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31.
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Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO3 and Mg2SiO4 melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ25Mg values in the MgSiO3 and Mg2SiO4 melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ26Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO3 and Mg2SiO4 melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope 24Mg and m′ is the mass of the heavier isotope, 25Mg or 26Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution. 相似文献
33.
中国建设用地的坡谱演化规律与爬坡影响 总被引:1,自引:0,他引:1
城镇建设用地规模与结构变化是国土空间开发与规划研究的基础。以往相关研究更关注建设用地水平空间扩张格局特征与模式,极少关注建设用地三维梯度上的“爬坡”特征规律与影响。因此,本文基于Google Earth Engine(GEE),并结合高精度地形数据与土地利用数据,在建设用地坡谱概念基础上,首次构建了平均建设用地爬坡指数(ABCI),系统地分析了1990—2018年中国建设用地坡谱在国家、区域、省级和城市4个尺度上的变化特征与规律并深入剖析建设用地爬坡的空间影响。结果显示:① 1990—2018年中国坡度5°以上地区建设用地面积增长了1.43倍,比例由10.25%上升至14.81%。其中2010—2015年是建设用地爬坡发展最迅速与规模最大的时期,且中西部地区建设用地爬坡最为显著。② 依据平均建设用地爬坡指数与上限坡度变化,可将中国34个省(自治区、直辖市)划分为高爬坡型、低爬坡型和水平扩展型3类,其中高爬坡型省份占50%以上,水平扩展型省份仅有7个,在空间上呈现“东南—西北”的两极分布特征。③ 1990—2010年爬坡型城市以山地与丘陵地貌城市为主,2010年后少数民族聚居区及低丘缓坡开发试点城市成为建设用地爬坡的主力。④ 建设用地爬坡在一定程度上能够减少建设用地扩张对平原优质耕地与生态用地的胁迫和侵占,缓解建设用地供需矛盾,但是无规划约束的开发和房地产驱动的“削山造地”则会导致地质灾害和生态环境风险的增加。 相似文献
34.
Carbon nanotubes (CNTs) are widely manufactured nanoparticles which are utilized in a number of consumer products, such as sporting goods, electronics and biomedical applications. Due to their accelerating production and use, CNTs constitute a potential environmental risk if they are released to soil and groundwater systems. It is, therefore, essential to improve the current understanding of environmental fate and transport of CNTs. The current study systematically investigated the effect of solution chemistry (pH and ionic strength) and physical conditions (collector grain size and flow rate) on the deposition and mobilization of functionalized multiwall carbon nanotubes (MWCNTs) using a series of column experiments under fully saturated conditions. A one-dimensional convection–dispersion model including collector efficiency for cylindrical nanoparticles was used to simulate the transport of MWCNTs in porous media. It was observed that an increase in pH resulted in increased mobility of MWCNTs. However, the transport of MWCNTs was strongly dependent on ionic strength of the background solution and a critical deposition concentration was observed between 3 and 4 mM NaCl concentration, with more than 99 % filtration of MWCNTs at 4 mM. The finer sand grains were able to filter a significant amount of MWCNTs (15 % more than coarse sand) from the inflow solution; this was likely caused by grain-to-grain straining mechanisms in the finer sand. A decrease in pore water velocity also led to more deposition of MWCNTs due to lowering of the kinetic energy of the particles. The results from this study indicated that a weak secondary minimum existed under unfavorable conditions for deposition, but the particles were trapped at both primary and secondary minimum. 相似文献
35.
根据2004年10月珠江三角洲3个代表性观测点大气边界层观测资料, 分析了珠江三角洲秋季大气边界层温度和风廓线特征。结果表明:珠江三角洲秋季气温递减率较低, 逆温出现频率较高, 强度较弱, 海风使珠江口贴地逆温的出现时间推迟、低空逆温的出现频率增加。珠江三角洲秋季受多种局地环流影响, 边界层内风廓线比较复杂, 晚上城市群与非城市群地区风向有明显差别; 城市群和珠江口多次分别观测到城市热岛环流和海风环流。 相似文献
36.
