Influence of alcohols on the extraction of cerium(IV) by Aliquat-336 in kerosene

Tricaprylmethylammonium chloride (Aliquat-336) diluted with kerosene was used to extract cerium(IV) from nitric acid medium. Various alcohols were used as modifiers to overcome the third phase problem. The different parameters affecting the extraction process including nitric, nitrate, hydrogen ion, extractant and metal concentrations as well as the temperature were separately investigated. The effect of the investigated alcohols on the extraction process was also studied in detail at two different concentrations and correlated to their physical constants. Based on the obtained results, the extraction equilibrium was deduced and the optimum conditions for the extraction of cerium(IV) were proposed. The method was tested and applied to the separation of cerium from the hydrous oxide cake resulting from monazite sand.     

高应力区砂岩加卸载条件下能量变化规律及损伤分析

根据高应力区砂岩三轴压缩试验和峰前卸围压试验的结果,分析了砂岩在不同应力路径下的能量变化规律。试验结果表明,相同围压下,峰前卸围压试验的各能量指标(总吸收能、弹性应变能、耗散能)均小于三轴压缩试验,能量变化特征与其初始应力路径密切相关,且随围压的增大而增大。峰前储存的弹性应变能比耗散能多,耗散能只在临近峰值点处才迅速增加。能量的耗散会导致岩石产生损伤,并且使岩性劣化、丧失强度,从能量角度定义的损伤变量,可以得出结论:开始卸荷低围压下的损伤变量大于高围压下,临近破坏时高围压下的损伤变量大于低围压下;卸围压使岩样束缚减小,加速了损伤的发展,岩样所受的应力状态愈趋不平衡。因此,基于能量的角度来表征岩石的损伤演化更符合实际。     

SEA LEVEL RISE OF THE ZHUJIANG RIVER DELTA AND NEOTECTONICS

A linear regression analysis of 28 selected tide-gauge stations of the Zhujiang Estuary shows that there has been a tendency of local sea level rise at a rate of 2.028 mm per year. The origin of the variation is significantly attributed to the local tectonic movement of discrepant fault-block. Based on this, four types of relative local sea level changes are classified. According to calculation, half of the fertile land, or 800 km2 of the delta plain will have been submerged by sea water by about 2040. This will yield a significant influence on the economic construction and human activities.     

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Origin of spongy textures in clinopyroxene and spinel from mantle xenoliths, Hessian Depression, Germany

Summary Spongy textures are observed in anhydrous Group 1 mantle xenoliths (harzburgite, lherzolite and wehrlite) hosted in Tertiary alkali basaltic lavas from the Hessian Depression, Germany. These textures are developed only on clinopyroxene and spinel, and occur as rims or cross-cutting veinlets and patches showing optical continuity with the host grain. They are often associated with pools of amorphous glassy material. There is no preferential development of spongy domains against the xenolith-lava contact suggesting that the host magma did not play any significant role in their formation. Spongy clinopyroxene and spinel occur in all rock types, but, are more pervasive in wehrlite. Chemically, spongy domains of clinopyroxene and spinel are more refractory than unaffected areas, which is consistent with their formation through a partial melting event. The associated glassy material shows chemical characteristics which suggest that the melt pools are genetically related to the development of the spongy textures. The partial melting event was probably triggered by the infiltration of a low-density fluid. The fluid may have evolved from a silicate melt responsible for the metasomatic Fe-enrichment recorded in wehrlite. In this context, the more pervasive development of spongy clinopyroxene in wehrlite may be explained by a higher concentration of the evolved fluid phase at proximity to its silicate melt source. Received March 15, 2000; revised version accepted September 6, 2001     

Isotopic and hydrochemical data to restrict the origin of the groundwater in the Badain Jaran Desert,Northern China

