海坛岛海域表层沉积物中主量化学成分的地球化学

本文对海坛岛海域３３个表层沉积物中１０种化学成分的含量、含量变化和区域平面分布作了描述和探讨。化学成分中Ｃｏｒｇ、Ｎ、Ｐ、Ｆｅ、ＡＩ、Ｔｉ、Ｍｇ等元素的关性好,和粘土矿物关系密切,从陆源搬运入海;Ｃａ、碳酸盐和上述及粘土含量呈负相关,在富含生物介壳的粗粒沉积中富集;Ｍｎ主要赋存于陆源碎屑,而在砾砂中有自生Ｍｎ沉积。Ｑ型聚类分析的结果表明,调查区可分为３个地球化学分区,综合反映了沉积物的地球化学特征。     

Dynamics of ocean cables with local low-tension regions

A general set of 3-D dynamic field equations for a cable segment is derived based on the classical Euler-Kirchhoff theory of an elastica. The model includes flexural stiffness to remove the potential singularity when cable tension vanishes and can be reduced to the equations for a perfectly flexible cable. A hybrid model and a solution scheme by direct integration are then proposed to solve the oceanic cable/body system with a localized low-tension region. Numerical examples demonstrate the capability and validity of the formulation and the numerical algorithm.     

如何正确理解海洋倾废的定义

我国的海洋倾废管理制度和体系日臻完善,既制定了《海洋环境保护法》等国内海洋法律、法规,又相继批准了《联合国海洋法公约》和加入了《1972伦敦公约》,在原则上与国际公约保持一致。但随着海洋经济的蓬勃发展,海洋倾废活动日益频繁,不断出现新的处置方式,从而导致对海洋倾废的定义有不同的理解,并因此引发了一些争议。文章从法律的角度,结合倾废管理实践,对海洋倾废的定义进行了深入研究。     

海底地震仪广角地震试验

介绍了海底地震仪(OBS)的基本原理、结构和海上调查方法,针对解决东海冲绳海槽地壳结构及性质等目的,利用大容量气枪枪阵震源和海底地震仪在东海冲绳海槽首次开展人工地震深部地球物理探测试验。本次试验布设一条NNW—SSE向垂直构造走向的勘测线,共投放海底地震仪40台,回收成功36台。获得了有效的深部地震数据,可识别到Pg、PmP、Pn等多种震相。此次试验是我国在冲绳海槽深部探测中的成功示范,有效填补了该地区深部地震数据的空白,为解决冲绳海槽深部地质问题奠定了坚实的基础。     

利用综合评分方法评估CMIP5模式对北极海冰的模拟能力

北极海冰冰盖自20世纪以来经历了前所未有的缩减,这使得北极海冰异常对大气环流的反馈作用日益显现。尽管目前的气候模式模拟北极海冰均为减少的趋势,但各模式间仍然存在较大的分散性。为了评估模式对于北极海冰变化及其气候效应的模拟能力,我们将海冰线性趋势和年际异常两者结合起来构造了一种合理的衡量指标。我们还强调巴伦支与卡拉海的重要性,因为前人研究证明此区域海冰异常是近年来影响大尺度大气环流变异的关键因子。根据我们设定的标准,CMIP5模式对海冰的模拟可被归为三种类型。这三组多模式集合平均之间存在巨大的差异,验证了这种分组方法的合理性。此外,我们还进一步探讨了造成模式海冰模拟能力差别的潜在物理因子。结果表明模式所采用的臭氧资料集对海冰模拟能力有显著的影响。     

中国近海生态环境变化的同位素示踪研究

同位素在确定物质来源、指示生物地球化学循环路径、定量生物地球化学过程速率等方面具有独特的优势,本文以近海生态环境变化研究中常用的稳定同位素（13C、15N、18O）和放射性核素（14C、234Th、232Th、230Th、228Th、210Po、210Pb、137Cs、226Ra、228Ra、224Ra、223Ra）为对象,介绍它们在揭示海洋有机质来源、食物网结构、水体缺氧机制、氮循环过程、颗粒动力学、海底地下水输入、有机地球化学过程、沉积年代学等方面的应用,侧重于总结我国近海生态环境研究中同位素示踪取得的进展。伴随着我国经济的发展,近百年来我国近海生态环境也发生了明显的变化,基于同位素示踪揭示的近海富营养化和沉积环境的演变规律表明,我国近海生态环境自20世纪50年代起经历持续的变化,特别是在过去20~30年时间里,近海生态环境的变化尤为剧烈,反映出人类活动是我国近海生态环境变化的主要驱动力。未来需要通过发展新的同位素技术及拓展更广泛的应用,围绕近海海洋生态环境变化的突出问题,重点揭示近海生态环境变化的响应特征、变化速率和作用机制,从而系统地掌握近海生态环境的时空变化规律。     

雅浦海沟南缘铁锰结核矿物与地球化学特征及其成因研究

本文采用X射线衍射、全岩地球化学和电子探针等测试方法,对雅浦海沟南部附近海域获得的铁锰结核样品进行了显微构造、矿物和地球化学分析,并探讨了其成因。结果表明:铁锰结核的显微构造主要包括平行纹层构造、柱状构造、叠层状构造和同心环状构造;显微构造和探针结果显示铁锰结核在生长初期处于底部海洋动力比较强烈的环境,后期生长环境逐渐趋于稳定;铁锰结核的矿物组分以水羟锰矿、钠水锰矿、石英和钙十字石为主;样品中Fe、Mn元素含量较高且含量比较接近,Cu、Co、Ni和REE相对富集,REE分布模式整体比较平缓并都出现较强的Ce正异常和重稀土元素亏损现象;文中两块铁锰结核都为水成成因,成矿物质主要来自同期的海水沉淀,同时也受一定海底火山物质和陆源风尘物质的影响。     

Authigenic iron oxide formation in the estuarine mixing zone of the Yangtze River

Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.     

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.     

南海沉积物细菌胞外蛋白酶在家族水平上的多样性

海洋产蛋白酶细菌及其分泌的胞外蛋白酶在降解有机氮以推动海洋氮循环进行方面发挥着重要作用,但目前对这二者多样性的认识非常有限。本研究自南海沉积物中筛选得到90株产蛋白酶细菌,并通过N-端氨基酸序列,分析了其胞外蛋白酶在家族水平上的多样性。16S rRNA基因序列分析的结果表明,筛选的产蛋白酶细菌均属于Gammaproteobacteria纲,且大多数属于Alteromonadales目和Vibrionales目的不同属。对其中14株菌株的14个胞外蛋白酶的N-端氨基酸序列分析表明,所有这些蛋白酶属于金属蛋白酶的M4家族或丝氨酸蛋白酶的S8家族。本研究提供了海洋沉积物产蛋白酶细菌在类群及其胞外蛋白酶在类型上的新细节,这将有助于全面了解微生物酶促降解海洋沉积物有机氮的过程和机理。