Settling of Kaolinite in Different Aqueous Environment

Settling characteristics of soils carry great importance for geotechnical engineers since sediments properties are formed during the settling of soil particles in an aqueous environment. In this study, settling characteristics of kaolinite are investigated. Different ionic strengths of NaCl, CaCl₂ and AlCl₃ were considered as a function of pH in aqueous environment of varying solid concentrations. Factors affecting the settling characteristics and fabric of kaolinitic sediments have been identified. The results of the study reveal that kaolinite settles in either flocculated or dispersed forms depending on pH and ion concentration. Flocculated settling occurs in acidic pH due to formation of flocs in edge-to-face structure with increasing positive charges at the particle edges. Dispersed settling occurs in alkaline pHs when ionic strength is low. When ionic strength is increased in alkaline pHs, kaolinite particles settle in flocculated form. Furthermore, the results show that pH has a significant role on the final sediment thickness or void ratio of kaolinite. Densely packed structures in alkaline and loosely packed structures in acidic aqueous environments are formed depending on pH level. Results also show that as the solid concentration increases, the settling rate decreases due to buoyancy effect. Finally, the zeta potential of kaolinite is correlated with the final sediment thickness or void ratio of kaolinite as a function of pH. This correlation proves that there is a good agreement between zeta potential and the final sediment thickness or void ratio, especially when the soil is settled in a dispersed form.     

Factors controlling the morphological evolution of the Çanakkale Strait (Dardanelles, Turkey)

Seismic profiling, bathymetric and physical oceanographic data collected from the Çanakkale Strait revealed that the morphological evolution of the strait has been controlled by tectonic activity, and sediment erosion and deposition. Sediments in the strait have been sourced mostly by rivers draining the Biga Peninsula during lowstand periods. In highstand periods, by contrast, deposits in the strait were reworked by currents. The seafloor morphology of the Çanakkale Strait is also controlled by a sequence of factors ranging from tectonics to current erosion and deposition. Channel deposits overlying the basement are being eroded at the narrower, meandering central section of the strait (the Nara Passage) due to high current velocities. The eroded sediments are deposited in the relatively linear and wider, northern and southern sectors of the strait exposed to low current velocities. As a result, the high-energy areas are more deeply incised due to the erosion, whereas deposition elevates the seafloor in the areas exposed to lower current energy. Three strike-slip faults, which possibly relate to the activity of the North Anatolian Fault Zone, are responsible for the irregular shape of the strait and this, in turn, controls the current velocity along the strait. The high-energy conditions probably commenced with the latest invasion of Mediterranean waters some 12 ka b.p., and have continued as a two-layered current system to the present day.     

Biostratigraphy of the Çeşmeler and Elmalι Dere formations: First records of upper Cretaceous planktonic foraminifera and radiolarians from the Eastern Pontides (Maçka,Trabzon, Turkey)

Upper Cretaceous pelagic deposits outcropping in the Maçka (Trabzon) region include radiolarians and pelagic foraminifera. The Çatak Group represented by the volcano-sedimentary successions consists of three formations having different properties. Two sections, ÇTK1 and ÇTK2, are selected from the Çe meler and Elmalι Dere formations, respectively, establishing the biostratigraphy of outcropping sedimentary units. A total of 17 species of Whiteinella, Helvetoglobotruncana, Marginotruncana, Dicarinella, Praeglobotruncana, Archaeoglobigerina and Hedbergella demonstrating the early Turonian–Coniacian are established in the ÇTK1 stratigraphic section. The early Turonian radiolarian fauna consisting of Halesium sexangulum Pessagno, 1971, Crucella cachensis Pessagno, 1971, Stichomitra communis Squinabol, 1903 is also defined in the same section. A total of 30 species of Crucella, Halesium, Pessagnobrachia, Patulibracchium, Alievium, Archaeospongoprunum, Dicyomitra, Stichomitra, Diacanthocapsa, Dactiyliodiscus, Amphipydax, Pseudoaulophocus, Acaeniotyle, Archaeodictyomitra, Actinomma, Xitus, Neosciadocapsidae characterizing the early and late Turonian, as well as the Coniacian–early Santonian are recognized from red-coloured pelagic limestones of the ÇTK2 section. Also, planktonic foraminifera species of Marginotruncana, Hedbergella, Heterohelix, Globotruncana, Globotruncanita, Archaeoglobigerina, Dicarinella characterizing the Coniacian–Santonian are described in the thin sections of the same samples. The age of red-coloured limestones is identified as the Coniacian–Santonian benefit from radiolarians and pelagic foraminifera. Consequently, radiolarians and pelagic foraminifera within sedimentary successions of the investigation area are distributed in two intervals that coincide with the early Turonian–Coniacian and Coniacian–Santonian intervals.     

