环氧树脂/沸石纳米复合材料的制备及表征

提出了一种用原位插入法制取环氧树脂/沸石纳米复合材料的新方法, 详细探讨了钠化、有机化、环氧树脂插入、固化及制备环氧树脂/沸石纳米复合材料的条件, 在实验的基础上确定了最佳条件, 制成了纳米复合材料, 并用XRD和TEM对其结构进行了表征, 发现纳米复合材料的平均粒径在5 0~ 6 0nm之间, 同时力学性能有明显提高, 可用于高性能的工程塑料和高品质的粘合剂.      

内蒙古孟恩陶勒盖银多金属矿床及其附近侵入岩的年代学

孟恩陶勒盖是内蒙古东部地区的一处大型银多金属矿床,铅锌银矿体呈脉状产出,受东西向断裂控制。对孟恩陶勒盖矿区及其外围主要侵入岩体开展了年代学和地球化学研究。LA-MC-ICP-MS锆石测年结果表明：孟恩陶勒盖岩基中黑云母斜长花岗岩的锆石年龄为（240.5±1.2） Ma,MSWD=0.48;白云母斜长花岗岩的锆石年龄为（234.3±3.2） Ma,MSWD=0.21;矿区外围杜尔基岩基中的黑云母正长花岗岩的锆石年龄为（154.5±0.5） Ma,MSWD=0.41;矿区外围的安山玢岩的锆石年龄为（127.5±0.7） Ma,MSWD=1.3;分别代表了中三叠世、晚侏罗世和早白垩世的3期岩浆活动。岩石地球化学分析结果表明：孟恩陶勒盖岩基的黑云母斜长花岗岩和白云母斜长花岗岩与杜尔基岩体的黑云母正长花岗岩均为富SiO₂、富碱、准铝的钙碱性岩石,具有轻稀土分异明显、富集大离子亲石元素（LILE）为特征,其中Ba、Nb、La、Sr、P、Ti相对亏损,而Rb、Th、K、Ta、Ce、Nd、Hf、Sm、Y 和Yb相对富集。岩体年代学和岩石地球化学特征表明,孟恩陶勒盖岩基和杜尔基岩基分别形成于印支期的碰撞造山和燕山期的伸展构造环境。根据获得的侵入岩的测年数据与前人获得的孟恩陶勒盖银铅锌矿与成矿有关的蚀变白云母的Ar-Ar年龄(179. 0士1. 5) Ma对比显示,这些侵入岩的侵位年龄与成矿年龄之间差别较大,说明这些岩体不太可能是孟恩陶勒盖银铅锌矿床的成矿母岩。成矿岩体可能在深部尚未出露,或者已被杜尔基岩体改造。     

造山带中增生楔识别与地质意义

增生楔主要由海沟复理石、远洋—半远洋沉积和洋岛/海山等大洋板块地层岩石及蛇绿岩共同构成,是汇聚板块边缘古俯冲带构造—沉积作用的综合产物,以发育叠瓦状逆冲断层、双冲断层和紧闭—倒转褶皱,以及片理、碎裂构造、小型褶皱、膝折等不同尺度的构造为特征。增生楔组成包括连续单元和混杂岩两部分,严格受滑脱面位置控制。增生楔是增生型造山带最基本大地构造相,它与弧前盆地、岛弧/大陆边缘弧的时空配置关系可直接指示大洋板块俯冲极性、揭示洋盆演化与造山作用方式。准确识别增生楔,详细解剖其结构特征与组成特征,综合判别并恢复大洋板块地层,可为古板块边界与古大洋盆地消亡位置确定、造山带结构精细划分及造山作用过程重建提供基本依据。大比例尺地质填图是研究增生楔结构和组成、以及大洋板块地层重建的有效手段。以南祁连拉脊山石灰窑增生楔为例,地质填图结果表明它是由中寒武世—早奥陶世洋壳物质构成,自北而南依次可分为海沟—大洋盆地—海山OPS和六道沟SSZ型蛇绿岩,被南倾逆冲断层分割成多个岩片。海沟—大洋盆地OPS岩片基本保留完整地层序列,海山OPS岩片包括连续单元和混杂岩两部分。顶帽山增生楔主要由海山OPS构成,内部结构层序相对完好,是南祁连构造带中保留最为完整、规模最大的海山OPS岩石组合序列。上述不同类型OPS片段和六道沟SSZ型蛇绿岩组成的增生楔与其南侧岛弧带同时代。增生楔—岩浆弧的时空配置暗示寒武纪—早奥陶世时期原特提斯洋自北向南俯冲极性。这些认识为南祁连早古生代火山—岩浆—沉积构造演化以及是否存在古洋盆与古洋盆演化重建提供基本佐证。     

