川东北普光地区深层富钾卤水钾资源提取研究

四川盆地地下卤水资源丰富,尤其川东北地区地下卤水富含高品质钾资源。本项目以四川普光地区富钾卤水为研究对象,根据卤水组成,采用模拟计算并结合实验验证的方法,研究了高温蒸发时,氯化钠、氯化钾、光卤石、硼酸等矿物的析出阶段及特点。研究结果表明,当蒸失水率约80%时,体系中约85%的NaCl析出,同时KCl达到饱和,继续蒸发可获取钾石盐。控制总蒸失水率94%~95%时分离,体系中大于80%的钾可在这一阶段析出,且湿基中KCl品位可高达约45%;析出钾石盐后的卤水降至室温可获得NaCl、KCl、KCl·MgCl₂·6H₂O及H₃BO₃的混合物,硼的析出率可达到约80%。同时,研究表明,将蒸失水率约80%时分离石盐后的卤水直接降温可以获得湿基品位约高达70%的钾石盐矿,钾析出率约50%。综合对比分析,提出两条以钾资源开发为主的工艺路线:其一为“高温蒸发析氯化钠-高温蒸发析氯化钾-冷却析钾硼混盐”,通过加工获得KCl及H₃BO₃产品;其二为“高温蒸发析氯化钠-冷却析钾”,通过加工获得高端KCl产品。     

卤水中溶解性有机质的光谱学性质和光降解行为研究

卤水中溶解性有机质(dissolved organic matter,DOM)会对盐田日晒工艺和产品质量产生不利影响,如盐田卤水的蒸发速率减缓、蒸发度减小以及提取的矿物产品带有刺鼻的气味、浓重的颜色等。因此,对具有资源开发利用价值的卤水体系中DOM结构和性质的研究可以为后续DOM的有效去除或在DOM共存体系中调控无机盐结晶工艺路线提供有效的指导意见。本文以自然界中广泛存在的两种不同类型的卤水体系,即盐湖卤水DOM(SLDOM)和油田卤水DOM(OFDOM)为研究对象,采用溶解性有机碳(dissolved organic carbon,DOC)分析、光谱学分析和平行因子分析等手段对DOM的含量、分子量分布特征、光谱学结构和光降解行为开展了研究。DOC和荧光分析表明SLDOM和OFDOM的DOC含量和生物指数(BIX)值相似;与OFDOM相比,SLDOM的腐质化指数(HIX)值和高分子量组分(HMW)比例偏高;特别吸收光谱(SUVA₂₅₄)和糖类化合物含量检测结果表明,SLDOM和OFDOM的HMW组分中含有的芳香类和糖类化合物所占比例比低分子量组分(LMW)高;三维荧光谱图分析(EEM)结果表明,SLDOM主要以腐殖质类物质为主,而OFDOM以蛋白质类组分为主。此外,DOM的荧光组分在不同分子量中的分布也存在明显差异:对于SLDOM,富里酸主要分布在HMW DOM中,而腐殖酸主要在LMW DOM中;对于OFDOM,芳香胺类蛋白组分主要分布在HMW DOM中,色氨酸和酪氨酸类蛋白组分主要分布在LMM DOM中。在光降解实验中,SLDOM和OFDOM的DOC含量随光照时间增加而逐渐减少,分别下降了29.32%和15.11%。进一步的分析表明,光照过程中两种卤水中糖类化合物均减少,小分子量的DOM优先分解。此外,在光照过程中SLDOM芳香类化合物增加,腐质化程度基本不变;OFDOM芳香类化合物减少,腐质化程度增加。EEM平行因子分析(PARAFAC)结果表明,SLDOM荧光组分在光降解过程中荧光强度增加,而OFDOM荧光强度减少。     

定量研究雅安地形坡向坡度对降水分布的影响

利用四川省雅安市30 m分辨率基础高程数据,提取栅格的坡向和坡度参数,将雅安307个区域自动站在2017年汛期(6—9月)共50次的降水天气个例,分为16次大尺度降水和34次中小尺度降水,使用对应时次的欧洲中心细网格0.25°×0.25°再分析风场资料,根据不同的站点地形高度将风场合成平均风场,和各站点地形的坡向和坡度计算出其动力抬升作用,同时使用当天日照和天文太阳辐射值来计算地形的热力抬升作用,与对应降水过程的降水分布进行多元线性回归,根据回归的标准系数的大小确定各自变量对降水分布的影响,得出以下结论:(1)中小尺度降水中,地形的热力抬升作用对降水分布的影响作用最大,其次是海拔高度,地形的动力抬升作用在三者中对降水分布的影响最小;(2)在大尺度降水中刚好相反,地形的动力抬升对降水的分布影响作用最大,海拔次之,热力抬升作用在三者中影响作用最小;(3)日降水量最大值的站点海拔高度基本位于1 000 m左右,与抬升凝结高度对应较好;(4)从长期的统计来看,地形的动力作用和地表的植被情况对降水分布的影响最大。在实际预报工作用,根据不同的降水类型,关注不同的动力和热力作用对于判断降水分布大值区的位置有较好的参考作用。     