Understanding Extragalactic Hydroxyl

Hydroxyl (OH) is one of the few molecules in space showing both maser emission and absorption. In the Milky Way, hydroxyl has been found in various environments such as stellar envelopes, star-forming regions, and HII regions, tracing the physical states of the interstellar medium. Extragalactic OH has been found to provide essential information about the dusty and obscuring material within the inner kiloparsec region of active galaxies. At angular resolution of a few tens of parsecs, OH shows a rather complicated spatial distribution and the interpretation of the circumnuclear environment is rather difficult. Based on results obtained from low- and high-resolution observations, the diagnostic tools of OH will be reviewed and the strategies to further investigate extragalactic OH will be discussed.     

Seismic performance of a high-rise building by using linear and nonlinear methods

Natural Hazards - In this paper, the seismic behavior of the existing reinforced concrete tall building is investigated by using the linear and nonlinear dynamic methods. The selected existing...     

Geochemistry of Proterozoic molybdenite — mineralized aplites in Northern Sweden

The largest known Precambrian molybdenite occurrences in Sweden are of the aplitic type. In order to improve the understanding of their genesis, 67 samples of aplites, aplitic granites and associated granites were analyzed for major elements, Mo, Sn, Be, Ba, Rb, Sr, Cu, Zn, Zr, V, Cr, Ni, Y, Nb, F, Cl and S. Five samples were analyzed for rare earth elements. The following genetic model can be proposed:In the upper parts of granitic intrusions the magma is enriched in lithophile elements and elements such as F and Mo. The aplites represent direct differentiation products of the granites and have solidified without the development of a second mobile aqueous phase, except locally, where small pegmatite segregations have formed. As crystallization proceeds, the concentration of Mo in the magma increases, and when the aplites solidify, the Mo that cannot be incorporated in the rock-forming minerals is precipitated as molybdenite. Biotite seems to be the major Mo-carrier among the rock-forming minerals in the aplites.     

Water absorption process effect on strength of Ayazini tuff,such as the uniaxial compressive strength (UCS), flexural strength and freeze and thaw effect

Tuffs have been used as a construction material possibly since ancient times. In Afyonkarahisar, Turkey, there are numerous buildings constructed by tuff. Tuff has been a local construction material, during the Roman, Seljuk and Ottoman periods. Even though tuffs have relatively low durability and low strength values compared to marble, etc., they have survived with no major deterioration failures on many historical buildings. It has also been preferred because of its high porous texture, lightweight and easy shaping and process properties in the building sector. Naturally, it would be easily affected by water and humidity because of its porous structure. However, having this kind of structure leads to poor durability properties due to keeping water in it. The main objective of this study was to evaluate the physical and mechanical properties of the tuff quarried from the region and possible water effect, which may lead to degradation of its strength and durability of the material, thereby shortening the life span of the building structure used. Samples, which were tested after exposing to water and the freeze and thaw effects, were measured at a certain time. In this study, uniaxial compressive strength and flexural strength tests were conducted on test samples. The test results indicate that water may deteriorate the tuff’s strength properties and durability of the materials in due time.     

LDF pseudopotential calculations of the α-quartz structure and hydrogarnet defect

Ab initio LDF theory has been used to study the structure of the hydrogarnet defect in α-quartz. The predicted structure is in good agreement with the available sexperimental data. The techniques employed also yield a good model for the structure of α-quartz, giving an average Si-O bond length of 1.62 Å and average Si-O-Si angle of 142°.     

Biodegradation effects over different types of coastal rocks

Modern coastal areas have natural and transported rocks (armourstone) on which various types of organisms live. Burrowing, boring and feeding by these organisms can destroy or modify the coastal rocks and hence change the coastal morphology. Two rock types and three dominant types of organisms have been studied in Mersin Bay, Eastern Mediterranean of southern Turkey. In this study area, Plio-Quaternary conglomerates and variously aged limestone armourplates have been affected by Phoronida worms, bivalve Brachidontes pharaonis (Fischer P. 1870) and the limpet Patella sp. Phoronida colonies were found covering the hard substratum as a mat and form tubular endolithes of 35.0 mm depth and 1.5 mm diameter, whilst Brachidontes pharaonis (Fischer P. 1870) form 44 mm deep vase-shaped gastrochaenolites. The bioerosive activity of Limpet Patella sp., found intertidal and within the spray zone, cannot be significantly observed on the rocks over short time periods. The soft sandy matrix of the conglomerates present were found to disintegrate by bioerosional processes, with the released gravels being transported and deposited onto the beach. Within the armourstone limestone blocks, a maximum of 44.0 mm deep holes developed after 50–60 years. However, these biological activities do not threaten the stability of the blocks due to their hard and homogeneous internal structure. Furthermore, the organism colonies that cover these rocks as a strong mat (maximum 29.0 mm) act to protect their surfaces from further biological attack and wave action.