Clinopyroxenes in the tawhiroko tholeiitic dolerite at Moeraki,north-eastern Otago,New Zealand

Clinopyroxenes from various lithologic units in a single tholeiitic dolerite intrusion 50 m thick were analysed with the electron microprobe. Microphenocrysts of augite in the chilled marginal rock have the least scattered CaMgFe ratios, around Ca₃₈Mg₅₀Fe₁₂, and lowest Ti/Al ratios, less than 1/4, of the augites examined; they crystallized prior to emplacement. The augites which crystallized in situ are more Fe-rich and have higher Ti/Al ratios, close to 1/2. Pigeonite started crystallizing later than augite and formed rims to augite crystals. Continuous zoning from augite to subcalcic augite as was previously reported by Benson (1944) for the same dolerite is not observed. Subcaloic ferroaugites, however, link augite and ferropigeonite in the outermost margins of pyroxenes in the later segregations. The small scale differentiation in situ gave rise to globules, veins, and pegmatoids, in which sector-zoning of augite is well developed. The {100} sectors are enriched in MgSiO₃, FeSiO₃, and MnSiO₃ components relative to the {010} and the {110} sectors, and are accordingly depleted in other components. The protosite theory of sector-zoning formation proposed by Nakamura (1973) is further developed and the environment which favours the development of sector-zoning is discussed. The formation of augite rims around quartz-rich xenoliths and the compositional characteristics of the augites concerned are due to local high silica activities. Comments are made concerning some lunar pyroxenes in the light of the present study.     

Complex geometry and segmentation of the surface rupture associated with the 14 November 2001 great Kunlun earthquake, northern Tibet, China

The 14 November 2001 Kunlun, China, earthquake with a moment magnitude (M_w) 7.8 occurred along the Kusai Lake–Kunlun Pass fault of the Kunlun fault system. We document the spatial distribution and geometry of surface rupture zone produced by this earthquake, based on high-resolution satellite (Landsat ETM, ASTER, SPOT and IKONOS) images combined with field measurements. Our results show that the surface rupture zone can be divided into five segments according to the geometry of surface rupture, including the Sun Lake, Buka Daban–Hongshui River, Kusai Lake, Hubei Peak and Kunlun Pass segments from west to east. These segments, each 55 to 130 km long, are separated by step-overs. The Sun Lake segment extends about 65 km with a strike of N45° 75°W (between 90°05′E 90°50′E) along the previously unrecognized West Sun Lake fault. A gap of about 30 km long exists between the Sun Lake and Buka Daban Peak where no obvious surface ruptures can be observed either from the satellite images or field observations. The Buka Daban–Hongshui River, Kusai Lake, Hubei Peak and Kunlun Pass segments run about 365 km striking N75° 85°W along the southern slope of the Kunlun Mountains (between 91°07′E 94°58′E). This segmentation of the surface rupture is well correlated with the pattern of slip distribution measured in the field. Detailed mapping suggest that these five first-order segments can be further separated into over 20 second-order segments with a length of 10–30 km, linked by smaller scale step-overs or bends.Our result also shows that the total coseismic surface rupture length produced by the 2001 Kunlun earthquake is about 430 km (excluding the 30-km-long gap), which is the longest coseismic surface rupture for an intracontinental earthquake ever recorded.Finally, we suggest a multiple bilateral rupture propagation model that shows the rupture process of the 2001 M_w 7.8 earthquake is complex. It consists of westward and eastward rupture propagations and interaction of these bilateral rupture processes.     

K-Ar ages of intrusive rocks in the Oban-Obudu massif and their significance for the tectonic and plutonic history of southeastern Nigeria

Abstract K-Ar ages have been obtained for mineral separates: plagioclases from two dolerites and biotites from one granite and four granodiorites in the Oban-Obudu massif of southeastern Nigeria. Dolerites in the Oban area give K-Ar plagioclase ages of 204.0 ± 9.9 Ma and 219.9 ± 4.7 Ma. The granite of the Obudu area yields a K-Ar biotite age of 507.6 ± 10.1 Ma whilst the granodiorites in the Oban area yield K-Ar biotite ages ranging from 474.6 ± 9.4 Ma to 511.8 ± 10.0 Ma. The dolerites are related to the tholeiitic basaltic magmatism at the early opening of the central Atlantic, and are compatible in age with the formation of the Ring Complexes and the rifting of the Benue Trough of Nigeria. The granites and granodiorites belong to the syntectonic Older Granite series in the Pan-African orogeny. The emplacement timing deduced from the reported Pb-Pb zircon age of 617 ± 2 Ma and the newly obtained biotite ages suggest that these older granites in southeastern Nigeria had a prolonged cooling history of ∼110 Ma.     

