Helium loss from Martian meteorites mainly induced by shock metamorphism: Evidence from new data and a literature compilation

Abstract— Noble gas data from Martian meteorites have provided key constraints about their origin and evolution, and their parent body. These meteorites have witnessed varying shock metamorphic overprinting (at least 5 to 14 GPa for the nakhlites and up to 45–55 GPa (e.g., the lherzolitic shergottite Allan Hills [ALH] A77005), solar heating, cosmic‐ray exposure, and weathering both on Mars and Earth. Influences on the helium budgets of Martian meteorites were evaluated by using a new data set and literature data. Concentrations of ³He, ⁴He, U, and Th are measured and shock pressures for same sample aliquots of 13 Martian meteorites were determined to asses a possible relationship between shock pressure and helium concentration. Partitioning of ⁴He into cosmogenic and radiogenic components was performed using the lowest ⁴He/³He ratio we measured on mineral separates (⁴He/³He = 4.1, pyroxene of ALHA77005). Our study revealed significant losses of radiogenic ⁴He. Systematics of cosmogenic ³He and neon led to the conclusion that solar radiation heating during transfer from Mars to Earth and terrestrial weathering can be ruled out as major causes of the observed losses of radiogenic helium in bulk meteorites. For bulk rock we observed a correlation of shock pressure and radiogenic ⁴He loss, ranging between ?20% for Chassigny and other moderately shocked Martian meteorites up to total loss for meteorites shocked above 40 GPa. A steep increase of loss occurs around 30 GPa, the pressure at which plagioclase transforms to maskelynite. This correlation suggests significant ⁴He loss induced by shock metamorphism. Noble gas loss in rocks is seen as diffusion due to (1) the temperature increase during shock loading (shock temperature) and (2) the remaining waste heat after adiabatic unloading (post shock temperature). Modeling of ⁴He diffusion in the main U, Th carrier phase apatite showed that post‐shock temperatures of ?300 °C are necessary to explain observed losses. This temperature corresponds to the post‐shock temperature calculated for bulk rocks shocked at about 40 GPa. From our investigation, data survey, and modeling, we conclude that the shock event during launch of the meteorites is the principal cause for ⁴He loss.     

Fidelity and repeatability of wave fields reconstructed from multicomponent streamer data

Wave field reconstruction – the estimation of a three‐dimensional (3D) wave field representing upgoing, downgoing or the combined total pressure at an arbitrary point within a marine streamer array – is enabled by simultaneous measurements of the crossline and vertical components of particle acceleration in addition to pressure in a multicomponent marine streamer. We examine a repeated sail line of North Sea data acquired by a prototype multicomponent towed‐streamer array for both wave field reconstruction fidelity (or accuracy) and reconstruction repeatability. Data from six cables, finely sampled in‐line but spaced at 75 m crossline, are reconstructed and placed on a rectangular data grid uniformly spaced at 6.25 m in‐line and crossline. Benchmarks are generated using recorded pressure data and compared with wave fields reconstructed from pressure alone, and from combinations of pressure, crossline acceleration and vertical acceleration. We find that reconstruction using pressure and both crossline and vertical acceleration has excellent fidelity, recapturing highly aliased diffractions that are lost by interpolation of pressure‐only data. We model wave field reconstruction error as a linear function of distance from the nearest physical sensor and find, for this data set with some mismatched shot positions, that the reconstructed wave field error sensitivity to sensor mispositioning is one‐third that of the recorded wave field sensitivity. Multicomponent reconstruction is also more repeatable, outperforming single‐component reconstruction in which wave field mismatch correlates with geometry mismatch. We find that adequate repeatability may mask poor reconstruction fidelity and that aliased reconstructions will repeat if the survey geometry repeats. Although the multicomponent 3D data have only 500 m in‐line aperture, limiting the attenuation of non‐repeating multiples, the level of repeatability achieved is extremely encouraging compared to full‐aperture, pressure‐only, time‐lapse data sets at an equivalent stage of processing.     

Spectral determination of source parameters in the Marmara Region

Ever since the 1999 Kocaeli earthquake, in which the Kandilli Observatory and Earthquake Research Institute (KOERI) was not able to correctly reflect the magnitude size in its preliminary report because of the saturation effect, a rapid and accurate determination of the earthquake becomes a very important issue. Therefore, in the framework of this study, an automatic determination of the moment magnitude was performed by using the displacement spectra of selected earthquakes in the Marmara Region. For this purpose, 39 three-component broadband stations from KOERI seismic network which recorded 174 earthquakes with magnitudes 2.5?≤?M?≤?5.0 in between 2006–2009 were used. Due to the importance of quality factor in determination of the moment magnitude with spectral analysis method, the quality factor was calculated for the whole region in the beginning. Source spectrum which was obtained by converting the velocity records to displacement spectra and moment magnitudes of earthquakes were determined by fitting this spectrum to classical Brune model. For this aim, an automatic procedure was utilized which based on minimizing the differences between observed and synthetic source spectra identified by the S waves. Besides moment magnitude and location parameters, some source parameters such as seismic moment, spectral level, corner frequency and stress drop were also calculated. Application of the method proves that determining the seismic moment from the source spectra is applicable not only for earthquakes with small magnitude but also moderate earthquakes as well.     

