钱家店铀矿床表生含氧含铀流体与深层酸性含烃流体的耦合成矿作用——来自岩心蚀变矿物填图的证据

以岩心光谱蚀变矿物填图为主要研究手段,结合野外地质编录、偏光显微镜、扫描电镜、电子探针能谱分析、氢氧同位素测试等方法,对开鲁盆地钱家店砂岩型铀矿床85个有效钻孔岩心开展了系统的蚀变矿物填图和矿物学研究。结果表明:①主要含矿层上白垩统姚家组蚀变矿物主要有黏土矿物(高岭石、蒙脱石、伊利石、伊/蒙混层及局部绿泥石)、铁的三价氧化物、黄铁矿、碳酸盐(方解石、白云石、铁白云石)等,它们呈现明显的分带特征:氧化带为高含量的"高岭石+Fe³⁺氧化物"组合、过渡带为中等含量的"高岭石+蒙脱石(伊/蒙混层)"+高含量的"黄铁矿+铁白云石"组合;还原带则主要为高含量的"蒙脱石(伊/蒙混层)+伊利石+黄铁矿"组合,矿体主要分布在氧化-还原过渡带和高岭石变化的梯度带上,并见有明显的高岭石、黄铁矿、铁白云石富集。②含氧含铀流体主要来自于WS、WN方向,其次为ES方向(也可能是WS向流体的分支),酸性含烃流体主要来自于NE向的断裂构造,流体温度介于40～120℃,两种不同性质流体的耦合作用是该地区的主成矿作用。③主成矿事件应发生在白兴吐"天窗"构造隆升之后,构造天窗在成矿系统中主要承担着还原...     

压裂微震数据初至拾取的时频谱熵法

在油气田开发过程中,微震监测是获得水力压裂引起裂缝分布的一种较为有效的方法。微震的定位成像与裂缝解释需要利用有效微震信号位置,而微震信号具有低信噪比的特点,传统信号拾取方法无法有效实现较低信噪比条件下初至时刻的准确拾取。本文提出一种基于时频谱熵的初至拾取新方法,该方法首先通过S变换获取含噪信号的时频谱;然后对谱内各个采样点沿频率方向进行分帧操作,并计算每帧频段内的近似负熵值,以最小近似负熵值作为该谱点的负熵值;最后沿时间方向比较各谱点的负熵值,最小值对应的时刻即为初至时刻。本文利用不同信噪比的合成地震数据对该方法进行效果验证,并与长短时窗能量比（STA/LTA）法进行拾取结果对比,结果表明：信噪比在-5 dB时,两种方法拾取效果都很好;信噪比在-10 dB时,时频谱熵法拾取效果更好。时频谱熵法更适合低信噪比情况下的信号初至拾取。     

Enhancement of backtracking search algorithm for identifying soil parameters

In this paper, an enhanced backtracking search algorithm (so-called MBSA-LS) for parameter identification is proposed with two modifications: (a) modifying the mutation of original backtracking search algorithm (BSA) considering the contribution of current best individual for accelerating convergence speed and (b) novelly incorporating an efficient differential evolution (DE) as local search for improving the quality of population. The proposed MBSA-LS is first validated with better performance than the original BSA and some other typical state-of-the-art optimization algorithms on a benchmark of soil parameter identification in terms of effectiveness, efficiency, and robustness. Then, the efficiency of the MBSA-LS is further illustrated by two representative cases: identifying soil parameters from both laboratory tests and field measurements. All comparisons demonstrate that the proposed MBSA-LS algorithm can give accurate results in a short time. Finally, to conveniently solve the problems of parameter identification, a practical tool ErosOpt for parameter identification is developed by integrating the proposed MBSA-LS and some other efficient algorithms for readers to conduct the parameter identification using optimisation algorithms.     

硫化物风化产酸对流域岩石风化和碳循环的影响——以黄河支流三川河流域为例

硫化物风化产酸可加速岩溶作用但抑制大气二氧化碳参与流域碳循环,其复杂的地球化学机制和过程待阐明。本文以黄河二级支流三川河流域为例,通过采集20个三川河及其支流地表水点样和30个柳林泉地下水点样,经实验测试获得了流域比较系统的水化学资料和δ¹³C、δ³⁴ S数据,运用碳、硫同位素分析与水化学平衡计量方法,量化了流域硫化物风化产酸对岩石风化作用的贡献以及对碳循环的影响。计算结果表明：煤系地层硫化物和矿床硫化物的氧化及大气酸沉降所形成的硫酸明显促进了流域碳酸盐岩的溶蚀,对碳酸盐岩溶蚀的贡献约占64.59%;柳林泉水石膏溶解来源的SO₄^2-占69%,河水中石膏溶解来源的SO₄^2-占30%,但这些部分SO₄^2-没有参与溶蚀作用,应当扣除;三川河流域平均岩石风化速率为10.02 mm/ka,其中碳酸盐岩、硅酸盐岩的风化速率分别为9.14 mm/ka和0.88 mm/ka,低于国内外很多流域;由于硫酸抵消了碳酸盐岩石风化作用对大气二氧化碳的吸收,流域岩石风化消耗大气/土壤CO₂通量为116.58 mmol/（km² ·a）,不足珠江流域的1/5,且硅酸盐岩风化的贡献占63.3%。

     

Geochemistry of rare-earth elements in shallow groundwater,northeastern Guangdong Province,China

Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+.     

