Organic matter of the Mulhouse Basin, France: a synthesis

The lower Oligocene evaporite sequence of the Mulhouse Basin (France) contains organic matter-rich marl deposits. These marls display an overall cyclic variation of sedimentation rate, organic carbon content, hydrogen index and selected molecular parameters over a 30 m thick stratigraphic interval. The integration of all sedimentological and geochemical parameters has allowed the reconstruction and characterization of the paleoenvironment of deposition. The marls were deposited in a perennial lake that was at times connected to the sea. Two organic facies end members could be assigned to a lake stage with a marine connection and a lake stage that received dominantly continental water input. The overall stratigraphic variation in the organic matter content is interpreted to reflect the adaptation of the Oligocene flora to the changing paleoclimate and environmental conditions.     

Types and distribution of silver ore deposits in China

Silver is generally recovered as a by- and co-product along with Au, Pb, Zn, Cu, Sb, Bi, Hg, Sn and W from polymetallic and gold mines in China. Chinese silver deposits can be classified into five principal types according to host rocks. These types and their host rocks are: (1) marine volcanic-sedimentary rocks hosting (la) massive sulfide Pb-Zn-(Cu)-Ag ores and (1b) stratiform Ag-(Au) ores; (2) continental volcanic-sedimentary rocks containing (2a) various polymetallic-silver veins and/or stockworks, and (2b) Ag-(Au) veins in pyroclastic rocks; (3) rocks affected by metasomatic processes including (3a) complex Sn-polymetallic-Ag ores, (3b) Pb-Zn-(Cu)-Ag skarns, (3c) associated W-Ag quartz veins and/or skarns, and (3d) Ag-(Au) zones and veins in altered carbonate rocks; (4) metamorphic-intrusive rocks, principally Ag-(Au) veins in sheared and brecciated metamorphic rocks; and (5) sedimentary rocks including (5a) stratiform Pb-Zn-Ag ores in carbonate rocks, (5b) Ag-V mantos in black shales, and (5c) Cu-(Ag) layers in red sandstones. A sixth grouping includes gossans. The tectonic settings, geological features, and temporal and spatial distribution of these different types of silver occurrences indicate that silver mineralization reflects to a great extent the evolution of tectonic environments in China throughout geological time. Type 1 is generally developed in association with several fold belts from the Caledonian to Yanshanian orogens, while types 2, 3 and 4 correlate with rejuvenation of the eastern China continent during the Mesozoic period. The three subgroups of type 5 are recognized in different stages and various sedimentry and diagenetic environments during the development of paraplatforms and fold belts. Type 6 results from recent weathering of existing sulfide ores or protores. Editorial handling: DR     

Magnotospheric imaging of high latitude ion outflows

High latitude ion outflows mostly consist of upward streaming O⁺ and He⁺ emanating from the ionosphere. At heights above 1000 km, these flows consist of cold and hot components which resonantly scatter solar extreme ultraviolet (EUV) light, however, the ion populations respond differently to Doppler shifting resulting from the large relative velocities between the ions and the Sun. The possibility of optical detection of the Doppler effect on the scattering rate will be discussed for the O⁺ (83.4 nm) ions. We have contrasted the EUV solar resonance images of these outflows by simulations of the 30.4 nm He⁺ and 83.4 nm O⁺ emissions for both quiet and disturbed geomagnetic conditions. Input data for the 1000 km level has been obtained from the EICS instrument aboard the Dynamics Explorer satellite. Our results show emission rates of 50 and 56 milli-Rayleighs at 30.4 nm for quiet and disturbed conditions and 65 and 75 milli-Rayleighs at 83.4 nm for quiet and disturbed conditions, respectively, obtained for a polar orbiting satellite and viewing radially outward. We also find that an imager at an equatorial distance of 9 R_E or more is in a favorable position for detecting ion outflows, particularly when the plasmapause is depressed in latitude. However, an occultation disk is necessary to obscure the bright plasmaspheric emissions.     

