The Quebradagrande Complex: A Lower Cretaceous ensialic marginal basin in the Central Cordillera of the Colombian Andes

The Quebradagrande Complex of Western Colombia consists of volcanic and Albian–Aptian sedimentary rocks of oceanic affinity and outcrops in a highly deformed zone where spatial relationships are difficult to unravel. Berriasian–Aptian sediments that display continental to shallow marine sedimentary facies and mafic and ultramafic plutonic rocks are associated with the Quebradagrande Complex. Geochemically, the basalts and andesites of the Quebradagrande Complex mostly display calc-alkaline affinities, are enriched in large-ion lithophile elements relative to high field strength elements, and thus are typical of volcanic rocks generated in supra-subduction zone mantle wedges. The Quebradagrande Complex parallels the western margin of the Colombian Andes’ Central Cordillera, forming a narrow, discontinuous strip fault-bounded on both sides by metamorphic rocks. The age of the metamorphic rocks east of the Quebradagrande Complex is well established as Neoproterozoic. However, the age of the metamorphics to the west – the Arquía Complex – is poorly constrained; they may have formed during either the Neoproterozoic or Lower Cretaceous. A Neoproterozoic age for the Arquía Complex is favored by both its close proximity to sedimentary rocks mapped as Paleozoic and its intrusion by Triassic plutons. Thus, the Quebradagrande Complex could represent an intracratonic marginal basin produced by spreading-subsidence, where the progressive thinning of the lithosphere generated gradually deeper sedimentary environments, eventually resulting in the generation of oceanic crust. This phenomenon was common in the Peruvian and Chilean Andes during the Uppermost Jurassic and Lower Cretaceous. The marginal basin was trapped during the collision of the Caribbean–Colombian Cretaceous oceanic plateau, which accreted west of the Arquía Complex in the Early Eocene. Differences in the geochemical characteristics of basalts of the oceanic plateau and those of the Quebradagrande Complex indicate these units were generated in very different tectonic settings.     

Copper isotopes as monitors of redox processes in hydrothermal mineralization

The stable copper isotope composition of 79 samples of primary and secondary copper minerals from hydrothermal veins in the Schwarzwald mining district, South Germany, shows a wide variation in δ⁶⁵Cu ranging from −2.92 to 2.41‰. We investigated primary chalcopyrite, various kinds of fahlores and emplectite, as well as supergene native copper, malachite, azurite, cuprite, tenorite, olivenite, pseudomalachite and chrysocolla. Fresh primary Cu(I) ores have at most localities copper isotope ratios (δ⁶⁵Cu values) of 0 ± 0.5‰ despite the fact that the samples come from mineralogically different types of deposits covering an area of about 100 by 50 km and that they formed during three different mineralization events spanning the last 300 Ma. Relics of the primary ores in oxidized samples (i.e., chalcopyrite relics in an iron oxide matrix with an outer malachite coating) display low isotope ratios down to −2.92‰. Secondary Cu(I) minerals such as cuprite have high δ⁶⁵Cu values between 0.4 and 1.65‰, whereas secondary Cu(II) minerals such as malachite show a range of values between −1.55 and 2.41‰, but typically have values above +0.5‰. Within single samples, supergene oxidation of fresh chalcopyrite with a δ value of 0‰ causes significant fractionation on the scale of a centimetre between malachite (up to 1.49‰) and relict chalcopyrite (down to −2.92‰). The results show that—with only two notable exceptions—high-temperature hydrothermal processes did not lead to significant and correlatable variations in copper isotope ratios within a large mining district mineralized over a long period of time. Conversely, low-temperature redox processes seriously affect the copper isotope compositions of hydrothermal copper ores. While details of the redox processes are not yet understood, we interpret the range in compositions found in both primary Cu(I) and secondary Cu(II) minerals as a result of two competing controls on the isotope fractionation process: within-fluid control, i.e., the fractionation during the redox process among dissolved species, and fluid-solid control, i.e., fractionation during precipitation involving reactions between dissolved Cu species and minerals. Additionally, Rayleigh fractionation in a closed system may be responsible for some of the spread in isotope compositions. Our study indicates that copper isotope variations may be used to decipher details of natural redox processes and therefore may have some bearing on exploration, evaluation and exploitation of copper deposits. On the other hand, copper isotope analyses of single archeological artefacts or geological or biological objects cannot be easily used as reliable fingerprint for the source of copper, because the variation caused by redox processes within a single deposit is usually much larger than the inter-deposit variation.     

The diversity of SCUBA-selected galaxies

We present extensive observations of a sample of distant, submillimetre (submm) galaxies detected in the field of the massive cluster lens Abell 1835, using the Submm Common-User Bolometer Array (SCUBA). Taken in conjunction with earlier observations of other submm-selected sources, we now have detailed, multiwavelength observations of seven examples of the submm population, having exploited the combination of achromatic amplification by cluster lenses and lavish archival data sets. These sources, all clearly at z ≳1, illustrate the wide range in the radio and optical properties of distant submm-selected galaxies. We include detailed observations of the first candidate 'pure' starburst submm galaxy at high redshift, a z =2.56 interacting galaxy which shows no obvious sign of hosting an AGN. The remaining sources have varying degrees of inferred AGN activity (three out of seven of the most luminous show some evidence of the presence of an AGN), although even when an AGN is obviously present it is still not apparent whether reprocessed radiation from this source dominates the submm emission. In contrast with the variation in the spectral properties, we see relatively homogeneous morphologies for the population, with a large fraction of merging or interacting systems. Our study shows that virtually identical spectral energy distributions are seen for galaxies that exhibit strikingly different optical/UV spectral-line characteristics. We conclude that standard optical/UV spectral classifications are misleading when applied to distant, highly obscured galaxies, and that we must seek other means of determining the various contributions to the overall energy budget of submm galaxies and hence to the far-infrared extragalactic background.     

