Annual fossil organic carbon delivery due to mechanical and chemical weathering of marly badlands areas

A key issue in the study of the carbon cycle is constraining the stocks and fluxes in and between C‐reservoirs. Among these, the role and importance of fossil organic carbon (FOC) release by weathering of outcropping sedimentary rocks on continental surfaces is still debated and remains poorly constrained. Our work focuses on FOC fluxes due to chemical and mechanical weathering of marls in two experimental watersheds with typical badlands geomorphology (Draix watersheds, Laval and Moulin, Alpes de Haute Provence, France). Organic matter from bedrock, soil litter and riverine particles are characterized by Rock‐Eval 6 pyrolysis. FOC fluxes due to mechanical weathering are then estimated by monitoring the annual particulate solid exports at the outlets of the watersheds (1985–2005 period). FOC fluxes from chemical weathering were calculated using Ca²⁺ concentrations in dissolved loads (year 2002) to assess the amount of FOC released by the dissolution of the carbonate matrix. Results show that FOC delivery is mainly driven by mechanical weathering, with a yield ranging from 30 to 59 t km^‐2 yr^‐1 in the Moulin (0.08 km²) and Laval (0.86 km²) catchments, respectively, (1985–2005 average). The release of FOC attributed to chemical weathering was 2.2 to 4.2 t km^‐2 for the year 2002. These high FOC fluxes from badlands are similar to those observed in tectonically active mountain catchments. At a regional scale, badland outcropping within the Durance watershed does not exceed 0.25% in area of the Rhône catchment, but could annually deliver 12 000 t yr^‐1 of FOC. This flux could correspond to 27% of the total particulate organic carbon (POC) load exported by the Rhône River to the Mediterranean Sea. At a global scale, our findings suggest that erosion of badlands may contribute significantly to the transfer of FOC from continental surfaces to depositional environments. Copyright © 2012 John Wiley & Sons, Ltd.     

Sea Surface Salinity Observations from Space with the SMOS Satellite: A New Means to Monitor the Marine Branch of the Water Cycle

While it is well known that the ocean is one of the most important component of the climate system, with a heat capacity 1,100 times greater than the atmosphere, the ocean is also the primary reservoir for freshwater transport to the atmosphere and largest component of the global water cycle. Two new satellite sensors, the ESA Soil Moisture and Ocean Salinity (SMOS) and the NASA Aquarius SAC-D missions, are now providing the first space-borne measurements of the sea surface salinity (SSS). In this paper, we present examples demonstrating how SMOS-derived SSS data are being used to better characterize key land–ocean and atmosphere–ocean interaction processes that occur within the marine hydrological cycle. In particular, SMOS with its ocean mapping capability provides observations across the world’s largest tropical ocean fresh pool regions, and we discuss from intraseasonal to interannual precipitation impacts as well as large-scale river runoff from the Amazon–Orinoco and Congo rivers and its offshore advection. Synergistic multi-satellite analyses of these new surface salinity data sets combined with sea surface temperature, dynamical height and currents from altimetry, surface wind, ocean color, rainfall estimates, and in situ observations are shown to yield new freshwater budget insight. Finally, SSS observations from the SMOS and Aquarius/SAC-D sensors are combined to examine the response of the upper ocean to tropical cyclone passage including the potential role that a freshwater-induced upper ocean barrier layer may play in modulating surface cooling and enthalpy flux in tropical cyclone track regions.     

Changes in the red giant and dusty environment of the recurrent nova RS Ophiuchi following the 2006 eruption

We present near-infrared spectroscopy of the recurrent nova RS Ophiuchi (RS Oph) obtained on several occasions after its latest outburst in 2006 February. The  1–5 μ  m spectra are dominated by the red giant, but the H  i , He  i and coronal lines present during the eruption are present in all our observations. From the fits of the computed infrared spectral energy distributions to the observed fluxes, we find   T _eff= 4200 ± 200   K for the red giant. The first overtone CO bands at  2.3 μ  m, formed in the atmosphere of the red giant, are variable. The spectra clearly exhibit an infrared excess due to dust emission longward of  5 μ  m; we estimate an effective temperature for the emitting dust shell of 500 K, and find that the dust emission is also variable, being beyond the limit of detection in 2007. Most likely, the secondary star in RS Oph is intrinsically variable.     

