Trace elements in the Goze Delchev coal deposit, Bulgaria

The geochemistry of trace elements in the underground and open-pit mine of the Goze Delchev subbituminous coal deposit have been studied. The coals in both mines are highly enriched in W, Ge and Be, and at less extent in As, Mn and Y as compared with the world-wide Clarkes for subbituminous coals. Ni and Ti are also enhanced in the underground coals, and Zr, Cr and Mo in the open-pit mine coals.Characteristic for the trace element contents in the deposit is a regular variation with depth. The following patterns were distinguished for profile I: a — the element content decreases from the bottom to the top of the bed paralleling ash distribution (Fe, Co, As, Sb, V, Y, Mo, Cs, REE, Hf, Ta, Th, P and Au); b — Ge and W are enriched in the near-bottom and near-top coals; c — in the middle part of the bed the content of K and Rb is maximal, while that of U is slightly enriched; d — Ba content decreases from the top to the bottom of the bed. In profile II, W and Be contents decrease from the bottom to the top. The near-bottom, and especially the near-roof samples of profile IV are highly enriched in Ge, while for W the highest is the content of the near-bottom sample.Ge, Be, As, Mn, Cl and Br are mainly organically associated. The organic affiliation is still strong for Co, B, Sr, Ba, Sb, U, Th, Mo, La, Ce, Sm, Tb and Yb in the underground coals, and Fe, Co, Na, W, Sr, Y and Ag in the coals from the open-pit mine. K, Rb, Ti, Zr, Hf and Ta are of dominant inorganic affinity. The chalcophile and siderophile elements correlate positively with Fe and each other and may be bound partly with pyrite or other sulphides and iron containing minerals.Compared statistically by the t-criteria, the elements Na, Li, Cu, Zn, Pb, Cr, Ni, Co, Mo, Fe and Be are of higher content in the open-pit mine. Tungsten is the only element of higher concentration in the underground mine. The contents of Ge, As, Sr, V, Mn, Y, Zr and P are not statistically different in both mines.It was supposed that there were multiple sources of the trace elements in the deposit. The source of the highly enriched elements (W, Ge, Be, and As) most probably were the thermal waters in the source area. The contemporary mineral springs are of high content of these elements. Another source were the hosting Mesta volcanic rocks, which are enriched in Sb, Mo, Hf, U, Th, As, Li and Rb. Some of the volcanics were hydrothermally altered and enriched or depleted of many elements. Thus, the hydrothermal solutions were also suppliers of elements for the coals. It is obvious that the contents, distribution and paragenesis, of the trace elements in both Goze Delchev coals reflect the geochemical specialization of the source area, including rocks, paleo- and contemporary thermal waters.     

A Keystone Transform Without Interpolation for SAR Ground Moving-Target Imaging

Synthetic aperture radar (SAR) image formation for a ground moving target necessitates the compensation of the unknown target trajectory. The keystone transform has been employed to remove the linear component of the range migration for the moving target, where interpolation is required. In this letter, a realization of the keystone transform avoiding interpolation is presented. The kernel of this transform, i.e., the range-frequency-dependent azimuth time rescaling, is implemented using only complex multiplications and fast Fourier transforms based on the scaling principle, which has been successfully applied in the equalization of the space-variant range cell migration in SAR processing. In addition, the moving target is coarsely focused according to the SAR geometry and the platform velocity while exploiting the scaling principle. This preliminary focusing is helpful in the isolation of the moving target from ground clutter, so as to facilitate a more refined processing with respect to each mover. SAR raw data combined with simulated echoes of moving targets are utilized to validate the presented approach     

Detecting and Locating Dielectric Objects Buried Under a Rough Interface

We present a method to detect and locate dielectric objects buried under a rough surface. The method is based on the determination of appearing surface impedance of the half-space, where the dielectric objects are located. The equivalent surface impedance is obtained directly from the impedance boundary condition, which requires the knowledge of the electric field and its normal derivative on the surface. These field values are obtained by measuring the far-field data and using single-layer-potential representation of the scattered field. Using the equivalent surface impedance, one can detect and locate the buried objects. The efficiency and efficacy of the method are tested via numerical simulations     

Variation on PAR to global solar radiation ratio along altitude gradient in Naeba Mountain

