平庄盆地六家立井地区找铀目标层岩石学特征及其找矿意义

六家立井地区位于平庄盆地北缘,白垩系下统阜新组上段是该区砂岩型铀矿床目标层位,具有较好找铀前景。为深入了解该区砂体的岩石学特征,通过野外钻探工作、岩心编录、样品采集及岩矿测试方法,详细研究了目标层碎屑岩类型、碎屑岩成分、结构构造等岩石学方面特征。结果表明目标层碎屑岩成分成熟度和结构成熟度均较低,具有搬运距离短、沉积速度快的特点,其物源较单一,初步判断物源来自盆地东北部和西北部隆起带酸性花岗岩,同时也为铀成矿提供了良好的铀源。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

鄂尔多斯盆地水文地质特征及地下水系统分析

鄂尔多斯盆地是我国西北地区东部的一个大型构造沉积盆地,蕴藏着丰富的矿产资源,是我国正在建设 的重要能源基地;鄂尔多斯盆地同时也是一个巨型地下水盆地,赋存相对丰富的地下水资源,将为能源基地建设提 供重要水源。鄂尔多斯盆地是由多种不同类型岩石上下叠置构成的构造沉积盆地,因此它也是一个由不同含水岩 类的多个含水层系统上下叠置构成的巨型地下水盆地。鄂尔多斯盆地总体上构成一个半开启型的地下水盆地,盆 地内不同含水层系统地下水交替循环的方式和深度不同,以寒武系-奥陶系碳酸盐岩类岩溶含水层系统和白垩系 碎屑岩类孔隙-裂隙含水层系统的交替循环深度较大(可达1200～1800m);新生界松散岩类孔隙含水层系统和 石炭系-侏罗系碎屑岩类裂隙含水层系统的交替循环深度较小(一般小于300m)。鄂尔多斯盆地实际上包含了周 边岩溶地下水、白垩系自流盆地地下水和东部黄土区地下水共3个地下水大系统。     

Past atmospheric trace metal deposition in a remote lake (Lake Ngoring) at the headwater areas of Yellow River,Tibetan Plateau

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Geochemical Information Indicating the Water Recharge to Lakes and Immovable Megadunes in the Badain Jaran Desert

1 Introduction The Badain Jaran Desert, located in western Inner Mongolia, China, has a unique landscape containing 144 lakes (72 of which are still watery) with a total water area of about 23 km2, and the world’s highest stationary sand dunes with a height between 200 m and 500 m. Much attention has been paid to the water recharge of the desert in the past decade. Investigations on the resources of water system there have been performed continuously since the early 1990s, which lead to th…     

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长春地区高回填土力学性质的研究

依据工程实例中桩顶位移数据,利用位移与内力之间的关系,采用"m"法,进行反分析研究.结果表明,支护桩桩顶理论位移为147.9 mm,与实际位移64 m差距较大,所以高回填土c,φ值所采用的经验值不精确.本文给出了长春地区回填土c,φ值的折减系数(分别为1.4和1.28).     

电子自旋共振(ESR)化石测年及其在晚新生代动物群年代学研究中的应用

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通过分析测定渤海湾100个站位表层沉积物中重金属元素的含量,探讨其分布特征及富集状况,并通过地累积指数法和潜在生态危害指数法对渤海湾西部岐口凹陷海域底质环境进行了评价。结果表明：渤海湾西部海域表层沉积物中As、Hg、Cu、Pb、Cd的平均含量分别为12．9×10－6、0．031×10－6、29．5×10－6、27．4×10－6、0．159×10－6。结合5种元素的地球化学图及地累积指数法分析表明,研究区表层沉积物整体上未受到As、Hg、Cu、Pb、Cd的污染,而在高值区Pb和Cu达到轻度污染的水平;潜在生态危害指数法的评价结果指明,重金属元素的潜在危害程度顺序是Hg＞Cd＞As＞Pb＞Cu,研究区重金属的潜在生态危害轻微,只有在高值区,Hg和Cd才达到中等程度的生态危害。     

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