热液成矿作用的地质地球化学动力学——以胶东牟平-乳山金矿带为例

通过对胶东牟平—乳山热液脉状金,铅锌矿床成矿动力学控制规律的研究,说明了建立热液成矿反应体系的方法,并得出以下认识:（1）区域断裂构造活动,通过影响成矿反应体系的热力学性质和条件,控制元素的富集和分散。（2）热液成矿过程中容矿断裂活动可划分为两种作用方式:脆性破裂和韧—脆性张开,构成热液成矿的两种构造动力学环境。（3）热液成矿反应体系是一种开放的动态的热力学体系。断裂的脆性破裂阶段,使体系处于强烈的过饱和状态,矿质在远离平衡状态下快速结晶,加剧物质分异;在脆—韧性张开阶段,矿质在接近平衡态体系中缓慢晶出。（4）热液演化晚期,金在残余溶液中富集;当断裂再次发生构造脉动震颤时,早期形成的块状黄铁矿矿石碎裂,富金溶液充填其中,形成含裂隙金和晶隙金的富矿石。成矿体系热力学演化与构造动力学条件有利的匹配控制着富矿石的形成。     

Kinetics of peptide hydrolysis and amino acid decomposition at high temperature

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.     

Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.     

Interregional migration in socialist countries: the case of China

This paper analyzes changing interregional migration in China and reveals that the recent eastward migration reverses patterns of migration under Mao. It finds that investment variables are more important than the conventional variables of income and job opportunities in determining China's recent interregional migration. It suggests that both state policy and the global force influence interregional migration, challenging the popular view that the socialist state is the only critical determinant. This paper also criticizes Mao's approach to interregional migration and discusses the impact of migration on development.     

Age — heaping: contrasting patterns from china

Detailed examination of China's 1982 census data confirms that the standard of age reporting among the Han Chinese, and among many of the ethnic minorities, is very good. Furthermore the quality of age reporting is unaffected by large variations in levels of literacy which exist between men and women, between young and old, and between rural and urban areas. Much of the credit for the high quality of China's age reporting stems from the distinctive nature of Chinese traditional calendars. However, in the far west of China, in the Xinjiang Autonomous Region, age heaping and age exaggeration are as bad as they are in many other developing countries. The authors show that the poor quality of age reporting in Xinjiang is confined to three of the region's ethnic communities, the Uygur, Kirgiz and Tajik, who appear to neither know, nor care, how old they are.     

铂族新矿物——峨眉矿OsAs_2的初步研究

峨眉矿发现于四川某地铜镍硫化物型铂矿床中。化学成分为锇的二砷化物,化学式为OsAs_2。斜方晶系,晶胞参数为a=5.409,b=6.167,c=3.021。空间群Pnnm或Pnn2。研究结果确定,这是一个铂族金属新矿物。以产地所在省境内的名山——峨眉山命名,称为峨眉矿(Omeiite)。     

云南滇东北与玄武岩有关的铜矿床含矿岩系组成与划分

滇东北与玄武岩有关的铜矿床是中国近3年来矿床学研究和资源勘查的热点之一，本文结合科研和资源勘查项目实际工作，对该区域含矿岩系的组成与划分进行了研究和探讨。依据研究，含矿岩系由二叠系峨眉山玄武岩组（P₂e）上部（第三岩性段顶部和第四岩性段）和宣威组（P₂x）底部组成，可划分为5个矿化层，进而对5个矿化层的岩性组成、矿化特征和成矿前景进行全面总结，这将为该区域今后进一步开展找矿和勘查工作提供方向和依据。     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

鲁北平原区暴雨成因及时空分布规律探讨

鲁北平原地处黄泛区，流域坡度较缓，降水量年际变化大，年内分配不均，且多以暴雨形式集中在每年的汛期(6～9月)，同时排涝河道层层建闸拦蓄，造成暴雨期排水不畅，极易积涝成灾。依据1951-2000年实测暴雨资料，对本区暴雨的成因、时空分布规律进行了探讨。     

黑龙江省水稻主栽品种热量指标鉴定及应用

本文主要从热量指标角度，通过黑龙江省水稻主栽品种的各生育期所需的活动积温、生育日数的实际观测，计算各生育期的有效积温、生育期下限温度。从热量资源的空间分布、可能生育期日数与各主栽品种全生育期活动积温、生育期日数的实测值作对比分析，讨论水稻各主栽品种的熟型和适宜分布区域。