Summary We investigated the ratio of photosynthetically active photon flux (Q _p ) to global solar radiation (R _s ) at three sites along different altitudes in Naeba Mountain, Japan at various temporal scales based on 3 years measurement data (1999–2001). The lowest values of the ratio ever reported were found for all sites on both an hourly and a daily scale. A similar slight diurnal pattern was found for all sites based on the monthly mean hourly values of the ratio. However, different sites exhibited different seasonal courses. Statistically significant altitude dependencies were found for the hourly Q _p /R _s under both clear and cloudy weather conditions (t-test, P < 0.001). For clear weather conditions, the hourly Q _p /R _s exhibited an increasing trend with altitude at an average rate of 3.6% per km. The increasing rate was more noticeable below 900 m (8.8% per km) than above (0.7% per km). The inverse trend was found for hourly Q _p /R _s with the altitude under cloudy weather conditions. The hourly Q _p /R _s decreased from 550 m to 1500 m at a rate of 1.8% per km. Again, a major decrease occurred below 900 m, which had the rate of 4.2% per km, compared with 0.2% per km over 900 m. Although the same tendencies were noted for daily Q _p /R _s , under clear sky conditions, they were not as statistically significant as the hourly counterpart (t-test, P < 0.021). The increasing rate of Q _p /R _s at this scale under clear weather conditions was near that of the hourly rate, but below the 900 m rate was reduced to near half of the hourly rate (4.7% per km). And the rate over 900 m increased to 2.7% per km. On the other hand, statistically significant altitude effect was noted for the daily under cloudy weather conditions (t-test, P < 0.002). A rapidly decreasing rate was found for it along the altitude gradient. The reason was due to the large decreasing rate below 900 m (12.4% per km). But again similar to the hourly Q _p /R _s , a very small decreasing rate of daily Q _p /R _s was found over 900 m under cloudy weather conditions. These results suggest the necessity of considering the altitude dependency of Q _p /R _s in future studies.     

Impact of different convective cloud schemes on the simulation of the tropical seasonal cycle in a coupled ocean–atmosphere model

The simulation of the mean seasonal cycle of sea surface temperature (SST) remains a challenge for coupled ocean–atmosphere general circulation models (OAGCMs). Here we investigate how the numerical representation of clouds and convection affects the simulation of the seasonal variations of tropical SST. For this purpose, we compare simulations performed with two versions of the same OAGCM differing only by their convection and cloud schemes. Most of the atmospheric temperature and precipitation differences between the two simulations reflect differences found in atmosphere-alone simulations. They affect the ocean interior down to 1,000 m. Substantial differences are found between the two coupled simulations in the seasonal march of the Intertropical Convergence Zone in the eastern part of the Pacific and Atlantic basins, where the equatorial upwelling develops. The results confirm that the distribution of atmospheric convection between ocean and land during the American and African boreal summer monsoons plays a key role in maintaining a cross equatorial flow and a strong windstress along the equator, and thereby the equatorial upwelling. Feedbacks between convection, large-scale circulation, SST and clouds are highlighted from the differences between the two simulations. In one case, these feedbacks maintain the ITCZ in a quite realistic position, whereas in the other case the ITCZ is located too far south close to the equator.     

Water vapour transport from the tropical Atlantic and summer rainfall in tropical southern Africa

An empirical orthogonal functions analysis of the onshore flow of moisture along the west coast of southern Africa using NCEP-DOE AMIP II Re-analyses suggests two dominant modes of variability that are linked to (a) variations in the circulation linked with the South Atlantic anticyclone (b) the intensity of the flow that penetrates from the tropical Atlantic. The second mode, referred as the Equatorial Westerly mode, contributes the most to moisture input from the Atlantic onto the subcontinent at tropical latitudes. Substantial correlations in austral summer between the Atlantic moisture flux in the tropics and rainfall over the upper lands surrounding the Congo basin suggest the potential role played by this zonal mode of water vapour transport. Composites for austral summer months when this Equatorial Westerly mode had a particularly strong expression, show an enhanced moisture input at tropical latitudes that feeds into the deep convection occurring over the Congo basin. Sustained meridional energy fluxes result in above normal rainfall east and south of the Congo belt. During years of reduced equatorial westerly moisture flux, a deficit of available humidity occurs in the southern tropics. A concomitant eastward shift of deep convection to the southwest Indian ocean and southeastern Africa, leads to below normal rainfall over the uplands surrounding the Congo basin.     

