粘土-有机树脂超吸水复合材料的制备及性能研究

超吸水材料是一种吸水能力特别强的物质,能够吸收自身重量的几十倍甚至几千倍的水;吸水后,在加压的情况下也不脱水或脱水很少。因此,又称它为高保水材料。由于它既具有独特的吸水和保水性能,又具备高分子材料的优点,从而在国民经济众多领域中获得了广泛的应用［１～３］,从１９６１年美国将其开发应用［３］至今,一直保持着良好的发展势头。本文制备了粘土淀粉接枝丙烯酰胺超吸水复合材料。通过Ｃｅ４＋引发,使淀粉、粘土接枝丙烯酰胺;以Ｎ,Ｎ’亚甲基双丙烯酰胺作为交联剂使接枝物适度交联;交联产物经水解、洗涤、脱水、干…     

Research Progress and Development Tendency About Thermal Physical Properties of Rocks

The fundamental researches about thermal physical properties of rocks have much concern in oil and gas field. They go through four stages and are applied in thermal structure of lithosphere, thermal evolution of sedimentary basins, geotechnical engineering and geothermal area. This article summarized the current research progress on the basis of thermal physical properties of rocks and proposed the development of tendency for the future. Moreover, some cylindrical heat pipe, disc heat pipe, spherical heat pipe based on in-situ measurement method and prediction model based on mathematical statistics have been developed. The scholars discuss the internal relation between thermal conductivity parameter of rocks and other physical properties by a large number of experiments. The researches show that the thermal conductivity of rocks is affected by many factors, and the petrologic characteristic is the most important factor. The porosity of rocks, filled fluid properties, acoustic characteristics are also related to thermal conductivity, which is affected by temperature, pressure and anisotropy. In consideration of the study of thermal physical properties of rocks, we proposed the following tendency for the future. First of all, shale gas is regarded as a hot spot in oil-gas exploration and the formation mechanism and the formation of shale gas reservoir are under the control of thermal physical properties of shale gas, but the relationship among thermal conductivity and organic porous, organic carbon content, gas content, fractured characteristics remains unknown. Therefore, exploring the thermal physical properties of gas-bearing shale is an important research direction in oil and gas field. Secondly, the study of big data represents the general trend. Though the database of rocks thermal parameter is continually expanding, measuring in-situ thermal conductivity continuously in well is the best method to get the accurate in-situ thermal conductivity of rocks. Hence, the development of logging method principle and logging instruments based on thermal physical properties of rocks is a necessary trend for the future.     

汉南地区晋宁晚期铜-金成矿事件的确认及意义

汉南地区位于扬子克拉通北缘西段。目前,在川、陕两省已在该区发现了数十个矿床(点)。其中,广泛分布的铜-金矿床(点)具有热液型矿化特征,成矿条件有利,具有寻找大-中型矿床的远景。为了查明这些铜-金矿产资源的形成时代,文章运用LA-ICP-MS锆石U-Pb法和单矿物~(40)Ar/~(39)Ar法对汉南地区有代表性的矿床(点)进行了成矿年代学研究。其结果显示,潘坝成矿期热液脉的锆石U-Pb年龄为(744±10)Ma,黑云母和钾长石~(40)Ar/~(39)Ar视年龄介于740 Ma~700 Ma之间。元山寺的成矿期白云母~(40)Ar/~(39)Ar坪年龄为(744±4)Ma,等时线年龄为(748±7)Ma。由于本次测试选择了成矿期矿物,其结果可以代表成矿时代。因此,汉南很可能存在晋宁晚期的铜-金成矿事件。根据区域地质演化历史,笔者认为汉南铜-金矿化(744 Ma)是造山晚期加厚岩石圈下部(山根)拆沉的结果。     

湖南慈利晚二叠世海绵礁与珊瑚礁的古生态研究

中国南方晚二叠世生物礁分布广泛，但绝大多数属于海绵礁，湖南慈利晚二叠世除发育有海绵礁外，还有至今为止发现的世界上发育最好的古代珊瑚礁，而且海绵礁与珊瑚礁在同一条带上连续分布；因此是研究海绵礁与珊瑚礁古生态关系十分理想的场所，通过对慈利晚二叠世海绵礁及珊瑚礁内部造礁生物群落、沉积相特征，礁化演化序列及成岩作用特征等的分析和对比来研究它们之间的生态关系，发现其中的海绵礁为台地边缘礁，而珊瑚礁则应属于岸     

汕头中环大厦桩基础持力层及桩型的选用

简述了汕头市３５层,１０３．５ｍ高的中环大厦场址地基土的工程地质特征,重点对地基土的第６层进行了岩土工程分析与计算,并对下卧层的强度和变形进行验算。首次在汕头市东区选用厚度较大,下卧层为中压缩性粘土的第６层,作为百米高层建筑物的桩基础持力层。通过选择和计算,桩基选用预制桩较为经济。沉降观测结果表明,中环大厦的最沉降降量符合有关规范要求。     

