The mineral chemistry of pyroxenite xenoliths in the volcanic rocks of Hoh Xil and their significance

The pyroxenite xenoliths in the volcanic rocks of Hoh Xil consist of clinopyroxenes and orthopyroxenes. The mineral composition of these pyroxenes is similar to that of mantle xenoliths including peridotite and pyroxenite from China and abroad, and different from that of granulites. The pyroxenes formed at 1101–1400°C (averaging 1250°C) and under 30–60 kb (averaging 46 kb). We deduced that the magma was derived from the mantle at a depth of more than 150 km, which fits in with the geophysical conclusion that the low-velocity layer existed in the mantle under 150 km.

     

Peak metamorphic temperatures in type 6 ordinary chondrites: An evaluation of pyroxene and plagioclase geothermometry

Abstract— Quantifying the peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent bodies. Various geothermometers have been used to estimate equilibration temperatures for chondrites of the highest metamorphic grade (type 6), but results are inconsistent and span hundreds of degrees. Because different geothermometers and calibration models were used with different meteorites, it is unclear whether variations in peak temperatures represent actual ranges of metamorphic conditions within type 6 chondrites or differences in model calibrations. We addressed this problem by performing twopyroxene geothermometry, using QUILF95, on the same type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer (Nakamuta and Motomura 1999). We also calculated temperatures for published pyroxene analyses from other type 6 H, L, and LL chondrites to determine the most representative peak metamorphic temperatures for ordinary chondrites. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865–926 °C), L6 (812–934 °C), and LL6 (874–945 °C) chondrites. Plagioclase temperature estimates are 96–179 °C lower than pyroxenes in the same type 6 meteorites. Plagioclase estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (～900 °C), which agrees with previously published oxygen isotope geothermometry, is at least 50 °C lower than the peak temperatures used in current asteroid thermal evolution models. This difference may require minor adjustments to thermal model calculations.     

Free radical scavenging abilities of polypeptide from Chlamys farreri

1 INTRODUCTION Active oxygen free radicals can damage cell structure, even kill the cells, causing aging and cer- tain serious diseases (Bors et al., 1989). Usually, the production and scavenging of active oxygen free radicals are in balance in healthy hu…     

南极威尔克斯地SGR钻孔处雪冰转化过程中的密度变化特征

本文着重描述了SGR钻孔处冰盖上的积雪在密实化过程中的特征变化,并对该过程进行了分段的和全面的回归分析.结果表明,冰盖密度随深度增大,但增长幅度随深度减小.作者提出密度变化减小度的概念.计算得出的所研究冰芯钻取点的密度变化减小度为-0.15kg/m~3·m~2,粒雪成冰前的密实速率平均值为4.08kg/m~3·a.本文得到的冰盖密度变化“临界点”与以往报道的有所不同.分析这一现象时,作者强调当积雪还在活动层时冰盖温度的影响,并以此解释密度剖面的异常变化以及离差的回升.特别指出,积雪的密度变化具有气候学意义,它在一定程度上能够反映出积雪形成及变化过程中气候变化的某些信息.本文由密度变化确定的钻孔点雪冰转化深度为50米.     

Theory of quadrupolar sunspots and the active region of August, 1972

Energy is stored when the force-free magnetic field in an active region departs from a potential field, the departure showing up as a shear in the field. As soon as the field untwists, energy will be released to produce flares. Based on this idea, we derived an analytical solution of the equation of force-free field under the assumption of a constant force-free factor, and found expressions for seven important quantities for quadrupolar sunspots: the magnetic energy of the twisted field, that of potential field, the extractable free energy ΔM, the magnetic flux, the total current, the force-free factor and the field decay factor, in terms of three observables: the field intensity, the twist angle and the distance between two spots of the same polarity. The expression for ΔM can be useful in solar prediction work. For the active region of August, 1972, we found ΔM up to 6 × 10³² erg, sufficient to supply the energy of the observed flare activity. Observations of this active region are in good general agreement with our theoretical expectations: in the entire twisting of the quadrupolar sunspot group, each spot assumes the form of a complete spiral in the clockwise direction for each of the four spots.     

Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.     

A simple mathematical model for soil nail and soil interaction analysis

Soil nails have been widely used to stabilize slopes and earth retaining structures in many countries and regions, especially, in Hong Kong. The analysis of the interaction between a soil nail and the surrounding soil is of great interests to both design engineers and researchers. In this paper, authors present a simple mathematical model for the interaction analysis of a soil nail and the surrounding soil considering a few key factors which are soil dilation, bending of the soil nail, vertical pressure, and non-linear subgrade reaction stiffness. The lateral subgrade reaction between the soil and the soil nail is assumed to obey a hyperbolic relation. Reported test data in the literature are used to verify the present model. The contributions of the soil-nail bending on the pull-out resistance are evaluated in two case studies.     

Micro-XANES mapping of sulphur and its association with magnesium and phosphorus in the shell of the brachiopod, Terebratulina retusa

Biominerals are natural composite materials comprising organic and inorganic components. Detailed knowledge of the nature and distribution of both components is a crucial requirement in order to advance our understanding of biomineral formation, their material properties and preservation potential as well as the interpretation of environmental data. Detailed chemical data are essential for our understanding of the nature and distribution of such components. Micro-XANES mapping at the sulphur K-edge reveals that, in the brachiopod Terebratulina retusa, the sulphate concentration is higher in the outer (primary) layer than in the calcite fibres of the secondary layer. This is co-incident with a higher magnesium concentration. In contrast, the sheaths surrounding the calcite fibres contain sulphur as thiol, confirming the presence of protein while, the sulphur within the fibres themselves, occurs as sulphate. Micro-XANES analysis of the insoluble organic extract from T. retusa indicates the presence of organic sulphate while Micro-Raman spectroscopy confirms that structurally substituted sulphate (SSS) is also present although semi-quantitative Raman spectroscopy carried out in this spectral region (wavenumbers 900–1200) indicates that the sulphate present is at the threshold of detection by Raman spectroscopy. The distribution of phosphorus in the shell of T. retusa correlates well with that of protein indicating the presence of phosphorylated proteins in the periostracum, the sheaths surrounding the calcite fibres and the interface between the primary and secondary layer.