Heat capacity,compressibility and thermal expansion coefficient of ilmenite-type MgGeO3

The accuracy of differential scanning calorimetry (DSC) on a heat capacity measurement was evaluated using MgO. The result indicated that the deviation of the result in comparison to literature values was less than 0.4% at temperatures above 300 K and 2.1% below this temperature. Since this experiment proved the reliability of DSC, heat capacity, compressibility, and thermal expansion of ilmenite-type MgGeO₃ were measured by means of DSC, a diamond anvil high pressure device, and a high-temperature X-ray camera, respectively. The heat capacity was approximated by C _p = a + b·T + c·T ^?2 at high temperatures and by the Debye function at low temperatures. The compressibility was well-represented by the Murnaghan-Birch equation of 2nd order. The thermal expansion coefficient was constant up to 1073 K.     

The Influence of Testing Procedures on Uniaxial Compressive Strength Prediction of Carbonate Rocks from Equotip Hardness Tester (EHT) and Proposal of a New Testing Methodology: Hybrid Dynamic Hardness (HDH)

The Equotip hardness tester (EHT) is a portable and non-destructive instrument used mainly for the dynamic rebound hardness testing of metals. Although various versions of the ‘single impacts’ and ‘repeated impacts’ testing procedures have been employed by different authors for different applications, it is not yet known whether a particular testing procedure is more relevant for a specific application in rock engineering. To be able to contribute to the subject, the present study was carried out to determine the suitability of different rebound testing procedures with this instrument for uniaxial compressive strength (UCS) estimations of some selected carbonate rocks. To achieve this goal, as well as four different existing rebound testing procedures, a newly proposed testing methodology involving the parameter hybrid dynamic hardness (HDH) was also employed. The statistical analyses performed on the experimental data, on the whole, showed that the test procedures which are based on single impacts test procedures outperformed the repeated impacts test procedures in terms of UCS prediction accuracy. The prediction capability of the newly introduced testing methodology was found to be superior to those of other procedures considered in this work, suggesting that it could be an efficient tool in practice for preliminary estimates of rock strength. The statistical analyses also indicated that, in practical applications of the EHT using different test procedures, it may be possible to predict the UCS more accurately when apparent density data is available. For the range of specimen sizes considered, no clear evidence of size effect was observed in the mean rebound values. The argument raised by some other authors that the EHT might not be a convenient instrument for the dynamic rebound hardness determination of relatively high-porosity rocks was not confirmed in this study.     

The effect of biological soil crusts of different successional stages and conditions on the germination of seeds of three desert plants

Biological soil crusts greatly affect soil surface properties, which, in turn, may alter seed germination of vascular plants. We investigated the effects of two types of biological soil crusts (moss crust and algal crust) at different ages on the seed germination of Bassia dasyphylla and Artemisia ordosica. We also investigated the effects of crust conditions (living crust and dead crust) on seed germination of B. dasyphylla, A. ordosica and Eragrostis poaeoides. The presence of both algal and moss crusts significantly enhanced the germination of B. dasyphylla and A. ordosica compared with uncrusted soil. Crust age had no significant effect on the germination of either B. dasyphylla or A. ordosica for both moss and algal crusts. Germination of B. dasyphylla differed significantly between moss and algal crusts, but germination of both A. ordosica and E. poaeoides did not. Germination of A. ordosica, E. poaeoides and B. dasyphylla was significantly higher on living algal crust than on dead crust and uncrusted soil, while living moss crust enhanced the germination of both A. ordosica and B. dasyphylla but had no significant effect on E. poaeoides.     

Halite oolites and ripples in the Dead Sea, Israel

Clastic features in recent halite deposits are observed along the beaches of an artificially dammed part of the Dead Sea. These features include halite oolites (termed halolites in this paper) and ripples. Halite precipitates initially either at the brine surface or on the floor. It is suggested that moderate increase of wave agitation shifts the balance towards brine-surface crystallization, and keeps the growing halite grains in constant motion. In this way rippled structures are formed. A further increase of wave energy leads to the growth of coated halite grains. The accumulation of the various halite grains along the beach, to form soft rippled floor and oolitic beach ridge is brought about during shoreward winds. During calm periods the bulk of the halite crystallizes directly on the floor. It develops into a hard crust which assumes the morphology of the substrate, including the ripple forms.     

