中国留学人员创业园分布及产业特征

以《中国留学人员创业年鉴》为基础数据,采用GIS空间分析技术,运用核密度估计法、L函数和最近邻层次聚类分析等方法,分析2006~2015年中国留学人员创业园空间分布规律以及园区产业集聚特征,结果表明：中国留学人员创业园集聚特征显著,而且随着时间的推移,其多中心趋势明显,集聚规模迅速增大,集聚强度呈“先升后降,但总体增大”趋势;主要集聚于长三角、京津冀和珠三角等地区,尤以前两者最显著,且三大集聚区的集聚强度与集聚规模差异明显,其中长三角留创园的集聚规模最大,京津冀集聚强度最高,而珠三角则比较复杂,其在很小空间尺度范围内服从集聚分布,而在较大空间尺度范围内则服从随机分布;基于不同主导产业的中国留学人员创业园依然集中于长三角、京津冀和珠三角等地区,其主导产业分布格局则差异显著,规律性不强。     

采煤塌陷地水域淹没范围模拟分析

采煤塌陷改变了矿区周边的地形地貌特征,使大量的耕地、园地变成水域。选择山东省龙口采煤塌陷区为研究对象,运用ArcGIS软件采集五期1:1万等高线和离散高程点数据,生成1×1 m2正方形网格的数字地面模型(DEM),以地表没有发生塌陷前的1978年DEM为标准高程数据,与其他各期DEM数据进行差值运算处理,得到不同时期采煤塌陷区面积。然后根据水利部门48年来的观测数据,计算出采煤塌陷区不同频率年份丰水期水文特征值,采用"无源淹没"分析法,计算给定水位条件下的采煤塌陷区水域淹没范围。     

土壤水盐运移模型研究进展及展望

回顾了国内外土壤水盐运移模型的发展历程,根据土壤水盐运移模型构成的原理和发展趋势,将土壤水盐运移模型分为水盐平衡模型、物理模型和系统模型。借助国内外文献对已有模型的原理和应用进行了介绍,并对存在的问题进行了分析;展望了新形势下土壤水盐运移模型的未来发展趋势和研究重点,旨在为今后土壤水盐运移模型研究提供新的思路。     

利用自回归模型检测地球极移重力效应

同时采用4个台站的国际超导重力仪长期连续重力观测资料和国际地球自转服务中心提供的同步地球自转参数，研究了极移引起的地球重力场变化特征。利用自回归模型估计了各序列的功率谱密度和积谱密度，结果表明极移导致的重力效应的主要能量集中在Chandler摆动和周年项附近，叠积后实际重力观测与极移重力信号理论值之间的差异分别为0．4％和3．9％，说明超导重力仪可有效监测极移导致的重力变化。     

铜陵新桥层状菱铁矿成因的矿物学证据及成矿意义

安徽铜陵新桥矿区二叠系栖霞组底部和石炭系黄龙组—船山组之间产出层状、似层状菱铁矿矿层。开展菱铁矿矿层成因研究对于深入剖析区域层控矽卡岩型铜铁矿床成矿机制具有重要意义。本文利用粉晶X射线衍射（XRD）、扫描电镜（SEM）对菱铁矿矿石进行矿物学研究,结果发现菱铁矿矿石主要由菱铁矿、石英、伊利石和有机质等组成,菱铁矿颗粒粒径较小,表面具有成岩自生的自形石英硬模的微结构,SEM原位微区成分分析显示菱铁矿中除了主量元素铁,还含有大量的锰、锌和钙。矿石中存在两种微结构和不同成因的石英：表面具菱铁矿硬模和次生加大结构的碎屑石英;具六方双锥、单锥以及生物成因球形的自生石英。菱铁矿矿石的组成和矿物表面微结构表明其为沉积成因,非岩浆热液起源。富有机质和亚铁的沉积菱铁矿层和沉积胶状黄铁矿层协同作用,可能是铜陵地区乃至长江中下游成矿带层状铜铁矿床层控性重要制约因素,以及可能作为燕山期中酸岩浆演化的氧化性含铜成矿流体卸载成矿的地球化学还原障。

     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

黄河下游窄河道挖河疏浚是维持黄河健康生命的重要措施之一

黄河水利委员会提出了“维持黄河健康生命”的治河新理念,把维持黄河健康生命作为黄河开发与管理的终极目标。“堤防不决口,河道不断流,污染不超标,河床不抬高”是实现其终极目标的4个主要标志。河床不抬高就要通过综合措施解决泥沙问题,包括上中游拦减人黄泥沙,中下游采取人工调控水沙“关系”,在黄河下游挖河疏浚。在黄河下游窄河道特别是在河口地区挖河疏浚,减少其对下游河道的反馈影响,是维持黄河健康生命的重要措施之     

Multi-scale coupling analysis of urbanization and ecosystem services supply-demand budget in the Beijing-Tianjin-Hebei region,China

Journal of Geographical Sciences - Rapid economic development and human activities have severely affected ecosystem function. Analysis of the spatial distribution of areas of rapid urbanization is...     

Isolation and pharmacological activities of bromophenols from Rhodomela confervoides

Four bromophenols were isolated from the extract of marine red alga,Rhodomela confervoides by column chromatography and HPLC methods. By means of spectroscopic methods inclding IR, MS, 1D, and 2D-NMR techniques, their structures were elucidated as (1) 3-bromo-4,5-dihydroxy benzoic acid methyl ester; (2) bis (2,3-dibromo-4,5-dihydroxybenzyl) ether; (3) 3,4-dibromo-5-(methoxymethyl)-1,2-benzenediol and (4) 3-bromo-4,5-dihydroxy-benzaldehyde. Compound 1 was first isolated from the algae in nature, and 1, 4 were found to have selective cytotoxic activities against KB, Bel 7402 and A549 cells, 2 showed powerful antibacterial activities againstStaphylococcus aurens andPseudomonas aeruginosa. Supported by National “863” Program (No. 2004AA625030, 2001AA620503), Quingdao marine sciences project (No. 04-2-NN-26) and Key Knowledge Innovative Project of the Chinese Academy of Sciences (KZCX3-SW-215).