量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

《中国21世纪议程》与西北持续发展

本文概要介绍了我国２１世纪发展白皮－《中国２１世纪议程》;全面列举了国际社会对西北地区第一批优先项目支持的承诺,勾勒了西北地区“可持续发展之路”的轮廓。     

Comprehensive methods for measuring regional multidimensional development and their applications in China

National and international research on regional development has matured from the use of single elements and indicators to the application of comprehensive multi-element and multi-indicator measures. We selected 12 indicators from six dimensions for analysis in this study, including income, consumption, education, population urbanization, traffic, and indoor living facilities. We then proposed the polyhedron method to comprehensively measure levels of regional multidimensional development. We also enhanced the polygon and vector sum methods to render them more suitable for studying the status of regional multidimensional development. Finally, we measured levels of regional multidimensional development at county, city, and provincial scales across China and analyzed spatial differences using the three methods above and the weighted sum method applied widely. The results of this study reveal the presence of remarkable regional differences at the county scale across China in terms of single and multidimensional levels of regional development. Analyses show that values of the regional multidimensional development index (RMDI) are high in eastern coastal areas, intermediate in the midlands and in northern border regions, and low in the southwest and in western border regions. Districts characterized by enhanced and the highest levels of this index are distributed in eastern coastal areas, including cities in central and western regions, as well as areas characterized by the development of energy and mineral resources. The regional distribution of reduced and the lowest levels of this index is consistent with concentrations of areas that have always been impoverished. Correlation analyses of the results generated by the four methods at provincial, city, and county scales show that all are equivalent in practical application and can be used to generate satisfactory measures for regional multidimensional development. Additional correlation analyses between RMDI values calculated using the polyhedron method and per capita gross domestic product (GDP) demonstrate that the latter is not a meaningful proxy for the level of regional multidimensional development.     

1961-2005年华东地区高温气候特征

Based on the daily maximum temperature data covering the period 1961-2005, temporal and spatial characteristics and their changing in mean annual and monthly high temperature days (HTDs) and the mean daily maximum temperature (MDMT) during annual and monthly HTDs in East China were studied. The results show that the mean annual HTDs were 15.1 and the MDMT during annual HTDs was 36.3℃ in the past 45 years. Both the mean annual HTDs and the MDMT during annual HTDs were negative anomaly in the1980s and positive anomaly in the other periods of time, oscillating with a cycle of about 12-15 years. The mean annual HTDs were more in the southern part, but less in the northern part of East China. The MDMT during annual HTDs was higher in Zhejiang, Anhui and Jiangxi provinces in the central and western parts of East China. The high temperature process (HTP) was more in the southwestern part, but less in northeastern part of East China. Both the HTDs and the numbers of HTP were at most in July, and the MDMT during monthly HTDs was also the highest in July. In the first 5 years of the 21st century, the mean annual HTDs and the MDMT during annual HTDs increased at most of the stations, both the mean monthly HTDs and the MDMT during monthly HTDs were positive anomalies from April to October, the number of each type of HTP generally was at most and the MDMT in each type of HTP was also the highest.     

南极长城站海雾特征分析

本文根据对海雾气象要素场、大气层结和天气形势的分析及其持续时间和季节、年际变化的统计分析,结合个例,讨论了南极长城站海雾的特征和形成机制。认为长城站海雾大多为平流冷却雾,高频率的偏北风和南大洋极锋附近显著的经向海温梯度是长城站多海雾的根本原因;夏半年海雾要多于冬半年,海雾的年际分布差异明显;海雾可出现于0-17m/s的各级风力中,3-11m/s偏北风最有利于海雾的维持;气温为-2-4℃、气-海温差为0-2℃时最易出现海雾;海雾的发生一般伴有稳定的大气层结;"东高西低"是长城站海雾的主要天气形势;海雾的持续时间取决于高压在南极半岛维持时间的长短,平均有10个小时。     

基于GML/SVG的WebGIS体系结构设计与实现

随着Internet的飞速发展,WebGIS也进入了蓬勃发展的阶段,而制约WebGIS发展的问题也日益突出。本文针对WebGIS中存在的地理空间数据语义共享和网络带宽日益紧张的问题,引入了GML和SVG,在此基础上提出并论证的基于GML和SVG的WebGIS系统的方案和应用模式,并详析了实现该系统的体系结构和相关技术,最后给出了该系统的应用实例。     

洪泛平原农村居民地空间分布特征定量研究及应用探讨

通过对影响居民地空间分布因素的分析,探讨了洪泛平原农村居民地空间分布特征;利用地理信息系统技术对不同高程带内居民地分布规模、等级和空间分布密度作了定量研究,得到了居民地空间分布密度和人口空间分布密度参数;并结合洪灾淹没区居民地损失的估算,对研究结果的应用作了探讨。     

Low-mass and high-mass supermassive black holes in radio-loud AGNs are spun-up in different evolution paths

How supermassive black holes(SMBHs) are spun-up is a key issue in modern astrophysics. As an extension to the study in Wang et al., here we address the issue by comparing the host galaxy properties of nearby(z 0.05) radio-selected Seyfert 2 galaxies. With the two-dimensional bulge+disk decompositions for the SDSS r-band images, we identify a dichotomy in various host galaxy properties for radio-loud SMBHs. By assuming that radio emission from the jet reflects a high SMBH spin, which stems from the well-known Blandford-Znajek mechanism of jet production, high-mass SMBHs(i.e., MBH 107.9 M⊙)have a preference for being spun-up in classical bulges, and low-mass SMBHs(i.e., MBH = 106-107 M⊙)in pseudo-bulges. This dichotomy suggests and confirms that high-mass and low-mass SMBHs are spun-up in different ways, i.e., a major "dry" merger and a secular evolution respectively.     

北京周围地区地震的分布特点与地壳屈曲

地震活动的规模常具有大尺度的特点,结合全球地震分布具有相当的似对称性,我们认为,地震的成因必然蕴含着地球的整体运动.地震活动具有块体性活动的特点.块体的边界线常与经纬线相交成45°.强震发生前也有这种情况.文中给出了与经纬线相交成45°的一个条块,近年华北的强震基本上都落在这个条块的两条边线上,且这些强震的分布具有较明显的等间隔分布特点,类似于地层中的褶皱所显示的一定的波长.我们分析了有历史记载以来我国全部八级地震,发现每次八级地震前后,都有另一次八级或七级半地震在它的一定距离上发生.这个间距有两个优势分布,一个短距的为480—550公里,另一个长距的为1100公里左右(后者约为前者的一倍).引用了柱壳轴向受力屈曲作为初步探讨.从分析可知,柱壳屈曲的半波长(1/2λ≈1.72$ \\sqrt{Rh} $)主要决定于圆柱半径与柱壳厚度:以 R=6000公里、h=15公里估算,得半波长为530公里,与我国强震分布间距较为符合.故我们的初步认识是地震的分布可能受着地壳屈曲的控制.     

乐都县碾伯镇洪水风险图的编制与应用

从非工程措施着手,采用水文学方法,绘制了不同重视期的洪水风险图。该图直观易懂,使用方便,为各级部门进行防洪决策,抗洪抢险,制定防洪规划和城市发展布局以及合理确定洪水保险费率等方面提供了科学依据,可大大提高全民的防洪抢险意识。