Climate change and modelling of extreme temperatures in Switzerland

This study models maximum temperatures in Switzerland monitored in twelve locations using the generalised extreme value (GEV) distribution. The parameters of the GEV distribution are determined within a Bayesian framework. We find that the parameters of the underlying distribution underwent a substantial change in the beginning of the 1980s. This change is characterised by an increase both in the level and the variability. We assess the likelihood of the heat wave of the summer 2003 using the fitted GEV distribution by accounting for the presence of a structural break. The estimation results do suggest that the heat wave of 2003 is not that statistically improbable if an appropriate methodology is used for dealing with nonstationarity.     

Transport properties in small-scale coastal flows: relative dispersion from VHF radar measurements in the Gulf of La Spezia

Lagrangian transport characteristics in the Gulf of La Spezia, a 5 × 10-km area along the western coast of Italy, are investigated using data collected from a very high frequency (VHF) radar system with 250 m and 30-min resolution and two clusters of Coastal Dynamics Experiment surface drifters during 2 weeks in the summer of 2007. The surface drifters are found to follow the temporal and spatial evolution of the finite-scale Lyapunov exponents (FSLEs) computed by the VHF radar, indicating the precision of both the radar measurements and the diagnostic FSLE in mapping accurately the transport pathways. In light of this agreement, an analysis of the relative dispersion is conducted. It is found that the average FSLE value varies within a narrow range of 4   day^-1 ￡ l ￡ 7   day^-14 \;\mbox{day}^{-1} \leq \lambda \leq 7 \;\mbox{day}^{-1} and displays an exponential regime over the entire extent of the measurements. The dynamical implication is that relative dispersion is controlled nonlocally, namely by slow, persistent, energetic mesoscale structures as opposed to the rapidly evolving high-gradient small-scale turbulent features. The value of the exponent is about an order of magnitude larger than those found in previous modeling studies and analysis of SCULP data in the Gulf of Mexico but somewhat smaller than that estimated from CLIMODE drifters in the Gulf Stream region. Scaling of the FSLE using a metric of resolved gradients of the Eulerian fields in the form of a positive Okubo–Weiss criterion is useful, but not as precise as in modeling studies. The horizontal flow convergence is found to have a small yet tangible effect on relative dispersion.     

Possible Light-Time Effect in the Eclipsing Binary System TY Boo

The O − C diagram for the eclipsing binary system TY Boo was constructed with the new minima times observed at the Ankara University Observatory along with the collected ones from the literature. The O − C diagram shows a cyclic variation superimposed on a quadratic variation. The quadratic variation can be explained in terms of mass loss/exchange mechanism in the system while the cyclic variation is attributed to a possible light-time effect caused by a third body revolving around the close binary.     

Hydrogeochemical and isotopic investigation of the Kolan geothermal field, southeastern Turkey

The Kolan geothermal field is located 24 km northwest of the Karakoçan area of Elaz city in southeastern Turkey. The Keban crystallized limestone of Permo-Carboniferous age is the oldest unit in the area. This unit is overlain by the middle-upper Eocene Krkgeçit formation consisting of conglomerate, sandstone, limestone and marl alternations. The youngest unit in the area is the Upper Miocene-Lower Pliocene Karabakr formation consisting of basalt, andesite and tuffs. Thermal Springs in the Kolan field issue along two major fault zones. The temperature of the hot springs is between 38°C and 45°C. Thermal waters in the area are heated by the geothermal gradient. The waters are classified as hot or very hot and as brackish waters. On the basis of International Association of Hydrogeologists Classification (IAH), waters are grouped as Ca–Na-HCO₃–CO₂-bearing thermal and mineral waters. Chemical analyses indicate a chemical composition of Ca>(Na+K)>Mg - HCO₃>SO₄>Cl. Saturation calculations reveal that the waters are oversaturated with respect to calcite, dolomite and aragonite while undersaturated with respect to gypsum, anhydrite and halite minerals. On the basis of ¹⁸O, ²H and ³H isotope data, Kolan waters are of meteoric origin, recharged from high elevations and then circulated deeply.