塞曼石墨炉原子吸收法直接测定海水中的铬

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。     

浅谈涉外海事仲裁协议的认定

仲裁亦称公断，是指争议的当事人在自愿的基础上，将争议提交非司法机构的第三者审理，并做出对争议各方有约束力裁决的一种解决争议的法律制度。以私法方面带有国际因素或涉外因素的争议为对象进行的仲裁，通常称为国际商事仲裁。其在狭义上不同于解决国家之间某一公法上的争端的国际仲裁、不同于为解决国家与企业或私人实体间争议所进行的跨国仲裁、也不同于解决一国范围内自然人、法人和其他组织之间争议包括行政仲裁在内的国内仲裁：广义上国际商事仲裁还包括跨国仲裁。国际商事仲裁主要包括国际贸易和国际海事仲裁。本文仅在狭义上讨论。按照我国现行法律规定，本文称涉外海事仲裁。     

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

Instrumentation and Numerical Analysis of Cylindrical Diaphragm Wall Movement During Deep Excavation at Coastal Area

The lateral deflection of a cylindrical diaphragm wall and the associated ground movement induced by deep excavation are analyzed by performing site instrumentations and numerical analyses in the coastal area of Korea. Wall lateral deflection, rebar stress, and pore water pressure were measured and analyzed in eight directions. Variations of soil properties with the decrease of confining pressure are compared by performing various in situ tests before ad after excavation. To calculate the wall lateral deflection accurately, the effects of small strain nonlinearity, confining pressure, and the hysteresis loading/unloading loop developed during excavation are considered in the proposed numerical analysis. By comparing numerical results with measured ones, the importances of considering small strain nonlinearity and confining pressure reduction in the nonlinear (FEM) are emphasized. Also, the effects of wall stiffness on the performance of cylindrical diaphragm walls are studied for future similar excavation in the coastal area.     

Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea

Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10^?4 m s^?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10^?4 m s^?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10^?6 m s^?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.     

第二次土地调查若干问题探讨

第二次土地调查的目的是全面查清全国土地利用状况,掌握真实的土地基础数据,如何保证调查的质量?文章以江阴市为例进行探讨。     

The contact binary system YY Eri

Relatively new and unanalysed photometric data-sets of the contact binary system YY Eri are presented. The light curves have been analysed using information limit optimization techniques, and the Binary Maker program of Bradstreet (1992).Comparison of the results allows insight into determinacy questions affecting the W UMa type of light curve, which relates to our general understanding of contact binaries. A limiting contact configuration cannot be ruled out on the basis of empirical data-analysis alone.Very careful analysis of the photospheric flux distribution over the surface of the Sun may help establish appropriate values of the gravity brightening parameter for cool dwarf stars. At present, however, empirical photometric information on contact binaries is non-discriminatory: i.e. alternative cosmogonies can find alternative support from available evidence. The implication is then for more and better observational data to allow better real independent parameter determination.     

On matching the spectrum of Io: Variations in the photometric properties of sulfur-containing mixtures

The problem of comparing laboratory spectra of sulfur-containing binary mixtures with the spectrum of Io is discussed. For the satellite, the observable is the geometric albedo as a function of wavelength, whereas in the laboratory one often measures some other type of albedo. In a previous paper we demonstrated that for pure sulfur the multiplicative factor which converts the laboratory albedos to geometric albedos can be strongly wavelength dependent. The present paper demonstrates that this is also true for binary sulfur-containing mixtures. Furthermore, there is no universal conversion factor applicable to all binary mixtures, nor can the factor be interpolated for a particular mixture from the conversion factors of the two end members. The conversion factor is a function not only of the specific composition of a binary mixture, but of the relative particle size distributions of the two components, and must be measured specifically for each individual sample if a quantitative comparison between a laboratory sample and Io's surface is desired.     

Genesis of monazite and Y zoning in garnet from the Black Hills, South Dakota

The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.