Reconstruction of sea surface dimethylsulfide in the North Pacific during 1970s to 2000s

We proposed an empirical equation of sea surface dimethylsulfide (DMS, nM) using sea surface temperature (SST, K), sea surface nitrate (SSN, μM) and latitude (L, °N) to reconstruct the sea surface flux of DMS over the North Pacific between 25°N and 55°N: ln DMS = 0.06346 · SST − 0.1210 · SSN − 14.11 · cos(L) − 6.278 (R² = 0.63, p < 0.0001). Applying our algorithm to climatological hydrographic data in the North Pacific, we reconstructed the climatological distributions of DMS and its flux between 25 °N and 55 °N. DMS generally increased eastward and northward, and DMS in the northeastern region became to 2–5 times as large as that in the southwestern region. DMS in the later half of the year was 2–4 times as large as that in the first half of the year. Moreover, applying our algorithm to hydrographic time series datasets in the western North Pacific from 1971 to 2000, we found that DMS in the last three decades has shown linear increasing trends of 0.03 ± 0.01 nM year^− 1 in the subpolar region, and 0.01 ± 0.001 nM year^− 1 in the subtropical region, indicating that the annual flux of DMS from sea to air has increased by 1.9–4.8 μmol m^− 2 year^− 1. The linear increase was consistent with the annual rate of increase of 1% of the climatological averaged flux in the western North Pacific in the last three decades.     

Algorithm for non-hydrostatic dynamics in the Regional Oceanic Modeling System

A non-hydrostatic algorithm for the Regional Oceanic Modeling System (ROMS) is proposed. It is based on a decomposition technique for hydrostatic and non-hydrostatic pressure. The algorithm has a pressure-correction scheme with split-explicit time-stepping for baroclinic and barotropic vertical modes with a free surface. The algorithm implementation requires solving a Poisson equation for a non-hydrostatic pressure that has a non-symmetric matrix in discrete form. The efficiency of a different class of solvers and preconditioners were tested. The algorithm is successfully implemented with several examples where non-hydrostatic effects are important. These include standing external gravity waves; strongly nonlinear internal wave generation and transformation; stratified shear instability and its associated mixing; and nonlinear internal tidal generation over a ridge. The corresponding changes in the pre-processing and post-processing infrastructure in the existing hydrostatic ROMS code were performed to implement parallel elliptic solvers and a new set of dynamical equations.     

Professionalization of the shipping industry via postgraduate education

The paper investigates the roles and nature of postgraduate education on the professionalization of the shipping industry. The recent growth of postgraduate education is marked by the massive expansion of professional programmes on disciplines which traditionally emphasized non-academic, apprentice-style learning approach, including shipping business and management. The reasons behind such growth of demands, however, have remained scarce and empirically under-researched. Understanding this deficiency, in this study, we have undertaken a questionnaire survey completed by students/graduates who are pursuing/have recently pursued masters' programmes in shipping-related business and management offered by six Asian and European universities. Specifically, we analyze student motivations, considerations, and sources of information before enrolling such programmes, the extent that the shipping industry or other forces act as driving forces towards such enrollment, as well as students' evaluation of the postgraduate programmes that they are pursing/have pursued. Integrated in these discussions are comparative analyses of the data provided by different student groups based on their professional experiences and cultural backgrounds. We believe that this study has provided the lacking empirical inputs essential for achieving the sustainable development of postgraduate education in shipping business and management.     

Transfer of60Co from midwater squid to sperm whales

Sperm whales are notable squid-eaters. They feed mainly on medium to large-sized cephalopods at midwater levels and defecate near the surface. This suggests the existence of an upward transport of⁶⁰Co by sperm whales from the mesopelagic zone (150–1,200 m). To elucidate this squid-whale route for this artificial radionuclide,⁶⁰Co content was determined in squid and in predator whales captured by commercial whaling. In the Cephalopoda livers⁶⁰Co levels of 30–500 mBq kg^–1 wet were found and in the viscera of Odontoceti (toothed whales) 15–40 mBq kg^–1 wet. About 0.3% of⁸⁰Co ingested was estimated to be retained in a 23-year-old male sperm whale. In the livers of Bryde's whales,⁶⁰Co levels of 40–80 mBq kg^–1 wet were detected, but not in euphausiids and sardines, their possible prey. The level of Co in sperm whales was nearly the same as in Bryde's whales. Specific radioactivity⁶⁰Co/⁵⁹Co in mBq µg^–1 was several times higher in sperm whale (1.1–1.6) than in cephalopods (0.19–0.77). Eating prey with a high content of⁶⁰Co in the 1960's may have contributed to the present body burden in sperm whales with a long-life span. However, the origin of⁶⁰Co in Bryde's whales is unknown.