Slope stability evaluation using Back Propagation Neural Networks

The Yudonghe landslide, located in western Hubei Province of China, consists of eastern and western subunits as well as a main landslide mass with upper and lower slip surfaces. As an important landslide close to Shuibuya Dam on the Qing River, its stability is crucial, as the slide might reactivate because of a change in ground-water level caused by filling of the Shuibuya Reservoir. Existing weakness zones, growth of ruptures, the downslope attitude of geologic strata, and water infiltration, which reduced the strength of rocks and soils, have been found to be the most important factors contributing to the Yudonghe landslide. With regard to the landslide processes, it can be noted that the original large-scale slide activity was due to erosion by the Qing River, the second sliding resulted from the fall of blocks from the head scarp, and the final activity was the growth of the eastern and western secondary slides. A base failure was the main type of slope movement, however, it was obvious that more than one sliding event occurred, as inferred from striations and fractures detected by microstructure analysis of soils along the failure surfaces. Slope instability was evaluated by the method of Back Propagation Neural Networks (BPNN), in which a four-layer BPNN model with five input nodes, two hidden layers, and two output nodes was constructed using a training data set of landslide samples throughout the Qing River area. The predicted results of this analysis showed that the factor of safety was 1.10, which indicates that the Yudonghe landslide is currently in a marginally stable condition.     

Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation

The iron stable isotope compositions (δ⁵⁶Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe³⁺/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ⁵⁶Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ⁵⁶Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ⁵⁶Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe³⁺/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe³⁺/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe³⁺/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ⁵⁶Fe values and Fe³⁺/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ²⁶Mg_{omphacite‐garnet} values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe³⁺/ΣFe ratios of omphacite from retrograde eclogites and variant Δ⁵⁶Fe_{omphacite‐garnet} values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ⁵⁶Fe values of omphacite during retrograde metamorphism.     

Preparation of iron phosphate from sludge sourced from the electrocoagulation treatment of source-separated urine

In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H₂O₂ and Na₃PO₄; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO₄. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.     

The kinetic studies of the cobalt ion removal from aqueous solutions by dolomite-based sorbent

The kinetics of Co(II) ions adsorption on thermally activated dolomite was studied with respect to the calcination temperature of natural dolomite. The sorption of Co(II) onto all samples is reasonably fast: The first 30–35 min accounts for approximately 70–80 % of Co(II) removal from feed solutions. In order to select the main rate-determining step in the overall uptake mechanism, a series of experiments were performed and data obtained were interpreted in terms of film diffusion control, intraparticle diffusion, pseudo-first-order and pseudo-second-order models. From the modeling of kinetic data, it can be concluded that adsorption of Co(II) ions from aqueous solution by heat-treated dolomite is a complex phenomenon and occurs in a mixed diffusion mode—the kinetic data are well described by the pseudo-second-order equation. The possible multistage sorption mechanism involving film diffusion and intraparticle diffusion control steps as well as chemical interaction between Co(II) ions and calcined dolomite is proposed.     

Sedimentary facies analysis and depositional model of gravity-flow deposits of the Yanchang Formation,southwestern Ordos Basin,NW China

During the deposition of the Chang-7 (Ch-7) and Chang-6 (Ch-6) units in the Upper Triassic, gravity flows were developed widely in a deep lake in the southwestern Ordos Basin, China. Based on cores, outcrops, well-logs and well-testing data, this paper documents the sedimentary characteristics of the gravity-flow deposits and constructs a depositional model. Gravity-flow deposits in the study area comprise seven lithofacies types, which are categorised into four groups: slides and slumps, debris-flow-dominated lithofacies, turbidity-current-dominated lithofacies, and deep-water mudstone-dominated lithofacies. The seven lithofacies form two sedimentary entities: sub-lacustrine fan and the slump olistolith, made up of three and two lithofacies associations, respectively. Lithofacies association 1 is a channel–levee complex with fining-/thinning-upward sequences whose main part is characterised by sandy debris flow-dominated, thick-bedded massive sandstones. Lithofacies association 2 represents distributary channelised lobes of sub-lacustrine fans, which can be further subdivided into distributary channel, channel lateral margin and inter-channel. Lithofacies association 3 is marked by non-channelised lobes of sub-lacustrine fans, including sheet-like turbidites and deep-lake mudstones. Lithofacies association 4 is represented by proximal lobes of slump olistolith, consisting of slides and slumps. Lithofacies association 5 is marked by distal lobes of slump olistolith, comprising tongue-shaped debris flow lobes and turbidite lobes. It is characterised by sandy debris flow, muddy debris flow-dominated sandstone and sandstone with classic Bouma sequences. Several factors caused the generation of gravity flows in the Ordos Basin, including sediment supply, terrain slope and external triggers, such as volcanisms, earthquakes and seasonal floods. The sediment supply of sub-lacustrine fan was most likely from seasonal floods with a high net-to-gross and incised channels. Triggered by volcanisms and earthquakes, the slump olistolith is deposited by the slumping and secondary transport of unconsolidated sediments in the delta front or prodelta with a low net-to-gross and no incised channels.     

Morphological analysis of deep-seated gravitational slope deformation (DSGSD) in the western part of the Argentera massif. A morpho-tectonic control?

The western part of the Argentera–Mercantour massif (French Alps) hosts very large currently active landslides responsible of many disorders and risks to the highly touristic valleys of the Mercantour National Park and skiing resorts. A regional scale mapping of gravitational deformations has been compared to the main geo-structures of the massif. A relative chronology of the events has been established and locally compared to absolute ¹⁰Be dating obtained from previous studies. Two types of large slope destabilisations were identified as follows: deep-seated landslides (DSL) that correspond to rock volumes bounded by a failure surface, and deep-seated gravitational slope deformations (DSGSD) defined as large sagging zones including gravitation landforms such as trenches and scarps or counterscarps. Gravitational landforms are mainly collinear to major N140°E and N020°E tectonic faults, and the most developed DSGSD are located in areas where the slope direction is comparable to the orientation of faults. DSL are mostly included within DSGSD zones and located at the slopes foot. Most of DSL followed a similar failure evolution process according to postglacial over steepened topographies and resulting from a progressive failure growing from the foot to the top of the DSGSD that lasts over a 10 ky time period. This massif-scale approach shows that large-scale DSGSD had a peak of activity from the end of the last deglaciation, to approximately 7000 years bp. Both morphologic and tectonic controls can be invoked to explain the gravitational behaviour of the massif slopes.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.