Insights into preservation of fossil plant cuticles using thermally assisted hydrolysis methylation

The chemical composition of Cretaceous leaf remains showing exceptionally well preserved cuticles was investigated using pyrolysis gas chromatography–mass spectrometry (Py-GC–MS) and thermally assisted hydrolysis methylation (THM)-GC–MS. Samples of Coniferales (Frenelopsis) and Ginkgoales (Nehvizdya penalveri) leaf remains were collected from freshwater and coastal marine depositional environments. Material for pyrolysis included (i) untreated leaves and cuticles obtained after extraction from mineral rock matrix and bleaching, (ii) kerogen fraction from both materials, (iii) non-hydrolysable fraction from kerogen. The THM-GC–MS data from untreated leaves and bleached cuticles show that the fossil cuticle geopolymer essentially released aliphatic components upon thermal treatment, with a dominance of fatty acids (FAs) and n-alkanes/n-alkenes. The FAs are essentially resistant to bleaching and remain after solvent extraction. They occur mainly as short chain compounds ranging from C₆ to C₁₆ and with maximum abundance at C₈–C₉. The n-alkanes/n-alkenes from kerogen and the non-hydrolysable residue occur mainly as short chain compounds in the range C₁₀–C₁₆, with the highest abundance at C₉–C₁₂. The THM-GC–MS pyrograms of the fossil cuticles differ from those of cutan from fresh living plants. They support the preservation model via polymerization of monomers derived from cutin or from unsaturated cell FAs.     

Global distribution of helium in the upper atmosphere during solar minimum

Helium in the Earth's thermosphere traces the dynamical systems that redistribute energy and mass. Measurements of the global helium distribution in the thermosphere, using Atmosphere Explorer satellite C. (AE-C), show a gradual seasonal change in the number density of helium for all latitudes. The enhancement in helium over the winter pole (the helium bulge) changes in magnitude slowly as seasons progress. The bulge builds and recedes following the progression of winter North to South and back again. This progression of the winter helium enhancement is presented in this paper using latitudinal profiles of helium number density for each month during the year. The absolute magnitude of the winter helium enhancement in the auroral regions is affected by auroral heating at low altitudes. The reduction in the winter helium bulge at low altitudes shown in AE-C data can be traced to this localized heating. The gradual variation in helium concentration measured at many latitudes for all seasons of the year implies that global thermospheric wind systems change gradually with the seasons.     

Magma dynamics, crystallization, and chemical differentiation of the 1959 Kilauea Iki lava lake, Hawaii, revisited

Using constraints from an extensive database of geological and geochemical observations along with results from fluid mechanical studies of convection in magma chambers, we identify the main physical processes at work during the solidification of the 1959 Kilauea Iki lava lakes. In turn, we investigate their quantitative influence on the crystallization and chemical differentiation of the magma, and on the development of the internal structure of the lava lake. In contrast to previous studies, vigorous stirring in the magma, driven predominately by the descent of dense crystal-laden thermal plumes from the roof solidification front and the ascent of buoyant compositional plumes due to the in situ growth of olivine crystals at the floor, is predicted to have been an inevitable consequence of very strong cooling at the roof and floor. The flow is expected to have caused extensive but imperfect mixing over most of the cooling history of the magma, producing minor compositional stratification at the roof and thermal stratification at the floor. The efficient stirring of the large roof cooling is expected to have resulted in significant internal nucleation of olivine crystals, which ultimately settled to the floor. Additional forcing due to either crystal sedimentation or the ascent of gas bubbles is not expected to have increased significantly the amount of mixing. In addition to convection in the magma, circulation driven by the convection of buoyant interstitial melt in highly permeable crystal-melt mushes forming the roof and the floor of the lava lake is envisaged to have produced a net upward flow of evolved magma from the floor during solidification. In the floor zone, mush convection may have caused the formation of axisymmetric chimneys through which evolved magma drained from deep within the floor into the overlying magma and potentially the roof. We hypothesize that the highly evolved, pipe-like ‘vertical olivine-rich bodies’ (VORBs) [Bull. Volcanol. 43 (1980) 675] observed in the floor zone, of the lake are fossil chimneys. In the roof zone, buoyant residual liquid both produced at the roof solidification front and gained from the floor as a result of incomplete convective mixing is envisaged to have percolated or ‘leaked‘ into the overlying highly-permeable cumulate, displacing less buoyant interstitial melt downward. The results from Rayleigh fractionation-type models formulated using boundary conditions based on a quantitative understanding of the convection in the magma indicate that most of the incompatible element variation over the height of the lake can be explained as a consequence of a combination of crystal settling and the extensive but imperfect convective mixing of buoyant residual liquid released from the floor solidification front. The remaining chemical variation is understood in terms of the additional influences of mush convection in the roof and floor on the vertical distribution of incompatible elements. Although cooling was concentrated at the roof of the lake, the floor zone is found to be thicker than the roof zone, implying that it grew more quickly. The large growth rate of the floor is explained as a consequence of a combination of the substantial sedimentation of olivine crystals and more rapid in situ crystallization due to both a higher liquidus temperature and enhanced cooling resulting from imperfect thermal and chemical mixing.     