武汉市汉剧剧场的时空分布特征分析

针对汉剧在文化全球化冲击背景下逐渐失去其影响力的问题,以武汉市为研究区域,汉剧剧场为研究对象,运用地理信息系统的方法对已有文字资料进行数据挖掘和可视化分析,探究近代武汉市汉剧剧场的空间分布规律,分析时空演变等影响因素.结果表明:在研究时段内,武汉市汉剧剧场从数量上呈现增多、减少、再增多的趋势;大革命到抗战胜利时期以及新...     

A Raman investigation on the boron form occurring in salt lake brine during evaporation

Boron resources are abundant in Da Qaidam salt lake of Qaidamu Basin. It has been given great attention for the polyborate species present in brine. In this study, the Raman spectroscopy was applied to investigate the existing-form of boron in brine during evaporation. The prepared solutions of MgO·2B2O3-H2O, MgO·2B2O3-MgCl2 -H2O, and MgO·2B2O3-MgSO4-H2O was also evaporated and recorded to study the influence of boron concentration, pH, and electrolytes on the borate speciation in brine. The mononborates of B(OH)3 and B(OH)4- were found to be the only forms present in the original salt lake brine. Brine evaporation promotes the formation of polyborate anions B3O3(OH)4-, B5O6(OH)4-, and B6O7(OH)62- and also disappearance of the B(OH)4- ion in brine with boron concentration of more than 11 g/L in B2O3. The pentaborate ion of B5O6(OH)4- was sensitive to the solution pH and found to be appeared under the pH value of 8.0. While the hexaborate ion of B6O7(OH)62- was observed more dependent on the electrolyte of magnesium chloride due to its special properties, such as promoting boron accumulation, lowering solution pH, and also the strong af?nity for water molecules, which is beneficial to the polymerization of borate ions in brine. The interaction mechanisms among polyborate anions during evaporation had also been proposed.     

Analyzing Population Density Disparity in China with GIS-automated Regionalization: The Hu Line Revisited

The famous ’Hu Line’, proposed by Hu Huanyong in 1935, divided China into two regions(southeast and northwest) of comparable area size but drastically different in population. However, the classic Hu Line was derived manually in absence of reliable census data and computational technologies of modern days. It has been subject to criticism of lack of scientific rigor and accuracy. This research uses a GIS-automated regionalization method, termed REDCAP(Regionalization with Dynamically Constrained Agglomerative Clustering and Partitioning), to reconstruct the demarcation line based on the 2010 county-level census data in China. The results show that the logarithmic transformation of population density is a better measure of attributive homogeneity in derived regions than density itself, and produces two regions of nearly identical area size and greater contrast in population. Specifically, the revised Hu Line by Hu Huanyong in 1990 had the southeast region with 94.4% of total population and 42.9% of total land, and our delineation line yields a southeast region with 97.4% population and 50.8% land. Therefore, the population density ratio of the two regions is 27.1 by our line, much higher than the ratio of 22.4 by the Hu Line, and thus outperforms the Hu Line in deriving regions of maximum density contrast with comparable area size. Furthermore, more regions are delineated to further advance our understanding of population distribution disparity in China.     

一种高光谱遥感图像快速谱聚类算法

为获得分类效果更优良的遥感图像分类方式并解决高光谱遥感图像分类运算速度缓慢的问题,集成Lanczos算法与谱聚类算法,探讨了高光谱遥感图像谱聚类算法应用于遥感图像分类的可行性,提出了一种面向高光谱遥感图像的快速谱聚类算法;通过对比美国圣地亚哥机场高光谱遥感图像K-均值算法与谱聚类算法的分类结果,发现面向高光谱遥感图像的谱聚类算法易于识别线性地物,且分类的速度能得到较大提升。     

任意阵列形状的欠定多目标方位估计

随着人类社会对海洋认识和探索的深入,对水下监测和探测设备提出了更高的要求,探测阵列模型和阵列信号处理算法决定了监测和探测设备的复杂度。 针对特定水下多目标定位平台的复杂环境,建立了一种任意空间阵列数学模型,介绍了四阶累积量算法,分析了阵列信号处理中四阶累积量的阵列扩展特性。 基于四阶累积量的 MUSIC 算法的空间谱分析,建立了任意阵列形状的欠自由度多目标方位估计的理论基础。 计算机仿真结果表明了算法的正确性和有效性。