Density measurements of liquid Fe–Si alloys at high pressure using the sink–float method

The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm³ non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.     

Extreme Infrared Stars Discovered in Magellanic Cloud Globular Clusters

We report preliminary results of our systematic survey for infrared stars in the globular clusters of the Magellanic Clouds. In the course of an ISOCAM survey for AGB stars in the intermediate-age clusters, we have discovered extremely red AGB stars in NGC 419 and NGC 1978. From their colours and luminosities, they are thought to be experiencing intense mass-loss and to be in the final or superwind phase of the AGB evolution. However, they seem to be of somewhat lower luminosity than the corresponding visible AGB stars when only the mid-infrared data are taken into account. This suggests that hitherto unobserved infrared excesses may exist at longer wavelengths. This revised version was published online in August 2006 with corrections to the Cover Date.     

Classification of Japanese rivers by heavy metals in bottom mud

Bottom mud was collected from the upper and lower reaches of 92 rivers in Japan to determine the distribution of 0.5N-HCI-soluble heavy metals. The average concentrations of Cu, Zn, Pb, and Cd in the mud from the lower reaches were from two to three times higher than those in the upper reaches. Japanese rivers were classified according to the degree of heavy metal pollution by using the values of 0.5N-HCI-soluble metals in the lower reaches of rivers. The content of 0.5N-HCI-soluble heavy metals in the mud of the upper reaches was used as the standard value. The classification of rivers was made by a cluster analysis according to Euclidian distance. As a result, rivers in Japan could be classified into three groups based on the degree of metal pollution, and the classification was in agreement with the pollution index.     

Thinning of the near-earth (10∼15 RE) plasma sheet preceding the substorm expansion phase

The timing of the plasma-sheet thinning relative to the onset of the expansion phase of substorms is examined by the analysis of the OGO 5 electron (79 ± 23 keV) and proton (100～150 keV) data with the aid of simultaneous magnetic field observations. It is found that the timing of the thinning is significantly dependent on the distance. At $\text{x}{}^2\text{+ y}{}^2\text{? 15 R}{}_{\mathrm{E}}$ the thinning often starts before the onset, while at $\text{x}{}^2\text{+ y}{}^2\text{? 15 R}{}_{\mathrm{E}}$ it tends to occur after the onset, where x and y refer to solar magnetospheric coordinates. The thinning that precedes the expansion-phase onset has been found to reduce the thickness to ～1 R_E, and further thinning may occur in a spatially limited region. Hence it is conceivable that the formation of the neutral line characterizing the substorm expansion phase is the consequence of the thinning of the plasma sheet in the near-Earth region.     

Does heavy oil pollution induce bacterial diseases in Japanese flounder Paralichthys olivaceus?

As basic research for the effect of heavy oil on the fish immune system, in this study, the number of leukocyte was counted in Japanese flounder Paralichthys olivaceus, after exposure to heavy oil at a concentration of 30 g/8L for 3 days. To compare the numbers of bacteria in the skin mucus between oil-exposed and control fish, viable bacteria were enumerated by counting colony forming unit (CFU). Compared with 5.79+/-1.88 x 10(7)leukocytes/mL in the controls, the exposed fish demonstrated higher counts, averaging 1.45+/-0.45 x 10(8)cells/mL. The bacterial numbers of control fish were 4.27+/-3.68 x 10(4)CFU/g, whereas they were 4.58+/-1.63 x 10(5)CFU/g in the exposed fish. The results suggest that immune suppression of the fish occurred due to heavy oil stressor, and bacteria could invade in the mucus, resulting in the increasing leukocyte number to prevent infectious disease.     

Scarifying and fingering surfaces of plunging jets

The local surface deformation resulting from the oblique impact of a columnar water jet has been computed, using a three-dimensional large eddy simulation, as a model of the overturning jet of a breaking wave. The emergence of the secondary jet from the front face of the initial jet has been examined and the organisation of the vortices within the jet characterised. As the secondary jet emerges, the vorticity field becomes unstable under the action of the strong shear beneath the jet surface and pairs of longitudinal counter-rotating vortices stretched along the direction of the jet projection are formed. The presence of these longitudinal vortex pairs creates convergent surface flows, resulting in the formation of longitudinal scars on the rear face of the projecting jet. Following significant growth of the scars on both its upper and lower surfaces, the jet decouples into fingers. The lateral widths of the longitudinal vortices provide a minimum measure of the finger size. A horizontal Froude number Fr_h, representing a measure of strength of horizontal shear in a gravity-dominated impacting flow is defined, which characterises the organisation of the longitudinal vortices occurring in the shear flow, and the resultant formation of scars and fingers. For higher Fr_h, stronger longitudinal vortices and deeper scars are formed at longer lateral intervals, enhancing the fingering process during the splashing event. Fundamental features of material transport in the vicinity of the surface of jets (e.g. gas transfer across a sea surface) are related to the entrainment of surface fluid by the longitudinal vortices, and is thus also characterised by Fr_h.     

Helium isotopic fingerprints of the heavy land subsidence left in groundwater of the Saga Plain,near Beppu–Shimabara graben,Kyushu, Japan

The Saga Plain is near Beppu–Shimabara graben, a region of potential active volcanism. In the graben, mantle He, which has a high ³He/⁴He ratio of 1.1 × 10⁻⁵, escapes easily from the underlying subduction zone. In groundwater of the Saga Plain, except in the Shiroishi district, this ratio gradually increased as the dissolved He content increased, to a maximum of 5 × 10⁻⁶. In central Shiroishi, however, the ratio reached a minimum of 8.7 × 10⁻⁷ with increasing dissolved He content, suggesting that groundwater in central Shiroishi has selectively accumulated radiogenic He, which has a very low ratio of 1 × 10⁻⁸, rather than reflecting the regional He, which is rich in mantle He. This can be explained if groundwater in Shiroishi has become mixed with fossil pore water drawn from impermeable marine clay aquitard layers. The withdrawal of pore water has also caused severe land subsidence in central Shiroishi.     