Paleoproterozoic metamorphism in the northern Fennoscandian Shield: age constraints revealed by monazite

ABSTRACT

We have identified two contrasting styles of Paleoproterozoic metamorphism in the northern part of the Fennoscandian Shield. The Karelia and Lapland-Kola Provinces, comprising Archean and overlying Paleoproterozoic supracrustal rocks, show a typical medium pressure Barrovian-style metamorphism with commonly found kyanite-bearing mineral assemblages and ITD (isothermal decompression) PT paths. In the juxtaposed Svecofennia Province metamorphism represents low pressure-high temperature Buchan style with garnet-cordierite migmatites and intercalated andalusite-cordierite and andalusite-staurolite schists and sillimanite-muscovite gneisses. The retrograde PT paths show only a moderate uplift during cooling.

U-Pb age determinations on monazite were made using the LA-ICP-MS from more than 80 samples from metasedimentary rocks. The sampling covered most parts of the Paleoproterozoic bedrock in Finland. The analyses reveal three peaks at c. 1.91 Ga, 1.86–1.88 Ga and at 1.79–1.81 Ga. The oldest, c. 1.91 Ga monazites are mostly found in the Lapland-Kola Province which is located in the northernmost Finland. In the Karelia Province where the Paleoproterozoic is underlain by Archean bedrock monazite yielded ages of 1.76?1.81 Ga with only a few older exceptions in samples showing a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.92–1.81 Ga. The Karelia Province underwent tectonic thickening, where monazite ages of around 1.80 Ga mostly represent exhumation near the temperature maximum.

In the Svecofennia Province monazite ages vary from c. 1.89 to 1.78 Ga. In the Western Finland Subprovince the monazite ages in high-grade migmatites are mostly 1.86?1.88 Ga but within the older migmatite areas there are lower grade zones where monazite yields ages of c. 1.80 Ga. Some samples also show a spread of ²⁰⁷Pb/²⁰⁶Pb ages from 1.89?1.86 Ga to c. 1.78 Ga. In the Southern Finland Subprovince most ages are either 1.80?1.78 Ga, especially in the andalusite grade schists, or the sample shows a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.88 to 1.78 Ga. Only in the eastern part of the Southern Finland Subprovince there are rocks which yield merely 1.86?1.89 Ga ages. Low pressure-high temperature metamorphism and lack of high or medium P/T rocks in the Svecofennia Province refers rather to accretionary than collisional processes.     

Mapping ethnic diversity in highland Northern Vietnam

In this paper we initially present a critical review of a range of ethnological maps produced over the last 130 years for highland northern Vietnam. In particular we illustrate the many difficulties faced when trying to represent mosaics of ethnic highland minority groups on two dimensional maps. Such historical maps included no attempts to bring topographic details into the picture, an idea that would have been virtually impossible anyway, given the cartographic technologies at the time. Yet by not including such details or not representing them clearly, a partial image of these populations has been created that, over time, has become a standardised representation. Therefore, as a more systematic approach to the analysis of these highland minority groups, we present recent attempts to create more functional maps and models for the northern Vietnam province of Lao Cai, using modern cartographic techniques and geographic information systems. Utilising tools such as digital cartography and digital elevation models a wealth of information can be gained which has the potential, amongst other possible uses, to allow for a greater understanding and sensitivity regarding ethnic minority groups in Northern Vietnam, and their use of the local environment. This revised version was published online in July 2006 with corrections to the Cover Date.     

Sur l'assimilation variationnelle de données par un modèle d'écosystème marin de type NPZ

A variational data assimilation method is applied to a simplified marine ecosystem model of NPZ (Nutrient Phytoplankton Zooplankton) type, which implies five parameters. The method allows us to optimise these parameters by an iterative process of minimisation of a cost function which quantifies the quadratic discrepancy between observations and simulation results. The first part of this note describes how to obtain the adjoint model of the NPZ model allowing us to compute the gradient of the cost function relative to the parameters. Two experiments of artificial data assimilation then show the efficiency of this method, but also its limitations because of non-linearities and sensitivity problems of the model relative to the parameters. To cite this article: Y. Leredde et al., C. R. Geoscience 337 (2005).     

Soil moisture retrievals from biangular L-band passive microwave observations

A simple approach for correcting the effect of vegetation in the estimation of soil moisture (w/sub S/) from L-band passive microwave observations is presented in this study. The approach is based on statistical relationships, calibrated from simulated datasets, which requires only two observations made at distinct incidence angles (/spl theta//sub 1/,/spl theta//sub 2/). A sensitivity study was carried out, and best retrieval remote sensing configurations, in terms of polarization and couple of incidence angles (/spl theta//sub 1/,/spl theta//sub 2/), were investigated. Best estimations of w/sub S/ could be made at H polarization, for /spl theta//sub 1/ varying between 15/spl deg/ and 30/spl deg/, and with a difference (/spl theta//sub 2/-/spl theta//sub 1/) larger than 30/spl deg/. The method was tested against two experimental datasets acquired over crop fields (soybean and wheat). The average accuracy in the soil moisture retrievals during the whole crop cycle was found to be about 0.05 m/sup 3//m/sup 3/ for both crops.