云南鲁甸6.5级地震灾害特点浅析

通过对2014年8月3日云南鲁甸6.5级地震震害开展实地调查,对灾区破坏情况进行总体介绍,并就各烈度区特征和建筑物震害、地震地质灾害、工程结构震害进行分析,初步得出本次地震的一些震害特点.一是灾区人口密度大,人员死亡较集中.人员死亡主要集中在Ⅷ和Ⅸ度区.二是地震振动强,灾区破坏严重.本次地震震源深度12km,极震区烈度高达Ⅸ度,震源破裂在11s内集中释放.三是抗震能力弱,房屋破坏严重.灾区属国家级贫困区,农村民居抗震能力弱,且多数民房坐落在河谷陡坡上,边坡效应加重房屋震害,重灾区砖木和土木房屋成片损毁、倒塌.四是灾区条件恶劣,救灾难度大.震区活动断裂密集发育、地质破碎疏松、地形崎岖不平,又恰值雨季,诱发极其严重次生地质灾害,导致人员伤亡,造成灾区大面积交通、通信、电力中断,救援物资与救援力量无法及时发挥作用.     

大气臭氧与气溶胶垂直分布的高空气球探测

本文给出了1993年9月12日利用高空科学气球在河北省香河地区探测到的大气臭氧和气溶胶的垂直分布。结果发现:(1) 大气臭氧的数密度在整个对流层较低(～10[12]mol/cm3)，并从地面到对流层顶略有下降；对流层顶以上开始快速增加，极值层高度在～24 km，其值为4.78×10[12]mol/cm3；臭氧分压有类似的分布特征，极值146×10[-4]Pa，位于同一高度；(2) 在平流层低层，臭氧分压有一个次极值62×10[-4]Pa，位于15～16 km；(3) 0～30 km大气气溶胶数密度呈现出三个峰值:143，8和1.1 个/cm[3]，分别位于近地面、5 km和21 km；（4）气溶胶的数密度谱在对流层为双模态；在平流层，次峰消失。同时，我们还与其他观测结果作了比较分析。     

基于CMIP5模式的中国气候变化敏感性预估与分析

以CMIP5提供的26个全球气候系统模式的温度和降水数据为基础,采用区域气候变化指数(Regional Climate Change Index,RCCI)分析中国的不同区域对21世纪气候变化响应的敏感性。结果表明,三种排放情景(RCP 2.6、RCP 4.5、RCP 8.5)下,21世纪全期,气候变化最敏感的区域分布在西藏地区,其次为我国西北地区以及东北地区,气候变化敏感性最低的区域分布在我国内蒙古中东部、华北地区以及长江中下游一带,且高排放情景对应更高的气候变化敏感性。对RCCI指数贡献因子分析结果表明,对中国气候变化敏感性贡献的大小依次为Δσ_TΔσ_pΔRRWAF。冬夏两季温度变化的大值区与RCCI指数的大致区分布一致,RCCI大小的分布很大程度上由温度变化的敏感性决定。而夏季降水变化的大值区主要出现在西藏地区、华南地区和东北地区,冬季降水变化的大值区则主要出现在黄河以南长江以北的中原地区以及东北地区。     

Environmental anomalies in the northeastern East China Sea during the last 3 000 years: implications for El Niño activity in the Holocene