Dissakisite-(Ce) chemical composition: some implications for its origins

Euhedral dissakisites from Trimouns dolomite mine, France, is compositionally zoned. Back-scattered electron (BSE) images reveal that each of the described dissakisite crystals has three distinct compositional zones: normal zoned core (Mg-rich), oscillatory zoned middle (Ca–Al-rich) and homogeneous rim (Fe–ΣREE-rich). The latter zone with Fe²⁺ > Mg corresponds to allanite-(Ce). Dissakisite-(Ce) also displays pronounced zoning in Fe/Mg which may suggest that the temperature of crystallization continuously decreased from core to rim. Despite a systematic increase in Fe/Mg of the dissakisite with an allanite rim, there is no monotonic decrease in the REE zoning: the normal zoned core and homogeneous rim are rich in La, Ce and Pr, but the relatively REE-poor oscillatory zoned middle is relatively abundant in Y, Sm and Gd. Discontinuous variation in REE content of the dissakisite, with the allanite rim may indicate a localized change in either the relative concentration of various ligands or pH of the crystallizing fluid. Observations under the polarizing microscope confirm that the different zones have simultaneous extinction. These chemical and optical observations suggest that epitaxial crystallization of dissakisite, from Trimouns, passes through three formation stages. The ternary Fe²⁺–Mg²⁺–(Al + Fe)³⁺ diagram illustrates that in general dissakisite can be classified into two groups, (Al + Fe)³⁺-rich and an Mg-rich; dissakisite from Trimouns belongs to the former group. Chondrite-normalized REE patterns of dissakisites from Trimouns are similar to those of allanites formed by hydrothermal fluids. In conclusion, it is clear from the above two geochemical characteristics that dissakisites from Trimouns are of (Al + Fe)³⁺-type, and were derived from hydrothermal fluids.     

Crystal chemistry of volcanic allanites indicative of naturally induced oxidation-dehydrogenation

The crystal chemistry of volcanic allanites from both the Youngest Toba Tuff (YTT), Sumatra, Indonesia and SK100 volcanic ash beds (SK100-VAB), Niigata, Japan has been examined by electron microprobe analysis (EMPA), Fourier-transform infrared spectroscopic analysis (FTIR), and single-crystal structure analysis. In the FTIR study, based on the Diamond ATR accessory, YTT and SK100- VAB allanites were observed to have different OH contents, respectively: the former has 0.64 wt% H₂O (OH: 0.40 apfu.), while the latter has 1.65 wt% H₂O (OH: 1.00 apfu.). The crystal structures of these two allanites have been refined to individual R indices (3.64 and 4.25) based on 1350 observed reflections (|Fo| > 4sig|Fo|) measured using a single-crystal diffractometer with MoKα X-radiation. The OH-poor YTT allanite has a shorter b axis, a longer c axis, and larger β value than the relatively OH-rich SK100-VAB one. The bond valence sums of O4 (accepter oxygen for H atom) and O10 (donor oxygen for H atom) are 1.962 and 1.709 v.u. for YTT allanite (valence sum: 3.671 v.u.) and 1.754 and 1.271 v.u. for SK100-VAB one (valence sum: 3.025 v.u.). The difference from the ideal total bond valence value (4.00 v.u.) of O4 and O10 in YTT allanite (0.33 v.u.) is smaller than that in SK100-VAB (0.98 v.u.). These difference values are also broadly consistent with the corresponding differences in OH content between the YTT (OH: 0.40 apfu.) and SK100-VAB allanites (OH: 1.00 apfu.) determined by FTIR- ATR. Chemical analyses, FTIR-ATR and crystal structure refinement of YTT and SK100-VAB allanites yielded the following crystal chemical formula: YTT: (Ca_0.83Mn²⁺ _0.06Fe²⁺ _0.11)(La_0.24Ce_0.32Pr_0.04Nd_0.11Sm_0.02Th_0.04Ca_0.21)(Al_0.73Fe³⁺ _0.19Ti_0.08)(Al_0.89Fe³⁺ _0.11)(Fe²⁺ _0.22Fe³⁺ _0.62Mg_0.16)(SiO₄)Si₂O₇O_1.6(OH)_0.4, SK100-VAB: (Ca_0.81Fe²⁺ _0.13Mn²⁺ _0.06)(La_0.22Ce_0.34Pr_0.05Nd_0.13Sm_0.02Th_0.02Ca_0.22)(Al_0.76Fe³⁺ _0.19Ti_0.05)Al_1.00(Fe²⁺ _0.73Fe³⁺ _0.17Mg_0.10)(Si_0.96Al_0.04O₄)Si₂O₇O(OH). Therefore, it is concluded that welding of the Youngest Toba Tuff caused the following post-crystallization changes to occur in YTT allanite: oxidation of Fe²⁺ to Fe³⁺, release of H₂, and the concomitant replacement of OH^? by O^2?. These oxidation and dehydrogenation processes advanced during the welding to thereby produce oxyallanite. Oxyallanite had been reported only in laboratory studies where it was produced by heating natural allanite. Our report on natural oxyallanite suggests that it may be present in other welded silicic volcanic rocks as well.