The radiance leaving the earth-atmosphere system which can be sensed by a satellite borne radiometer is the sum of radiation emission from the earth surface and each atmospheric level that are transmitted to the top of the atmosphere. The radiation emission from the earth surface and the radiance of each atmospheric level can be separated from the radiance at the top the atmospheric level measured by a satellite borne radiometer. However, it is very difficult to measure the atmospheric radiance, especially the synchronous measurement with the satellite. Thus some atmospheric radiative transfer models have been developed to provide many options for modeling atmospheric radiation transport, such as LOWTRAN, MODTRAN, 6S, FASCODE, LBLRTM, SHARC, and SAMM. Meanwhile, these models can support the detailed detector system design, the optimization and evaluation of satellite mission parameters, and the data processing procedures. As an example, the newly atmospheric radiative transfer models, MODTRAN will be compared with other models after the atmospheric radiative transfer is described. And the atmospheric radiative transfer simulation procedures and their applications to atmospheric transmittance, retrieval of atmospheric elements, and surface parameters, will also be presented. 相似文献
37.
干热岩是一种新型清洁能源,其开发利用区的确定十分重要。笔者首先通过对松辽盆地热源、资源量、导热、聚热、地震活动5个方面资料的收集,提出了松辽盆地增强型地热系统开发选区适宜性评价方法;然后选取8项评价因子,利用ArcGIS 10.2平台将松辽盆地划分为26个评价单元,根据打分法和层次分析法(AHP)求取每个因子的权重;最后,对26个选区进行综合评价,将其分成适宜、较适宜、一般适宜、较不适宜和不适宜5个等级。结果表明:松辽盆地干热岩开发适宜区和较适宜区主要集中在盆地中部的大安—大庆一带,确定的适宜选区范围对今后干热岩开发工作具有一定指导作用。 相似文献
38.
西南印度洋深海热液硫化物区沉积物微生物群落结构和固氮基因多样性 总被引:1,自引:0,他引:1
A sediment sample was collected from a deep-sea hydrothermal vent field located at a depth of 2 951 m on the Southwest Indian Ridge. Phylogenetic analyses were performed on the prokaryotic community using polymerase chain reaction(PCR) amplification of the 16 S rRNA and nifH genes. Within the Archaea, the dominant clones were from marine benthic group E(MBGE) and marine group I(MGI) belonging to the phyla Euryarchaeota and Thaumarchaeota, respectively. More than half of the bacterial clones belonged to the Proteobacteria, and most fell within the Gammaproteobacteria. No epsilonproteobacterial sequence was observed. Additional phyla were detected including the Actinobacteria, Bacteroidetes, Planctomycetes, Acidobacteria, Nitrospirae, Chloroflexi, Chlorobi, Chlamydiae, Verrucomicrobia, and candidate divisions OD1, OP11, WS3 and TM6, confirming their existence in hydrothermal vent environments. The detection of nifH gene suggests that biological nitrogen fixation may occur in the hydrothermal vent field of the Southwest Indian Ridge. Phylogenetic analysis indicated that only Clusters I and III NifH were present. This is consistent with the phylogenetic analysis of the microbial 16 S rRNA genes, indicating that Bacteria play the main role in nitrogen fixation in this hydrothermal vent environment. 相似文献
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40.
利用贝类(Lamprotula)化石碳氧同位素再建山西丁村地区晚更新世气候环境 总被引:3,自引:0,他引:3
较大的湖泊中的贝类生长线的氧同位素可能记录了季节性的温度变化。对拔氏丽蚌 (楔丽蚌 )Lamprotula(Cuneolamprotula)bazini (Heude)和环带丽蚌 (丽蚌 )Lamprotula (Lamprotula)zonata (Heude)的生长线进行氧同位素研究表明,前者有较强的适应环境变化的能力。δ18O值记录的襄汾地区晚更新世的古温度为 2 0~ 2 4℃至 30~34℃,古降雨量多出现代 2 0 0~ 2 6 7mm,河水排泄不畅,积水成湖。这些结果给人的启示是:全球变暖后,该地区气温可能有较大升幅 ;降雨量的增加有可能在排水不畅地区形成水灾,应注意防患于未然。 相似文献