On Two-Dimensional Modeling Of Magnetotelluric Field Data

In this paper, some recent topics on the modeling of magnetotelluric data are introduced. The focus is on the handling of real field data for two-dimensional resistivity modeling. First, the removal of the effects of near surface heterogeneity is reviewed. It covers telluric distortions (phase mixing and static shift) and magnetic distortions using conventional Groom-Bailey type 3D/2D model (three-dimensional local anomaly underlain by regional two-dimensional structure). The extension of a 3D/2D distortion model for multi-site, multi-frequency is a new development. Magnetic distortion seems to be less significant for land observations, but significant for sea floor data, where the regional magnetic field is weak due to seawater. In special cases involving for example, distortion due to topography and bathymetry, explicit removal is possible. There are some schemes proposed for a 3D/3D model (three-dimensional local anomaly underlain by regional three-dimensional structure). Along with the removal of the distortion, it is important to recognize the dimensionality of the dataset prior to modeling. A property using strike estimates for each site is an indicator for dimensionality which is unaffected by local distortion. Mapping the local strike or a rose diagram is an effective visualization of the dimensionality.Two-dimensional inversion is becoming routine. For the fast calculation of derivatives, approximate calculation, reciprocity or conjugate gradient methods are used. In order to incorporate a priori information and to overcome the intrinsic ill-posed nature of the inversion problem, imposing constraints on the model structure is important. A proper tradeoff between the data fit and constraints should be optimized to obtain minimum structures that are required by the field data. However, the choice of constraints is rather subjective and depends on the geological situations. For field data, two-dimensional inversion has limits on modes, area, and period range. Special care must be taken for the structure outside the profile. Two-dimensional inversion incorporating anisotropy is interesting and becoming popular, but the structure may not be unique. Future development in three-dimensional inversion for real datasets should take the above points into consideration.     

Audio frequency magneto-telluric survey of Norikura Volcano in central Japan

Norikura Volcano has not been active during the last 10,000 years in spite of the activity of the surrounding volcanic mountains. To study past volcanic activities, geological studies were carried out extensively. However, quite a few geophysical investigations were conducted to contribute to volcanology. Our objective is to detect the present subsurface structure of Norikura Volcano and to define volcanic stratifications. In the vicinity of Norikura Volcano, geothermal fields are still active. Subsurface volcanic rocks in this area have been exposed to geothermal activity and altered. To comprehend volcanic stratifications of Norikura and geothermal activity, we conducted audio frequency magneto-telluric (AMT) surveys around Norikura Volcano. AMT survey is useful in clearly defining the resistivity structure related to volcanic regions. The AMT data were acquired over a frequency range 10 Hz–10 kHz. Decomposition analysis was applied to the tensor impedance data. Subsequently, apparent resistivity and phase data were inverted using a two-dimensional magneto-telluric (MT) inversion and a model of Norikura was derived. The final model manifests that the surface resistors are in agreement with andesite lava or dacite lava. As for the deeper structure, a horizontal conductor is situated above resistive basements. The alteration of the conductor was weak, while basement rocks were strongly altered and/or heated through the thermal activity. The existence of these layers seems to indicate the degree of thermal activity of Norikura Volcano.     

Impact of septic tank systems on local groundwater quality and water supply in the Pearl River Delta,China: case study

Located at southern coast of China, the Pearl River Delta (PRD) is facing serious water problems in both quantity and quality after its rapid urbanization in the last decade. Most remarkably, the local groundwater, that was used to be the source of drinking water before the urbanization was polluted due to poor management of the septic tanks. In order to study the effects of suburban development on local groundwater flow and water quality in the PRD region, Fengcun of Guangzhou has been chosen as the study area. In Fengcun, drinking water was groundwater before the 1990s, but now piped reservoir water is used by each family because the groundwater has been polluted. This study clarifies the source and process of the groundwater pollution from septic tanks using isotopic and geochemical characteristics, especially nitrate (NO₃^?) concentrations. Water samples were collected from the wells and ponds in Fengcun in March and July 2005 and in July 2006. Based on the pe–pH diagram, NO₃^? and ammonium of groundwater are from the effect of human activities, rather than from nitrification and ammonification of N₂. NO₃^? pollution of groundwater is from point sources, and NO₃^? concentrations decrease from northeast to southwest. Groundwater is polluted rapidly by the leakage of septic tanks. NO₃^? concentrations of pollution sources were lower than 20 mg l^?1 in March 2005, but had increased to about 120 mg l^?1 in July 2006. This implies that groundwater protection should be strengthened in rural areas of the PRD. Copyright © 2007 John Wiley & Sons, Ltd.     

