Experimental Study Assessing the Role of Sedimentary Organic Materials to Control the Redox State of Ground Materials to Control the Redox State of Groundwater: Consumption of Dissolved Oxygen by Humic Acid

Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O₂ concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O₂ concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10^-9 at 25°C, 2.22 × 10^-8 at 45°C, and 1.28 × 10^-7 moles m^-2 s^-1 at 65°C.     

Formation of the Yakuno ophiolite; accretionary subduction under medium-pressure-type metamorphic conditions

The notion that the Yakuno ophiolite and overlying Maizuru Group represents an accretionary prism formed during the Permian evolution of Japan on the Yakuno eruptive sequence, association of hemipelagic mudstone with silicic tuff, exotic fossiliferous limestones derived from previously accreted sea-mounts, upward coarsening of sequences terrigenous sandstone and conglomerate, and mildly deformed Permian and Triassic forearc basin formations. The most important indicator, however, is the seaward imbrication and repetition observed in both the Maizuru Group and the ophiolite itself. D1 deformation structures include axial–planar foliations (pressure-solution cleavage for the Maizuru Group and granulite–amphibolite metamorphic layering in the ophiolite), flattening type strain, symmetric pressure shadows and fringes, and isoclinal folds showing axial–planar foliations and thrust faulting at their overturned limb. The exceptional asymmetry observed indicates seaward-directed shearing near the thrust, while D1 structures in the Maizuru zone are explained by off-scraping, above the basal decollement. The later Jurassic D2 kink fold structure includes a first-order asymmetric kink with a brittle thrust at its overturned limb, more-or-less coeval with M2 retrograde metamorphism. Medium-pressure M1 prograde metamorphism in the Yakuno ophiolite produced layering of granulite and amphibolite, and in the Maizuru Group, formation of illite along pressure-solution cleavage of mudstones. The metamorphic grade is controlled by the stratigraphic relationships and appears typical of that in ocean floor regions. However, there was only one episode of M1 prograde metamorphism which occurred contemporaneously with D1 off-scraping. Given that subduction zones are normally characterized by high P/T metamorphic regimes, the observed P/T history appears to reflect relatively unusual conditions. Such high thermal gradients may plausibly reflect the approach of a young, hot oceanic plate which continued subducting beneath the Japanese arc. Accordingly, the Yakuno ophiolite was probably formed at the trench–trench–ridge triple junction.     

Runoff and water budget of the Liudaogou Catchment at the wind–water erosion crisscross region on the Loess Plateau of China

The objectives of this study were to examine the runoff characteristics and to estimate water budget at the wind–water erosion crisscross region on the Loess Plateau of China. A small catchment known as Liudaogou that has representative meteorological and hydrological conditions of the wind–water erosion crisscross region was chosen as the study location. A numerical model for rainfall-runoff was developed and verified; rainfall-runoff calculation for 5 years (2005–2009) was performed. The observed data and numerical result of the surface runoff were used for evaluating runoff characteristics and estimating the annual water budget. Runoff rate was proportional to average intensity of rain. Even though rainfall duration was for few minutes, surface runoff was generated by intensity of more than 2.6 mm × 5 min^?1, when rainfall duration exceeded 10 h; surface runoff was generated by an intensity of 0.6 mm × 5 min^?1, while annual runoff rate was 10–15 %. The unit area of 1 km² was adopted as the index area for estimating annual water budget. Runoff, evapotranspiration, variation of water storage, and habitant water consumption accounted for 20.4, 75.6, 0, and 4 % of the total annual precipitation, respectively. Results of this study provide the basis for further research on hydrology, water resources, and sustainable water development and utilization at the wind–water erosion crisscross region on the northern Loess Plateau where annual water resources are relatively deficient.