Transcrystalline melt migration in clinopyroxene

Glass inclusions in clinopyroxene phenocrysts from La Sommata (Vulcano Island, Aeolian Arc) were reheated and submitted to a sustained thermal gradient. Each remelted inclusion undergoes a transient textural and chemical reequilibration and concomitantly begins to migrate along a crystallographic direction, at a small angle with the thermal gradient. The completion of morphological evolution requires a characteristic time that is governed by chemical diffusion. Chemical reequilibration results in the formation of a colored halo that delineates the former location and shape of the inclusion after it has migrated away. Transcrystalline migration proceeds by dissolution of the host clinopyroxene ahead and precipitation astern. Its rate is not limited by Fick’s law, but by the crystal-melt interface kinetics. Clinopyroxene dissolution and growth are slower than for olivine in similar conditions but obey the same analytical law, which can be transposed to equally or more sluggish melting or crystallization events in nature. When a gas bubble is initially present, it responds to elastic forces by quickly shifting toward the cold end of the inclusion, where it soon becomes engulfed as an isolated fluid inclusion in the reprecipitated crystal. This study confirms that transcrystalline melt migration, beside its possible implications for small-scale melt segregation and fluid-inclusion generation in the Earth’s mantle, provides an experimental access to interfacial kinetic laws in near-equilibrium conditions.     

Near‐surface temperatures and heat balance of bare outcrops exposed to solar radiation

Subsurface temperatures in rocks naturally fluctuate under the influence of local meteorological conditions. These fluctuations play a role in mechanical weathering, thus creating the environmental conditions conducive to natural hazards such as rockfalls and providing important sediment source terms for landscape evolution. However, the physics that control heat penetration into rocks are not fully understood, which makes the underground thermal state difficult to interpret when temperature measurements are available and even more difficult to estimate for unmonitored sites. This is an important lacuna given possible impacts of future climate change on mechanical weathering processes. The natural daily variations of subsurface temperatures were investigated on a bare gneiss outcrop exposed to solar radiation, where temperatures at various depths (up to 50 cm), as well as the solar radiation reaching a pyranometer, were monitored hourly for several months. This detailed times series of thermal data was used to gain insight into the heat balance at the inclined free surface of the rock mass. Attention was focused on two major contributors to the heat balance; the heat flux entering the rock mass through conduction and the incoming shortwave (solar) radiation. A Fourier decomposition of the temperature measurements provided an estimate of the in situ thermal conductivity of the rock and was used to calculate the conductive term. The shortwave radiation term was determined on the basis of the pyranometer measurements adjusted to account for the angle of incidence of the sun. It is shown that, throughout clear‐sky periods, heat exchanges at the surface are mainly controlled by direct solar radiation during the day, and by a roughly constant outgoing heat flux during the night. Subsurface temperatures can be reliably estimated with a semi‐infinite medium model whose boundary condition is derived from an analytical insolation model that takes atmospheric attenuation into account. Copyright © 2011 John Wiley & Sons, Ltd.     

Ecosystem-based marine spatial management: Review of concepts, policies, tools, and critical issues

Conventional sectoral management and piecemeal governance are considered less and less appropriate in pursuit of sustainable development. Ecosystem based marine spatial management (EB-MSM) is an approach that recognizes the full array of interactions within an ecosystem, including human uses, rather than considering single issues, species, or ecosystem services in isolation. Marine spatial planning and ocean zoning are emerging concepts that can support EB-MSM. EB-MSM is driven by high-level goals that managers aim to achieve through the implementation of measures. High-level goals and objectives need to be translated into more operational objectives before specific targets, limits and measures can be elaborated.Monitoring, evaluation and adaptation are necessary to ensure that marine management measures are both effective and efficient. Solid monitoring frameworks are the foundation of adaptive management, as they provide the necessary information to evaluate performance and the effectiveness of management actions. Marine protected areas (MPAs) - possibly set up in networks - constitute a key component in EB-MSM policies and practises and have been applied as a cornerstone in conservation of marine biodiversity, management of fish populations, development of coastal tourism, etc. Moreover, MPA experiences have provided methods and concepts (such as zoning) to a wider EB-MSM context. The assignment of values to biophysical features of the marine environment allows the direct assessment of related management choices and may assist EB-MSM.A range of monetary valuation techniques have been proposed to reduce attributes of goods and services to a single metric. However, in the marine environment such an approach is often over simplistic, and thus less reductive techniques may be necessary. Rather than producing a single metric, the results of non-monetary assessments guide policy allowing weight to be given as necessary to potential areas of conflict and consensus.Strategies to take into account climate change effects and geohazard risks in EB-MSM have been applied or proposed worldwide. EB-MSM regimes must be alert to such risks and flexible to account for changes.     

The April 2010 North African heatwave: when the water vapor greenhouse effect drives nighttime temperatures

Climate Dynamics - North Africa experienced a severe heatwave in April 2010 with daily maximum temperatures ( $$T_{max}$$ ) frequently exceeding $$40\,^{\circ }\mathrm{C}$$ and daily minimum...