Sensitivity analysis of groundwater level in Jinci Spring Basin (China) based on artificial neural network modeling

Jinci Spring in Shanxi, north China, is a major local water source. It dried up in April 1994 due to groundwater overexploitation. The groundwater system is complex, involving many nonlinear and uncertain factors. Artificial neural network (ANN) models are statistical techniques to study parameter nonlinear relationships of groundwater systems. However, ANN models offer little explanatory insight into the mechanisms of prediction models. Sensitivity analysis can overcome this shortcoming. In this study, a back-propagation neural network model was built based on the relationship between groundwater level and its sensitivity factors in Jinci Spring Basin; these sensitivity factors included precipitation, river seepage, mining drainage, groundwater withdrawals and lateral discharge to the associated Quaternary aquifer. All the sensitivity factors were analyzed with Garson’s algorithm based on the connection weights of the neural network model. The concept of “sensitivity range” was proposed to describe the value range of the input variables to which the output variables are most sensitive. The sensitivity ranges were analyzed by a local sensitivity approach. The results showed that coal mining drainage is the most sensitive anthropogenic factor, having a large effect on groundwater level of the Jinci Spring Basin.     

水热条件下黄铁矿片、板状晶体的微结构

利用透射电子显微镜(TEM)系统观测了黄铁矿片、板状晶体的微结构,发现在水热条件下生成的黄铁矿片、板状晶体具有正方形、矩形等多种形貌。其中,正方形较多,矩形次之,另可见到一些其他不规则形状。黄铁矿片、板状晶生长完好,未见缺陷。经测定多数四边形片状黄铁矿的两组边分别平行(010)和(100),其生长晶面为(001);个别四边形片状黄铁矿的两组边分别平行(010)和(101),其生长晶面为(101),矩形片状黄铁矿长轴生长方向为001。在水热条件下黄铁矿以多形貌出现,黄铁矿的片、板状晶体多数是沿(001)面生长的结果,(001)为黄铁矿片、板状晶体的主要二维生长面,并沿001方向扩展,构成了二维晶体。     

一株产铁载体细菌的筛选及其与云母的相互作用

        产铁载体细菌与云母类矿物相互作用的研究有助于了解矿物生物风化和土壤形成的演化规律和机理。采用纯培养法 自南京龙山废钾矿区酸模根际土壤分离筛选到一株高产荧光铁载体的细菌Z6,通过16S rDNA 序列分析和生理生化反应将其 鉴定为假单胞菌属（Pseudomonas sp.）;通过室温静置培养试验研究Z6 菌株与云母的相互作用结果表明,细菌生长代谢前期 （8~15 d）快速产生大量铁载体,菌株与矿物共培养75 d 后,产铁载体细菌对云母类矿物确实产生了风化作用,黑云母组发 酵液中Fe 含量增加了211 倍,Si 含量增加了约27.8 倍,SEM 显示云母表面出现溶蚀坑,细菌可以在矿物表面形成生物膜或 矿物- 细菌复合物。不同矿物对共培养体系中细菌数量、荧光铁载体含量、溶液pH 的影响不同。     

A study on terrain-induced tropical cyclone looping in East Taiwan: case study of Typhoon Haitang in 2005

A mesoscale mountain such as the Central Mountain Range (CMR) of Taiwan can considerably affect the motion and the structure of an approaching tropical cyclone in very complicated ways. Many studies have presented and explained the mechanism for the change of moving speed, track deflection, or track discontinuity. In the past, the tracks of Typhoon Mary (1965), Tropical Cyclone Polly (1993), and Typhoon Haitang (2005) have a looping motion prior to making landfall on Taiwan. When the looping occurs, the timing and the intensity of the typhoon to affect Taiwan can be very different from the one moving with smooth track. It is very important to have a correct forecast for disaster mitigation operations. However, the mechanism causing such looping has not been fully understood. In this study, the case of Typhoon Haitang is examined. The radar reflectivity diagrams are used to illustrate looping in its track. By applying piecewise potential vorticity inversion analysis and numerical model simulations, it is shown that the looping motion of Typhoon Haitang near Taiwan resulted from the CMR terrain effect. When Typhoon Haitang approaches Taiwan and its circulation encounters the CMR, the terrain induces a cyclonic vortex in the lee side of the mountain over southeast of Taiwan. This terrain-induced vortex interacts with Typhoon Haitang in a way similar to the binary vortex interaction. The two vortex centers rotate around their system center, which causes looping of Typhoon Haitang.     

冀西北尚义上侏罗统—下白垩统后城组恐龙足迹新发现及生物古地理意义*

简要报道了新近首次在冀西北张家口尚义地区发现的恐龙足迹。野外地质调查发现,恐龙足迹赋存于尚义晚中生代盆地侏罗系—白垩系后城组顶部。恐龙行迹呈近东西向展布,由数十个足迹构成。初步研究表明,造迹者分别属于兽脚类和蜥脚类恐龙,由西向东行进。足迹中包括兽脚类足迹70余个,组成数个行迹;蜥脚类足迹15个,构成1列行迹。蜥脚类足迹特征显示其可能属于游泳状的行迹。华北北部土城子组/后城组发育于燕辽生物群—热河生物群更替演化时期（晚侏罗世—早白垩世早期）,以往在该时期沉积物中罕见脊椎动物骨骼化石。近年来华北北部土城子组/后城组中频繁发现的恐龙足迹表明,燕辽生物群—热河生物群更替演化时期发育着以恐龙为代表的脊椎动物群。该发现将有助于进一步了解土城子组/后城组沉积时期恐龙属种的多样性及其生物古地理环境。晚侏罗世—早白垩世早期沉积古地理和古生态环境及其与恐龙动物群发育的研究有助于揭示陆地生物群更替演化和环境的关系。