云南个旧南部地区元素地球化学特征

在野外调研和大量样品采集分析的基础上， 运用数学地质中对应分析和因子分析两种方法对样品和变量进行分类划分和成因解释。首先，将样品和元素进行综合计算，按第一、二因子轴作出样品－元素因子平面图，在图上划分四个象限，按象限进行分类，探讨其样品－元素分类规律。其次，按象限计算因子载荷矩阵，分析各因子轴所代表的元素共生组成规律和成矿期次。根据上述研究认为第一因子轴（F1）所代表的Sn、Cu、Pb、Cu、Zn、Au、Ag等元素为主成矿元素组合和主成矿期次，而其它因子轴所代表的Mo、W、Bi、Be等元素为次成矿元素组合和次成矿期次。成矿作用是在区域构造应力驱动力的作用下，与花岗岩侵入有关。成矿溶液除来自深源以外，还与周围基性岩体（脉）和围岩密切相关，矿液实质是一种混合矿浆，在上升运移过程中，充填在有利的构造部位和有利 的地层层位中形成矿体。     

山东山旺盆地中新世两个蚂蚁新属（Heteromyrmex Zhang,1989和Tolylasius Zhang,1989）的修正

1989年,张俊峰发表了山东山旺盆地中新世（N2）2个蚂蚁新属新种：Heteromyrmex atopogaster Zhang,1989和Tolylasius inflatus Zhang,1989。经检验,前一个属是基于不实的观察结果,新属、种应予废除,作为未定属种归人蚁亚科（Formicinae);后一个属的建属根据都非建属的根据,其他的特征系毛蚁属（Lasius)的属征范围,没有建属条件,属应予废,保留其种,转移到毛蚁属。     

河北省邯邢地区高岭石伊利石粘土矿床特征及找矿方向

邯邢地区高岭石、伊利石粘土矿赋存于石炭系本溪组、太原组,二叠系山西组、下石盒子组、上石盒子组的7个层位.矿体主要呈层状产出,厚度变化较大.矿石主要由片状高岭石组成,次要和少量矿物为绢云母、石英、黑云母等.矿床成因包括沉积矿床(如石炭-二叠系高岭石伊利石粘土矿)、风化残积矿床(如软质高岭石粘土矿床).该地区可划分出临城竹...     

Mineralogical studies of pyropes in kimberlites from China

Based on the measurements of refractive index,specific gravity,unit cell parameter,and mineral chemistry and infrared absorption spectrum analyses of pyropes in kimberlites from China,systematic studies of the Physical properties and compositional variations of pyropes of different colors and diverse paragenetic types,within and between kimberlite provinces have been undertaken,The origin of pyropes in the Kimberlites and the depth of their formation have been discussed.Pyropes of the purple series are different from those of the orange series in physical and chemical properties,for exaple,pyropes of the puple series are higher in α0,RI,SG,Cr2O3,MgO,Cr/(Cr Al),Mg/(Mg Fe),and Mg/(Mg Ca),and lower in Al2O3,Fe2O3 FeO than those of the orange series.The classification of garnets in kimberlites from china by the Dawson and Stephens‘ method(1975) has been undertaken and clearly demonstrates that pyropes of diamond-rich kimberlites contain much more groups than those of diamond-poor,especially diamond-free kimberlites.The higher in α0,RI,SG,Cr2O(3.Cr/(Cr Al),knorringite and Cr-component the pyropes are ,the richer in diamond the kimberlites will be.The infrared absorption spectrum patterns of pyropes change with their chemical composition regularly,as reflected in the shape and position of infrared absorption peaks.Two absortpion bands at 862-901 cm^-1 will grade into degeneration from splitting and the absorption band positions of pyropes shift toward lower frequency with increasing Cr2O3 content and Cr/(Cr Al) ratio of pyropes,LREE contents of orange pyrope megacrysts are similar to those of porple pyrope macrocrysts,but the former is higher in HREE than the latter,showing their different chondrite-normalized patterns.The formation pressures of pyropes calculated by Cr-component,Ca-component,knorringite molecules of pyropes show that some pyropes of the purple series in diamondiferous kimberlites fall into the diamond stability field.but all pyropes of diamond-free kimberlites lie outside the diamond stability field.The megacrysts were formed through early crystallization of kimberlites magma at high pressure condition,the majority of the purple pyrope macrocrysts have been derived from disaggregated xenoliths but the minoirty of them appear to be fragments of the discrete megacryst pyropes,or phenocrysts.     