The geometrical and fractal properties of visible radiances associated with breaking waves in the ocean

We consider the natural processes of wind-wave-breaking in the ocean in terms of fractal dimension. Digital algorithms for the analysis of aircraft optical images are employed to investigate spatial and statistical characteristics of foam streaks and whitecaps. The new results are as follows: 1. the fractal dimension of the wave-breaking set (foam streaks and whitecaps) depends on the ocean surface state and changes from d_H=1.05 to 1.25; 2. the fractal dimension differs from foam streaks and whitecaps - d_s=1.23 and 1.39, respectively.     

Hydrostatic compression of γ-Mg2SiO4 to mantle pressures and 700 K: Thermal equation of state and related thermoelastic properties

P-V-T equations of state for the γ phase of Mg₂SiO₄ have been fitted to unit cell volumes measured under simultaneous high pressure (up 30 GPa) and high temperature (up to 700 K) conditions. The measurements were conducted in an externally heated diamond anvil cell using synchrotron x-ray diffraction. Neon was used as a pressure medium to provide a more hydrostatic pressure environment. The P-V-T data include 300 K-isothermal compression to 30 GPa, 700 K-compression to 25 GPa and some additional data in P-T space in the region 15 to 30 GPa and 300 to 700 K. The isothermal bulk modulus and its pressure derivative, determined from the isothermal compression data, are 182(3) GPa and 4.2(0.3) at T=300 K, and 171(4) GPa and 4.4(0.5) at T=700 K. Fitting all the P-V-T data to a high-temperature Murnaghan equation of state yields: K _TO=182(3.0) GPa, K _TO=4.0(0.3), ?K _T /?T)₀=?2.7(0.5)×10^?2 GPa/K and (?² K _T /?P?T)₀=5.5(5.2)×10^?4/K at the ambient condition.     

A framework for coupling shoals and shallow embayments with main channels in numerical modeling of coastal plain estuaries

A simple computational framework is developed to include shoals and shallow embayments (SSE) and their interaction with main channels in estuarine modeling. The scheme, treating SSE as temporary storage areas, accounts for the water and material exchanges between SSE and main channels as the tide rises and falls, and for the biogeochemical processes affecting nonconservative substances such as water-quality parameters in SSE. The scheme, because of its simple nature, can be easily incorporated into one-, two- or three-dimensional models of estuaries with substantial SSE. The concept and the model implementation of the scheme are explained using a vertical two-dimensional model of estuarine hydrodynamics and water quality. The model application to the tidal Rappahannock River, a western shore tributary of Chesapeake Bay, demonstrates the scheme is simple and physically reasonable, and the importance of SSE in estuarine modeling. The inclusion of SSE in a water-quality model not only provides a framework, for computing water-quality conditions therein but also accounts for the interaction between SSE and the main channel. It is shown that significant errors may result if the effects of SSE are not properly accounted for in modeling of an estuary with extensive SSE.     

A note on the chemical composition of lake water in the Laguna Amarga,a saline lake in Patagonia,Chile

The chemical composition of lake water in Laguna Amarga, a small, shallow, saline lake near the Torres del Paine National Park (at 51°S), Chilean Patagonia, was studied in January, 1993. The water was strongly alkaline (pH 9.4) conductivity was 71.4 mS cm^–1, and salinity was 77 g L^–1. The major ions were sodium and sulphate.     

The Quaternary record of eastern Svalbard - an overview

The eastern part Svalbard archipelago and the adjacent areas of the Barents Sea were subject to extensive erosion during the Late Weichselian glaciation. Small remnants of older sediment successions have been preserved on Edgeeya, whereas a more complete succession on Kongsøya contains sediments from two different ice-free periods, both probably older than the Early Weichselian. Ice movement indicators in the region suggest that the Late Weichselian ice radiated from a centre east of Kong Karls Land. On Bjørnøya, on the edge of the Barents Shelf, the lack of raised shorelines or glacial striae from the east indicates that the western parts of the ice sheet were thin during the Late Weichselian. The deglaciation of Edgeøya and Barentsøya occurred ca 10,300 bp as a response to calving of the marine-based portion of the ice sheet. Atlantic water, which does not much influence the coasts of eastern Svalbard today, penetrated the northwestern Barents Sea shortly after the deglaciation. At that time, the coastal environment was characterised by extensive longshore sediment transport and deposition of spits at the mouths of shallow palaeo-fjords.