To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea (ECS), biogenic compounds (such as carbonate, organic carbon and opal), marine micropaleontological fossils (planktonic foraminifera, benthic foraminifera, radiolarian and silicoflagellate) and the compositional characters of benthic foraminifera fauna analyses were carried out on a sediment core DOC082 obtained from the western slope of Okinawa Trough (29°13.93′N, 128°08.53′E; 1 128 m water depth). The long-term changes of biogenic and micropaleontological proxies display some similarities through the last 10 500 a, which show three different phases: lower values are recorded during the early and middle Holocene (before about 4 000 a BP), followed by an abrupt and remarkable increase at about 4 000 a BP, the late Holocene (after about 3 000 a BP) is characterized by continuously high values. The multi-proxy data of paleoproductivity and percents of benthic foraminifera genera (Uvigerina and Bulimina) show that during the early and middle Holocene (10 500–4 000 a BP) productivity was relatively low with a sudden and distinct increase at about 4 000 a BP, and the late Holocene (3 400–0 a BP) is marked by significantly higher productivity. Also, the radiolarian-based sea surface temperature (SST) records reveal a distinct decline in SST in the late Holocene after 3 200 a BP, very different from the early and middle Holocene. For the last 3 000 a, the enhanced biological productivity and distinctly lower SST indicate a major change of oceanographic conditions in the northeastern ECS. These marine environmental anomalies are consistent with other paleoclimatic records for the late Holocene in the Chinese continent and its surrounding regions. After analyzing the mechanisms of modern productivity and SST changes in the northeastern ECS, and based on the climatic anomalies in the Chinese continent and variations in the Kuroshio Current during modern El Niño periods, we suggest that the anomalous environmental conditions in the northeastern ECS may imply intensified El Niño activity during the late Holocene.     

Carbon pools and fluxes in the China Seas and adjacent oceans

The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km~2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr~(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr~(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr~(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr~(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr~(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr~(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr~(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr~(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr~(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr~(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr~(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr~(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr~(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr~(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.     

顾及空间尺度效应的城市土地利用变化精细化模拟

城市土地利用变化模拟是优化土地资源配置的科学依据,提高其精细化程度和可靠性有助于准确把握城市用地发展趋势,对城市土地资源精准调控具有重要意义。基于宏观遥感分类的土地利用变化模拟,难以在街区尺度上揭示城市用地社会功能变化及精细化模拟中空间尺度效应来源和作用机理。本文联合遥感影像和POI数据识别出城市土地利用精细化特征,运用响应面法率定土地利用精细化模拟的最优空间尺度组合,在此基础上,利用CA-Markov模型开展了未来土地利用变化的精细化模拟。以武汉市中心城区为应用案例,研究结果表明：基于POI 的城市土地利用精细化识别方法,可以深度解析城市建设用地的社会功能,极大改善了传统基于遥感的土地覆被宏观解译效果;研究区土地利用变化元胞自动机精细化模拟的最优空间尺度组合是30 m元胞、7×7邻域以及冯诺依曼邻域类型,采用最优空间尺度组合能够提高土地利用变化精细化模拟的可靠性。响应面试验设计结果可有效识别精细化模拟过程中空间尺度效应的主要来源,并区分其对模拟精度的影响程度与正负效应;预计到2025年,研究区建设用地范围将继续向周边扩张,各类型用地之间互为交织,土地利用空间格局将呈更加破碎化趋势。     

Distribution and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments from Zhanjiang Bay and Leizhou Bay, South China

The concentrations and spatial distribution of polycyclic aromatic hydrocarbons have been investigated in two adjacent bays of Zhanjiang and Leizhou, China. The total concentrations of the 16 USEPA priority PAHs were ranged from 41.96 to 933.90ng/g dry weight with an average concentration of 315.98ng/g and ranged from 21.72 to 319.61ng/g with an average concentration of 103.91ng/g in Zhanjiang and Leizhou Bays, respectively. The spatial distribution of PAHs was site-specific and appeared to be somewhat positively correlated with TOC and negatively correlated with sediment grain size in the two bays. The values of Phe/Ant, BaA/228 and InP/276 were higher than 10, less than 0.2, and from 0.2 to 0.5, respectively, indicating that the sources of PAHs in the two bays were mainly from petroleum and its combustion, which predominantly originated from those ships and boats coming and going in the two bays.