泥岩有水热解产生低分子量有机酸实验研究

直接采用泥岩岩屑进行有水热解,测定实验后水溶液中几种常见低分子量有机酸.结果表明,在实验的水溶液中检测到了丰富的低分子量有机酸,组成上主要为一元羧酸,其中又以乙酸占优势.讨论了不同热解条件对有机酸产率以及组成的影响.实验结果表明,有机酸总量随加热温度和时间增加而增加,并且溶液中不同有机酸相对组成也发生变化.当温度高于1...     

甘肃酒西盆地早白垩世两种Elatides化石微细构造

现已绝灭的古老松柏类植物似纵属Elatides在中生代北半球中高纬度植被组成研究上具有重要意义。甘肃酒西盆地早白垩世地层中发现了Elatides的营养枝和雌球果,并保存有较好的碳膜,对它们进行了详细的宏观形态和微细特征研究。根据营养枝、叶角质层、花粉、球果、苞鳞和种子的特征,鉴定这些化石为2个种：Elatides harrisii Chow和Elatides curvifolia (Dunker) Nathorst。其中：Elatides harrisii的突出特征是,花粉球形且具乳状小突起、表面光滑无纹饰,侧面观具褶皱;Elatides Curvifolia的显著特点为,着生于苞鳞腹面基部的种鳞先端三裂,具三枚胚珠。这些特征与现生杉木Cunninghamia非常相似,推论Elatides与现生Cunninghamia可能具有亲缘关系。通过对Elatides地质历史和地理分布的研究,发现该属的演化方向与中生代大陆漂移的方向具可比性,因而为板块构造学说提供了又一古生物学佐证。     

Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.     

土钉与锚杆联合支护在深基坑工程中的应用

结合深圳市星海阁办公楼的工程实例,从周边环境对深基坑支护的特殊要求及复杂的地质条件出发,论述了采用土钉与锚杆联合支护形式的依据.介绍了在深基坑支护施工中采取的具体措施后期效果.同时分析了这种联合支护结构形式的力学特点,通过将两者联合使用,可实现锚杆支护结构水平侧移小和土钉支护结构受力合理的优点.且土钉与锚杆联合支护,使得上部锚杆和中下部的土钉墙两者形成了统一的受力整体,共同抵抗荷载和变形.     

基于DGT和化学提取法研究浙西北地质高背景区土壤镉生物有效性

地质高背景区相较于人类活动引起的土壤镉污染影响范围更广,在区域尺度上对生态系统和人类健康构成危害。土壤镉生物有效性是决定其生物可利用性、生物毒性的关键因素,因此探寻可行的土壤镉生物有效性评价方法对污染农用地安全利用和风险管控具有重要的理论和实际意义。DGT技术、单一提取法、连续提取法和土壤溶液法常用于测定土壤有效镉,但已有研究成果主要基于同种土地利用类型土壤的室内盆栽实验,难以代表自然污染土壤中的复杂情况。为探明各土壤重金属有效态提取技术对地质高背景区不同土地利用类型土壤Cd生物有效性评估效果,本文以浙江西北部土壤Cd高地质背景区水田土壤-水稻籽实和旱地土壤-小白菜样品为研究对象,实验应用DGT技术、单一提取法（0.01mol/L氯化钙提取）、连续提取法（七步连续提取）和土壤溶液法评价土壤中镉生物有效性。结果显示：①研究区水田和旱地土壤Cd平均含量分别为1.07mg/kg和0.73mg/kg,显著高于浙江和全国土壤平均水平,Cd的异常富集主要与浙西北地区广泛分布的黑色岩系有关。②相较于碳酸盐岩区,黑色岩系区土壤中Cd的生物有效组分占比较高,水田和旱地土壤Cd的活动系数（MF）高达59.9%和51.8%,Cd易在土壤-作物系统中发生迁移富集;③植物体内镉含量Cd-P与不同方法测定的有效镉含量均呈显著正相关,但Cd-P与DGT技术测定的有效镉含量相关性优于其他三种方法,水田土壤测得的有效Cd与水稻籽实相关关系：$ {{C}}_{\text{soln}} $>CDGT>$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $,旱地土壤测得的有效Cd与小白菜相关关系：CDGT >$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $>$ {{C}}_{\text{soln}} $。综合比较不同土壤有效Cd测定方法的优缺点,DGT技术可以模拟植物体对Cd的动态吸收过程,更能准确地反映土壤Cd生物有效性,预测作物Cd含量水平,这与已有研究成果一致。此外,本文研究成果表明DGT技术评价土壤Cd生物有效性,不仅适用于人为污染区,也可应用于地质高背景区。