吉林西部土地退化成因分析与防治对策

严重的土地退化已经成为制约吉林西部农业可持续发展的障碍。生态 经济 社会复合系统结构失调、功能减弱是导致土地退化的根本原因,是自然因素、经济因素和社会因素综合作用的结果。综合治理本区的生态环境是防治土地退化的前提,调整农业生产结构,合理安排农、林、牧用地比例;集约化利用耕地,加大投入,重点提高中低产田的生产能力;大力开发农村替代能源,解决烧柴问题;加强管理,恢复草原生态,提高牧业的经济效益;控制人口增长速度,提高人口质量;加强法制,用经济手段保障土地质量;使社会效益、生态效益和经济效益协调统一。     

鄂尔多斯盆地下奥陶统碳酸盐岩有机相类型及生烃潜力

对鄂尔多斯盆地下奥陶统马家沟组碳酸盐岩的各种沉积环境的有机相特征进行了研究,结果表明平均有机碳丰度最高的是陆缘斜坡相碳酸盐岩(0.26%),其次是膏盐湖(0.22%)、膏云坪(0.21%),而开阔海、云坪和滩等环境的碳酸盐岩有机碳平均含量较低(<0.20%);碳酸盐岩干酪根样品多数为富氧、贫氢,显示其有机质类型较差;岩石地球化学特征和生物化石特征反映出陆缘斜坡处于相对还原的环境,而其他沉积环境则为氧化环境。鄂尔多斯盆地下奥陶统的大部分碳酸盐岩处于生烃潜力较差的C～D相。从有机质数量、有机相类型来判断,鄂尔多斯盆地下奥陶统碳酸盐岩不是好烃源岩,难以形成具有一定规模的气田。     

Stress distribution characteristic analysis and control of coal and gas outburst disaster in a pressure-relief boundary area in protective layer mining

Coal and gas outburst disasters in coal seams are becoming more serious as coal mines extend deeper underground in China. Furthermore, the protective coal seam mining technology featured by economic efficiency has been proven to be the most effective and widely applied method for the prevention of coal and gas outburst disasters. However, the determinations of the protective area coal and gas outburst prevention in a pressure-relief boundary area are fundamental issues that research should be focused on. The technical method for determining stress distribution in pressure-relief boundary area during protective coal seam mining is put forward in this paper. The method is based on a stress-seepage coupled relationship within a gas-containing coal seam. The method includes complex lab experiments and on-site measurements at the Qingdong Coal Mine. The final data illustrate that the permeability and vertical stress in the pressure-relief boundary area of the coal sample form a negative exponential function relationship. Additionally, the permeability of the coal sample within the abovementioned area is significantly different compared with that located at the center of the pressure-relief area. In the pressure-relief boundary area, the gas pressure distribution gradient is 0.0375 MPa/m, while the vertical stress distribution gradient registers 0.56 MPa/m. Under this condition, coal and gas outburst disasters are prone to be triggered. Therefore, effective precautions against coal and gas outburst disasters can be put forward in accordance with stress distribution characteristics within the abovementioned “boundary area.”     

冻融作用下PPF稳定土力学性能研究

为了研究冻融作用下外加材料稳定土的力学性能,以一种国产土壤固化剂（TG固化剂）加固低剂量水泥石灰稳定土为研究对象,通过冻融前后的无侧限抗压强度试验、劈裂强度试验和抗压回弹模量试验,研究不同压实度、聚丙烯纤维（PPF）掺量稳定土的力学性能。结果表明：稳定土的抗压强度、劈裂强度及回弹模量均随冻融次数的增加而降低,经历6次冻融循环后,强度、模量损失率基本稳定。冻融前后稳定土的抗压强度、劈裂强度、抗压回弹模量以及强度、模量的残留百分比均随着压实度和PPF掺量的提高而增大。结合工程实际情况,选取压实度为95%,0.2% PPF综合稳定土进行冻融试验,得到抗压强度残留比（BDR）达到59.32%,质量变化率仅为6.28%,研究表明,PPF综合稳定土具有优良的冻稳定性,可用作路面基层材料。     

塔河油田二区奥陶系优势储集体特征及控制因素

塔河油田二区奥陶系碳酸盐岩油藏储集体类型由缝洞型、高能微孔隙型、压溶孔缝型组成。通过岩心薄片观察并结合地震、测井、录井和试油等资料,查明了受次生溶蚀作用控制的岩溶缝洞型、受高能沉积相带控制的微孔隙型和受压溶作用及白云化作用控制的压溶孔缝型储层的特征和分布,并且识别出溶蚀孔洞、溶蚀缝、构造缝、粒内孔、粒间孔、铸模孔、晶间孔、晶内孔、缝合线和微裂缝10种储集空间。实际上,上述储集体主要为高能沉积相带形成的颗粒灰岩演化而成,这些颗粒灰岩经过埋藏压实和胶结等作用形成了以次生微孔隙为主的微孔隙型储集体,经过压溶和白云岩化作用形成了受成岩演化控制的压溶孔缝型储集体,在塔北奥陶系岩溶期形成了岩溶缝洞型储集体。塔河油田二区南部受沉积相展布和成岩作用影响,颗粒灰岩和云斑状灰岩发育;北部古隆起风化剥蚀作用较强,发育大型溶洞储层;东部斜坡带古河流发育,溶蚀缝洞储层多沿古河道分布;西部受深大断裂控制,溶蚀孔洞沿断裂垂向发育。