Radiation-hydrodynamic waves and global solar oscillations

We investigate nonadiabatic hydrodynamic waves in a nongrey, radiating, thermally conducting, homogeneous atmosphere in LTE with a finite mean free path of photons. Avoiding the Eddington approximation the remaining simplifications in the basic equations are discussed, the generalized dispersion relation is analysed, and some wave properties in a grey model are studied. The properties of waves in a stratified atmosphere are analysed as well. In connection with the predicted properties of the nonadiabatic waves we discuss observations ofp-modes by measuring brightness fluctuations.     

Kinetics of peptide hydrolysis and amino acid decomposition at high temperature

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.     

An occurrence of ardennite in quartz veins in piemontite schist,Western Otago,New Zealand

Summary Ardennite of complex composition: (Mn²⁺ _3.488Ca_0.509Ba_0.002)₌₄(Mg_0.916916 Fe³⁺ _0.165 Mn³⁺ _0.099Cu_0.033Ni_0.009Zn_0.006 Ti_0.008Al_4.764)₌₆(As⁵⁺ _0.823V⁵⁺ _0.022P_0.005B_0.069Al_0.042Si_5.039)₌₆O_21.81(OH)_6.17 occurs in crack-seal quartz veins in quartz-albite-piemontite-spessartine-phengitehematite-chlorite-rutile-tourmaline ± calcite schist of the Haast Schist Group near Arrow Junction, western Otago, New Zealand. The Mn²⁺/Mn³⁺-ratio is sensitive to calculations and to accuracy of analyses. Boron is detected in ardennite for the first time. Other properties include = 1.734(3), = 1.735(3), = 1.751(3), 2V_Z = 30(2)°;a = 8.721(1),b = 5.816(1),c = 18.545(3) Å,V = 940.7(2) ų. Associated mineral phases are spessartine, hematite, piemontite containing 0.7% SrO and 0.06% PbO, and phengite. Later-stage vein minerals comprise chlorite, albite, and manganoan calcite which were deposited under less highly oxidizing conditions. Digenite with minor intergrown covellite occurs in small amount with manganoan calcite and quartz in a cross-cutting late-stage veina chalcopyrite and native copper occur in other late-stage veins. Arsenic and other components of the ardennite and associated minerals are derived from highly oxidized ferromanganese oxide- and hydroxide-bearing siliceous pelagic sediments that formed the protolith for the piemontite schist. The veins formed at a relatively early stage after metamorphism peaked in the chlorite zone of the greenschist facies under conditions that have been estimated at about 4.5 kbar, 390 °C.

---

Vorkommen von Ardennit in Quarzgängen aus Piemontit-Schiefern, West-Otago, Neuseeland

Zusammenfassung Ardennit mit der Zusammensetzung (Mn²⁺ _3.488Ca_0.509Ba_0.002)₌₄(Mg_0.916Fe³⁺ _0.165Mn³⁺ _0.099Cu_0.033Ni_0.009Zn_0.006 Ti_0.008Al_4.764)₌₆(As⁵⁺ _0.823V⁵⁺ _0.022P_0.005B_0.069Al_0.042Si_5.039)₌₆O_21.81(OH)_6.17 tritt in Crack-seal-Quarzgängen in Quarz-Albit-Piemontit-Spessartin-Phengit-Hämatit-Chlorit-Rutil-Turmalin ± Calcit-Schiefern der Haast Schiefer-Gruppe nahe der Arrow Junction, West-Otago, Neuseeland, auf. Die Proportionen von Mn²⁺/Mn³⁺ hängen von der Kalkulation und der Genauigkeit der Analyse ab. Bor wird zum ersten Mal im Ardennit bestimmt. Andere Eigenschaften sind: = 1.734(3), = 1.735(3), = 1.751(3), 2Vz = 30(2)°; a = 8.721(1), b = 5.816(1), c = 18.545(3) Å, V = 940.7(2) Å3. Assoziierte Mineralphasen sind Spessartin, Hämatit, Piemontit, der 0.7% SrO und 0.06% PbO enthält und Phengit. Spät gebildete Gangmineralien, wie Chlorit, Albit und Mn-Calcit, sind unter geringer oxidierenden Bedingungen entstanden. Digenit mit etwas Covellin tritt in kleinen Mengen zusammen mit Mn-Calcit und Quartz in einem querschlägigen Gang auf, Chalcopyrit und gediegenes Kupfer kommen in anderen späten Gängen vor. Arsen und andere Komponenten des Ardennites and der assoziierten Minerale können von hochoxidierten, Fe-Mn-Oxid- und Hydroxyd-führenden, Sireichen, pelagischen Sedimenten hergeleitet werden, die das Ausgangsgestein für den Piemontit darstellen. Die Gänge wurden in einem relativ frühen Stadium, nach dem Metamorphosehöhepunkt, innerhalb der Chloritzone der Grünschiefer-Fazies, unter ungefähr 4.5 kbar und 390°C, gebildet.

