油页岩综合利用对周围环境的影响——以抚顺矿区为例

世界能源日益减少的局面为油页岩的开发应用带来广阔的前景，但油页岩工业所带来的环境影响亦不容忽视。以抚顺油页岩为例，从油页岩综合利用和油页岩工业对环境的影响等方面系统讨论了在我国发展油页岩工业时，如何本着节约能源、保护环境、实现可持续发展的观念，利用现有先进技术，科学发展油页岩工业，降低生产过程中的固、液、气污染物对环境的危害。     

LA-ICPMS U-Pb Ages of Zircon from Metaleucosomes, Olongbuluke Microcontinent, North Qaidam, and Implications on the Response to the Global Rodinia Supercontinent Assembly Event in NW China

INTRODUCTION The Olongbuluke microcontinent , which wasdisintegratedfromthe northern margin of the Qaidamblock (Lu,2002) ,is composed of a two-fold base-ment with cover strata . The lower basement is themedium- to high-grade Delingha complex and theDakendaban Group, and the upper is the low-gradeWandonggou Group. The Wandonggou Group of theupper basement experienced a Late Mesoproterozoicmetamorphic event (see Yu et al .,1994) ,consistentwith the early isotopic geochronological respo…     

水对不同岩石声波速度影响的研究

通过分析不同成因类型岩石的声波速度,提出了水对不同岩石声波速度的影响,从岩石孔隙及隐微裂隙的发育程度及岩石的水理性质解释了在水的作用下岩石声波变化规律,利用这些规律可以初步判断岩石的隐微裂隙发育程度及水理性质。     

Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: The modern Qinghai Lake, Qinghai–Tibet Plateau

The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ¹⁸O values, and these vary with water salinity. The relationship between lake water δ¹⁸O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ¹⁸O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ¹⁸O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ¹⁸O values of ostracod and bulk carbonate.     

Rare earth elements (REE) of dissolved and suspended loads in the Xijiang River, South China

The Xijiang River is the main channel of the Zhujiang (Pearl River), the second largest river in China in terms of water discharge, and flows through one of the largest carbonate provinces in the world. The rare earth element (REE) concentrations of the dissolved load and the suspended particulate matter (SPM) load were measured in the Xijiang River system during the high-flow season. The low dissolved REE concentration in the Xijiang River is attributed to the interaction of high pH and low DOC concentration. The PAAS-normalized REE patterns for the dissolved load show some common features: negative Ce anomaly, progressively heavy REE (HREE) enrichment relative to light REE (LREE). Similar to the world’s major rivers the absolute concentration of the dissolved REE in the Xijiang River are mainly pH controlled. The degree of REE partitioning between the dissolved load and SPM load is also strongly pH dependent. The negative Ce anomaly is progressively developed with increasing pH, being consistent with the oxidation of Ce (III) to Ce (IV) in the alkaline river waters, and the lack of Ce anomalies in several DOC-rich waters is presumably due to both Ce (III) and Ce (IV) being strongly bound by organic matter. The PAAS-normalized REE patterns for the dissolved load and the SPM load in rivers draining the carbonate rock area exhibit middle REE (MREE) enrichment and a distinct maximum at Eu, indicating the preferential dissolution of phosphatic minerals during weathering of host lithologies. Compared to the Xijiang River waters, the MREE enrichment with a maximum at Eu disappeared and light REE were more depleted in the South China Sea (SCS) waters, suggesting that the REE sourced from the Xijiang River must be further fractionated and modified on entering the SCS. The river fluxes of individual dissolved REE introduced by the Xijiang River into the SCS vary from 0.04 to 4.36 × 10⁴ mol a⁻¹.     

