selected response measures to natural hazards are critically reviewed with respect to the actual and potential consequences that these measures might imply for additional adaptation needs and changes within social-ecological systems. In this context, the author introduces the concept of first- and second-order adaptation processes in order to underline the cascade process that adaptation implies, the potentials for failure, and the limits of adaptation. Important aspects of first- and second-order adaptation processes as well as the issue of the limits of adaptation are illustrated based on observations and empirical work conducted in Vietnam. In its final part, the paper discusses the findings in light of selected theoretical approaches that might help to understand how stabilization and destabilization processes are influenced or even triggered by adaptation measures.     

Landfill site selection and landfill liner design for Ankara, Turkey

Considering the high population growth rate of Ankara, it is inevitable that landfill(s) will be required in the area in the near future to sustain the sanitary waste disposal needs of the city. The main scope of this study is to select alternative landfill sites for Ankara based on the growing trends of Ankara toward the northwest, particularly toward the Sincan municipality, and to eventually select the best alternative through utilizing multi-criteria decision making. Landfill site selection was carried out utilizing Geographic Information System (GIS) and Multi-Criteria Decision Analysis. A number of criteria, namely, settlement, slope, proximity to roads, geology, availability and proximity of landfill containment material (i.e., clay for composite lining system), suitability for agriculture, erosion, vegetation cover and lineament system were gathered in a GIS environment. Each criterion was assigned a weight value by applying the Pairwise Comparison Method and the Analytical Hierarchy Method. In order to choose the best alternative, the Technique for Order Preference by Similarity to the Ideal Solution, which is regarded as an ideal point method, was applied and a landfill site was selected. The geotechnical properties of the so-called “Ankara clay” that shows widespread distribution in Ankara were reviewed and assessed for its suitability as a compacted clay liner.