Dynamical effects of environmental vertical wind shear on tropical cyclone motion, structure, and intensity

Summary A series of numerical experiments on an f plane are conducted using the fifth-generation Pennsylvania State University-National Center for Atmospheric Research Mesoscale Model, version 3 (MM5) to investigate how environmental vertical wind shear affects the motion, structure, and intensity of a tropical cyclone. The results show that a tropical cyclone has a motion component perpendicular to the vertical shear vector, first to the right of the shear and then to the left. An initially axisymmetric, upright tropical cyclone vortex develops a downshear tilt and wavenumber-one asymmetry when embedded in environmental vertical wind shear. In both small-moderate shears, a storm weakens slightly compared to that in a quiescent environment. The circulation centers between 300 hPa and the surface varies from 20 km to over 80 km. The secondary circulation becomes quite asymmetric about the surface cyclone center. As a result, convection on the upshear-right quadrant diminishes, limiting the upward heat transport in the eyewall and thus lowering the warm core and leading to a weakening of the storm. In strong vertical shear (above 12 m s⁻¹), the vertical tilt exceeds 160 km in 48 h of simulation and the secondary circulation on the upshear side is completely destroyed with low-level outflow. The axisymmetric component of eyewall convection weakens remarkably and becomes much less penetrative. As a result, the warm core becomes weak and appears at lower levels and the storm weakens rapidly accordingly. This up-down weakening mechanism discussed in this study is different from those previously discussed. It emphasizes the penetrative role of eyewall convection in transporting heat from the ocean to the mid-upper troposphere, maintaining the warm core structure of the tropical cyclone. The vertical shear is found negative to eyewall penetrative convection.     

Initialization and simulation of a landfalling typhoon using a variational bogus mapped data assimilation (BMDA)

Summary Recently, a new data assimilation method called “3-dimensional variational data assimilation of mapped observation (3DVM)” has been developed by the authors. We have shown that the new method is very efficient and inexpensive compared with its counterpart 4-dimensional variational data assimilation (4DVar). The new method has been implemented into the Penn State/NCAR mesoscale model MM5V1 (MM5_3DVM). In this study, we apply the new method to the bogus data assimilation (BDA) available in the original MM5 with the 4DVar. By the new approach, a specified sea-level pressure (SLP) field (bogus data) is incorporated into MM5 through the 3DVM (for convenient, we call it variational bogus mapped data assimilation – BMDA) instead of the original 4DVar data assimilation. To demonstrate the effectiveness of the new 3DVM method, initialization and simulation of a landfalling typhoon – typhoon Dan (1999) over the western North Pacific with the new method are compared with that with its counterpart 4DVar in MM5. Results show that the initial structure and the simulated intensity and track are improved more significantly using 3DVM than 4DVar. Sensitivity experiments also show that the simulated typhoon track and intensity are more sensitive to the size of the assimilation window in the 4DVar than that in the 3DVM. Meanwhile, 3DVM takes much less computing cost than its counterpart 4DVar for a given time window.     

The Filament Disappearance of 7 May 1992 (the Ebi)

The 7 May 1992 filament disappearance in the low corona is analyzed. The cool and hot components of this event are studied, using H, soft X-ray and radio data. We first show the general effect of the disparition brusque (DB) on the life of the filament, which was a quiescent filament in the vicinity of an active region, and then give the history of the development of the 7 May event. The main stages of the event are: (i) the formation of hot arches spanning the cool filament; (ii) rise of the filament, with plasma ejection into the corona, in which we note some spreading of loops from the main body, with two distinct rising velocity phases of the H filament; (iii) formation of X-ray arches below the filament, the foot points of the arcades being two-ribbon H flare patches. The dynamics of H and X-rays features are given.     

Hydrous and anhydrous alterations of chondrules in Kaba and Mokoia CV chondrites

Abstract— Chondrules in the Bali-like CV chondrite Kaba and the Allende-like portion of the Mokoia breccia have been studied to explore the relationship between hydrous alteration to form phyllosilicates and anhydrous alteration resulting in secondary olivine zonation, replacement of enstatite by ferroan olivine and formation of feldspathoids (nepheline and sodalite). All Kaba chondrules experienced extensive hydrous alteration; whereas, anhydrous alteration was minor and resulted only in the olivine zonation. On the other hand, all of the Mokoia chondrules experienced both extensive anhydrous and hydrous alteration. Bronzite rims formed between relic enstatite grains and phyllosilicates in both Kaba and Mokoia during the hydrous alteration. Petrographic observations indicate that phyllosilicates in Mokoia postdate formation of the secondary ferroan olivine and feldspathoids. We conclude that anhydrous alteration in Kaba and Mokoia predated hydrous alteration and took place before accretion of chondrules into the CV parent asteroid.