泊江海子矿白垩纪地层冻结软岩力学特性试验

针对泊江海子矿白垩纪地层中的砂岩和泥岩,分别进行了不同温度（-20~20℃）下的三轴压缩试验。试验结果表明：在-20~20℃之间,白垩纪地层软岩的峰值强度和弹性模量均随温度的降低及围压的升高而增加,其中中砂岩的峰值强度随温度的变化程度明显大于泥岩,即其对温度的敏感性更高;而岩石峰值处的轴向应变则随温度的下降而减小;另外,随着温度降低,两种岩石的峰值内摩擦角和黏聚力均有一定程度的提高,并且抗剪强度指标的增加主要集中在黏聚力上。通过对试验结果的整理和分析,掌握了白垩纪地层软岩在不同低温和围压下的力学特性和规律,为西部地区矿井冻结法设计与施工提供了可靠的依据。     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Thermal equation of state of natural tourmaline at high pressure and temperature

Synchrotron-based in situ angle-dispersive X-ray diffraction experiments were conducted on a natural uvite-dominated tourmaline sample by using an external-heating diamond anvil cell at simultaneously high pressures and temperatures up to 18 GPa and 723 K, respectively. The angle-dispersive X-ray diffraction data reveal no indication of a structural phase transition over the P–T range of the current experiment in this study. The pressure–volume–temperature data were fitted by the high-temperature Birch–Murnaghan equation of state. Isothermal bulk modulus of K ₀ = 96.6 (9) GPa, pressure derivative of the bulk modulus of \(K_{0}^{\prime } = 12.5 \;(4)\), thermal expansion coefficient of α ₀ = 4.39 (27) × 10^?5 K^?1 and temperature derivative of the bulk modulus (?K/?T) _P  = ?0.009 (6) GPa K^?1 were obtained. The axial thermoelastic properties were also obtained with K _a0 = 139 (2) GPa, \(K_{a0}^{\prime }\) = 11.5 (7) and α _a0 = 1.00 (11) × 10^?5 K^?1 for the a-axis, and K _c0 = 59 (1) GPa, \(K_{c0}^{\prime }\) = 11.4 (5) and α _c0 = 2.41 (24) × 10^?5 K^?1 for the c-axis. Both of axial compression and thermal expansion exhibit large anisotropic behavior. Thermoelastic parameters of tourmaline in this study were also compared with that of the other two ring silicates of beryl and cordierite.     

汶川地震地表破裂面形貌特征

准确描述破裂面形貌对于我们理解地震断层作用是非常重要的,破裂面的形貌特征包含许多关于地震和断层机制的有用信息。在Mw7.9 2008汶川地震中断层活动产生了两个新鲜的破裂面,八角庙破裂面和沙坝破裂面。我们使用3D便携式激光扫描仪(Tri mble GX)对两个破裂表面进行测量,在野外微观尺度上研究了破裂面形貌特征。通过能谱密度和均方值两个方法分析破裂面形貌,新鲜的破裂面表现为自相仿性,能谱密度和均方值均与剖面长度存在幂律关系。在能谱密度与空间频率的对数图中,能谱密度曲线存在明显的拐点,该拐点所对应的波长称为特征波长,表明单一分形不能准确描述破裂面形貌。八角庙破裂面在平行滑动方向上的特征波长为7 mm,在垂直方向上特征波长略大一些(区域Ⅰ为10 mm,区域Ⅱ为9 mm);沙坝破裂面在平行滑动方向上的特征波长为8 mm,但垂直方向上特征波长略小(6 mm)。均方值曲线的最小二乘拟合直线的斜率为Hurst指数,该指数依赖于剖面线方向并描述破裂面形貌的各向异性,H指数的最小值和最大值分别与平行擦痕和垂直擦痕方向对应,这与野外断层面擦痕测量结果一致。沙坝破裂面的H指数极坐标图中存在次级H指数峰值(对应剖面线方向为85°和160°),这揭示破裂面上存在一组隐匿擦痕。该组隐匿擦痕为汶川地震之前断层活动中形成的,但这还不足以推测上一次断层活动的时间和规模。另外,通过比较新鲜节理面和破裂面表明H指数是否大于0.8反映了断层类型。在整个空间频率域上,能谱密度曲线斜率(-α)和均方值曲线斜率(H)的线性拟合关系为α=1.22+1.72H,并不严格满足两者之间理论关系式,α=1+2H。这个差异是由于测量信号噪音、破裂面的多分形性和分析方法的差异造成的。