---

---

With 4 Figures     

Radiation pressure effects in the oscillations of compressible rotating homogeneous spheroids

Earlier models of compressible, rotating, and homogeneous ellipsoids with gas pressure are generalized to include the presence of radiation pressure. Under the assumptions of a linear velocity field of the fluid and a bounded ellipsoidal surface, the dynamical behaviour of these models can be described by ordinary differential equations. These equations are used to study the finite oscillations of massive radiative models with masses 10M and 30M in which the effects of radiation pressure are expected to be important.Models with two different degrees of equilibrium are chosen: an equilibrium (i.e., dynamically stable) model with an initial asymmetric inward velocity, and a nonequilibrium model with a nonequilibrium central temperature and which falls inwards from rest. For each of these two degrees of equilibrium, two initial configurations are considered: rotating spheroidal and nonrotating spherical models.From the numerical integration of the differential equations for these models, we obtain the time evolution of their principal semi-diametersa ₁ anda ₃, and of their central temperatures, which are graphically displayed by making plots of the trajectories in the (a ₁,a ₃) phase space, and of botha ₁ and the total central pressureP _c against time.It is found that in all the equilibrium radiative models (in which radiation pressure is taken into account), the periods of the oscillations of botha ₁ andP _c are longer than those of the corresponding nonradiative models, while the reverse is true for the nonequilibrium radiative models. The envelopes of thea ₁ oscillations of the equilibrium radiative models also have much longer periods; this result also holds for the nonequilibrium models whenever the envelope is well defined. Further, as compared to the nonradiative models, almost all the radiative models collapse to smaller volumes before rebouncing, with the more massive model undergoing a larger collapse and attaining a correspondingly larger peakP _c.When the mass is increased, the dynamical behavior of the radiative model generally becomes more nonperiodic. The ratio of the central radiation pressure to the central gas pressure, which is small for low mass models, increases with mass, and at the center of the more massive model, the radiation pressure can be comparable in magnitude to the gas pressure. In all the radiative models, the average periods as well as the average amplitudes of both thea ₁ andP _c oscillations also increase with mass.When either rotation or radiation pressure effects or both are included in the equilibrium nonradiative model, the period of the envelope of thea ₁ oscillations is increased. The presence of rotation in the equilibrium radiative model, however, decreases this period.Some astrophysical implications of this work are briefly discussed.     

Interregional migration in socialist countries: the case of China

This paper analyzes changing interregional migration in China and reveals that the recent eastward migration reverses patterns of migration under Mao. It finds that investment variables are more important than the conventional variables of income and job opportunities in determining China's recent interregional migration. It suggests that both state policy and the global force influence interregional migration, challenging the popular view that the socialist state is the only critical determinant. This paper also criticizes Mao's approach to interregional migration and discusses the impact of migration on development.     

Feasibility study of a multiple flyby mission of main belt asteroids

Specific information on the surface morphology, composition, mean density, and internal structure of asteroids, which is necessary to advance our understanding of asteroids, can be obtained only by a detailed investigation of individual bodies: this will require space missions to individual targets. Since an essential characteristic of the asteroids is their variety, several objects must be visited. The Ariane launcher developed presently in Europe makes a multiple flyby mission possible. The first results of our feasibility study are particularly encouraging: during one revolution, five to six preselected main belt asteroids may be approached to within 1000 km with relative velocities which lie between 3 and 14 km/sec using a total impulse correction on the order of 1 to 2 km/sec. The weight of the spacecraft, excluding the engine and the propellant, would be at least 250 kg. This allows a scientific payload of 50 to 60 kg, in which priority will be given to an imaging system and radar altimeter.     