Despite its extreme aridity, the Badain Jaran Desert is rich in groundwater. In the southeastern part of the desert, it is characterized by coexistence of high megadunes and a great number of lakes. Deuterium and oxygen 18 isotope compositions as well as hydrochemistry of groundwater, lake water, soil water and river water were investigated in detail to gain an insight into their relationships and the origin of the ground-water. The results show that the groundwater and the lake water are genetically related, but unrelated to local precipitation and the leakage of Heine River at northern slope of Qilian mountain. δD and δ¹⁸O values of deep soil water (lower than 40 cm) and groundwater plot on the same evaporation line E11, which shows that they have the same recharge source. The point of intersection between E11 and LMWL suggests that the groundwater originates from the water resource which has a weighted mean value that is lighter by some 6‰ δ¹⁸O than the local precipitation in Badain Jaran Desert. ³H data of water samples shows that the groundwater in Badain Jaran Desert originates from the water recharged after the nuclear test. The deep fault zone underground maybe the water circulation channel based on Helium analysis of groundwater. The result has guiding significance to rational exploitation and utilization of the local groundwater.     

Evolution of sedimentary basins from the standpoint of petroleum origin and accumulation—an approach for a quantitative basin study

Generation, migration and accumulation of petroleum in a sedimentary basin is a function of geologic, hydrodynamic and thermodynamic development of the basin and the type and amount of organic matter. Temperature history not only determines rate of hydrocarbon generation, but also affects paleohydrodynamics and physical and thermal properties vs depth relationships. Therefore, paleotemperature is the most important parameter. Paleohydrodynamics together with geologic history of the basin is important in shaping secondary migration patterns and accumulation of hydrocarbons.Quantification of all the above processes is complicated. Steps in constructing a deterministic dynamic model for calculation of petroleum potential during a sedimentary basin development are stated and analyzed in this paper. The effect of paleotemperature variations on petroleum generation and on physical properties of sedimentary sequences are illustrated by numerical examples. Computer models will enable exploration geologists to make quantitative exploration predictions in sedimentary basins.     

多维邻近下浙江城市创新网络演化及其机制研究

以浙江90个县级城市（城区）为对象,基于大数据专利文本挖掘析取城市间合作申请专利数,构建创新网络,采用空间网络模型和负二项回归模型分析2007—2017年浙江城市创新网络的网络结构、时空演化及创新合作强度的影响机制。研究发现：① 浙江城市创新网络规模逐渐扩张,“小世界性”显著,通达性较好,整体呈以杭州湾区为核心的“网络局部化、辐射中心化”特征,等级层次性清晰;② 浙江城市创新合作强度与经济规模、教育水平、政策支持、技术势差、城市行政等级、技术邻近性、边界相邻效应显著正相关且受地理距离约束,认知邻近性和制度邻近性与创新合作间分别呈“U”型和倒“U”型曲线关系,网络效应更多在整体网层面上促进了创新合作。在特定省份县级城市层面探讨了如何加强城市创新网络协同效应,以促进地方城市间的创新联系。     

Sea surface height variations in the Mindanao Dome region in response to the northern tropical Pacific winds

Sea surface height (SSH) variability in the Mindanao Dome (MD) region is found to be one of the strong variations in the northern Pacific. It is only weaker than that in the Kuroshio Extension area, and is comparable to that in the North Pacific Subtropical Countercurrent region. Based on a 1.5-layer reduced gravity model, we analyzed SSH variations in this region and their responses to northern tropical Pacific winds. The average SSH anomaly in the region varies mainly on a seasonal scale, with significant periods of 0.5 and 1 year, ENSO time scale2-7years, and time scale in excess of 8 years. Annual and long-term variabilities are comparably stronger. These variations are essentially a response to the northern tropical Pacific winds. On seasonal and ENSO time scales, they are mainly caused by wind anomalies east of the region, which generate westward-propagating, long Rossby waves. On time scales longer than 8 years, they are mostly induced by local Ekman pumping. Long-term SSH variations in the MD region and their responses to local winds are examined and discussed for the first time .