Phase transition in CaSiO3 perovskite

A phase transition in pure CaSiO₃ perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO₃ perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al₂O₃ content dissolved in CaSiO₃ perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO₃(+ 3 wt.% Al₂O₃) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.     

High-pressure behavior of MnGeO3 and CdGeO3 perovskites and the post-perovskite phase transition

The stability and high-pressure behavior of perovskite structure in MnGeO₃ and CdGeO₃ were examined on the basis of in situ synchrotron X-ray diffraction measurements at high pressure and temperature in a laser-heated diamond-anvil cell. Results demonstrate that the structural distortion of orthorhombic MnGeO₃ perovskite is enhanced with increasing pressure and it undergoes phase transition to a CaIrO₃-type post-perovskite structure above 60 GPa at 1,800 K. A molar volume of the post-perovskite phase is smaller by 1.6% than that of perovskite at equivalent pressure. In contrast, the structure of CdGeO₃ perovskite becomes less distorted from the ideal cubic perovskite structure with increasing pressure, and it is stable even at 110 GPa and 2,000 K. These results suggest that the phase transition to post-perovskite is induced by a large distortion of perovskite structure with increasing pressure.     

Pb, Nd, and Sr isotopic constraints on the origin of Miocene basaltic rocks from northeast Hokkaido, Japan: Implications for opening of the Kurile back-arc basin

Late Miocene (7–9 Ma) basaltic rocks from the Monbetsu‐Kamishihoro graben in northeast Hokkaido have chemical affinities to certain back‐arc basin basalts (referred to herein as Hokkaido BABB). Pb‐, Nd‐ and Sr‐isotopic compositions of the Hokkaido BABB and arc‐type volcanic rocks (11–13 Ma and 4–4.5 Ma) from the nearby region indicate mixing between the depleted mantle and an EM II‐like enriched component (e.g. subducted pelagic sediment) in the magma generation. At a given ⁸⁷Sr/⁸⁶Sr, Hokkaido BABB have slightly lower ¹⁴³Nd/¹⁴⁴Nd and slightly less radiogenic ²⁰⁶Pb/²⁰⁴Pb compared with associated arc‐type lavas, but both these suites are difficult to distinguish solely on the basis of isotopic compositions. These isotopic data indicate that while generation of the Hokkaido BABB involves smaller amounts of the EM II‐like enriched component than do associated arc lavas, Hokkaido BABB are isotopically distinct from basalts produced at normal back‐arc basin spreading centers. Instead, northeast Hokkaido BABB are more similar to basalts erupted during the initial rifting stage of back‐arc basins. The Monbetsu‐Kamishihoro graben may have developed in association with extension that formed the Kurile Basin, suggesting that opening of the basin continued until late Miocene (7–9 Ma).     

Stabilities of NAL and Ca-ferrite-type phases on the join NaAlSiO<Subscript>4</Subscript>-MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript> at high pressure

Stabilities of hexagonal new aluminous (NAL) phase and Ca-ferrite-type (CF) phase were investigated on the join NaAlSiO₄-MgAl₂O₄ in a pressure range from 23 to 58 GPa at approximately constant temperature of 1,850 K, on the basis of in situ synchrotron X-ray diffraction measurements in a laser-heated diamond-anvil cell. The results show that NAL is formed as a single phase up to 34 GPa, NAL + CF between 34 and 43 GPa, and only CF at higher pressures in 40%NaAlSiO₄-60%MgAl₂O₄ bulk composition. On the other hand, both NAL and CF coexist below 38 and 36 GPa, and only CF was obtained at higher pressures in 60%NaAlSiO₄-40%MgAl₂O₄ and 20%NaAlSiO₄-80%MgAl₂O₄ composition, respectively. These results indicate that NAL appears only up to 46 GPa at 1,850 K, and CF forms continuous solid solution at higher pressures on the join NaAlSiO₄-MgAl₂O₄. NAL has limited stability in subducted mid-oceanic ridge basalt crust in the Earth’s lower mantle and undergoes a phase transition to CF in deeper levels.