A model for thinning of the plasma sheet

A one-dimensional model for thinning of the plasma sheet is developed on the basis of launching a fast mode MHD rarefaction wave propagating in the tailward direction along the plasma sheet. Behind the rarefaction wave the pressure is reduced, leading to thinning of the plasma sheet and also to an Earthward plasma flow with a speed on the order of the sound speed a₀. The plasma sheet thickness is reduced by a factor of 2 if an Earthward plasma flow speed of 0.8a₀ is induced. The predictions of the model are in reasonable agreement with observations.     

Water-rock interaction in a zone of lateral flow: A natural example from the active geothermal field and gold-mineralized zone of Beppu (Kyushu Island,Japan)

Summary Beppu is a water-dominated active geothermal system in Kyushu (Japan). Gold mineralization exists in places within altered Pleistocene volcanites in the southernmost part of this field. A shallow 300 m well was drilled in an alluvial fan deposit made up of unsorted volcanic clasts of andesite and dacite. Water and core samples were collected and a temperature log was carried out. In the depth range of 150-230 m and at temperatures of 126-148° C the main authigenic minerals are quartz, calcite, K-feldspar, mixed layers illite/smectite, stilbite and pyrite. The chemical data of the waters indicate that mixing occurs between shallow bicarbonate waters and deep Na-Cl geothermal waters in the outflow zone. The authigenic mineral assemblages found in the well are analogous to those found in the epithermal gold deposits of southern Kyushu. Au concentration data for the hydrothermal springs of Beppu (0.53 g/kg) indicate that the fluids found in the borehole at 148° C could theoretically deposit gold. It is reasonable to hypothesise that a process of mixing between deep Na-Cl fluids and shallow Ca-HCO₃-SO₄ fluids were responsible for massive silicate deposition, accompanied in places by Au mineralizations.

---

Wasser-Gesteins-Wechselwirkung in einer Zone lateraler Fließbewegung: ein natürliches Beispiel aus der aktiven Geothermal-Golderz-Zone von Beppu (Kyushu, Japan)

Zusammenfassung Beppu ist ein geothermales System auf der Insel Kyushu, Japan, in der Wasser die dominante Rolle spielt. Goldvererzungen treten stellenweise in umgewandelten pleistozänen Vulkaniten im südlichsten Teil des Gebietes auf. Ein 300 m tiefes Bohrloch wurde in einem alluvialen Sedimentations-Fächer, der aus unsortierten vulkanischen Klasten, aus Andesit und Dazit besteht, niedergebracht. Wasserproben und Kernproben wurden genommen und die Temperaturen im Bohrloch systematisch gemessen. In Tiefen von 150–230 m und bei Temperaturen von 126–148°C sind die wichtigsten autigen gebildeten Minerale Quarz, Calcit, K-Feldspat, Illit/Smectit, Stilbit und Pyrit. Der Chemismus der Wässer zeigt, daß eine Mischung zwischen seichten Bikarbonat-Wässern und aus der Tiefe stammenden Na-Cl geothermalen Wässern erfolgt. Die autigenen Mineralassoziationen in diesem. Bohrloch sind vergleichbar mit denen in epithermalen Goldlagerstätten des südlichen Kyushu. Auf der Basis von existierenden Goldkonzentrationsdaten für die hydrothermalen Quellen auf Beppu (0.53 g/kg) läßt sich zeigen, daß die Fluide, die in dem Bohrloch bei 148 angetroffen wurden, theoretisch Gold absetzen könnten. Daher läßt sich die Theorie vertreten, daß Mischungsvorgänge zwischen einem aus der Tiefe stammenden Na-Cl Fluid und einem oberflächennahen Ca-HCO₃-SO₄ Wasser für die massive Silikatausscheidung verantwortlich waren, die stellenweise von Goldmineralisation begleitet wurden.

---

---

Contribution No 4. Foreign Visiting Scientist Section, Beppu Geophysical Research Laboratory, Kyoto University.

---

This paper was presented at the IGCP 291 Project Symposium Metamorphic Fluids and Mineral Deposits, ETH Zurich, March 21–23, 1991.