Isolation and pharmacological activities of bromophenols from Rhodomela confervoides

Four bromophenols were isolated from the extract of marine red alga,Rhodomela confervoides by column chromatography and HPLC methods. By means of spectroscopic methods inclding IR, MS, 1D, and 2D-NMR techniques, their structures were elucidated as (1) 3-bromo-4,5-dihydroxy benzoic acid methyl ester; (2) bis (2,3-dibromo-4,5-dihydroxybenzyl) ether; (3) 3,4-dibromo-5-(methoxymethyl)-1,2-benzenediol and (4) 3-bromo-4,5-dihydroxy-benzaldehyde. Compound 1 was first isolated from the algae in nature, and 1, 4 were found to have selective cytotoxic activities against KB, Bel 7402 and A549 cells, 2 showed powerful antibacterial activities againstStaphylococcus aurens andPseudomonas aeruginosa. Supported by National “863” Program (No. 2004AA625030, 2001AA620503), Quingdao marine sciences project (No. 04-2-NN-26) and Key Knowledge Innovative Project of the Chinese Academy of Sciences (KZCX3-SW-215).     

相变存储材料Ge1Sb2Te4和Ge2Sb2Te5薄膜的结构和电学特性研究

采用射频磁控溅射方法制备了两种用于相变存储器的Ge₁Sb₂Te₄和Ge₂Sb₂Te₅相变薄膜材料,对其结构、电学输运性质和恒温下电阻随时间的变化关系进行了比较和分析.X射线衍射(XRD)和原子力显微镜(AFM)的结果表明:随着退火温度的升高,Ge₁Sb₂Te₄薄膜逐步晶化,由非晶态转变为多晶态,表面出现均匀的、     

Numerical analysis of the symmetric methods

Aimed at the initial value problem of the particular second-order ordinary differential equations,y =f(x, y), the symmetric methods (Quinlan and Tremaine, 1990) and our methods (Xu and Zhang, 1994) have been compared in detail by integrating the artificial earth satellite orbits in this paper. In the end, we point out clearly that the integral accuracy of numerical integration of the satellite orbits by applying our methods is obviously higher than that by applying the same order formula of the symmetric methods when the integration time-interval is not greater than 12000 periods.     

南大洋海冰影像地图投影变换与瓦片切割应用研究

南大洋海冰分布是南极考察过程中影响破冰船航行的重要因素,也是南极研究的重要内容之一。目前国际上不同机构发布的南大洋海冰分布图,大多是球面投影,不能直接用于主流的瓦片地图发布。将极方位立体投影海冰图转换为目前主流的网络墨卡托投影地图,并利用合适的图像重采样方法,按照不同级别比例尺进行瓦片切割和编号存储,最终实现海冰影像地图的发布共享是本文的主要研究内容。笔者对不同的图像重采样方法进行了比较,分析了最邻近点采样方法、双线性内插和双三次卷积重采样方法的优劣,针对本文的研究优选双线性内插方法进行影像地图瓦片的切割,并最终叠加融合在Google地图上,实现了Google底图、准实时海冰影像图与破冰船走航位置的集成显示,为雪龙船的冰区航行提供了重要的数据支撑。     

2005～2015年中国高校科研人才的时空变化及影响因素分析

基于2005~2015年全国统计年鉴数据,采用统计地图法和空间自相关分析,分析中国高校科研人才的时空分布特征（不包括港澳台数据）,并采用面板负二项回归模型,识别高校科研人才空间分布的决定因素。研究结果表明:①中国的高校科研人才分布表现出较强的空间不均衡性,总体趋势为东南密集,西北稀疏,科研人才高度集中在北京、天津、上海;②高校科研人才分布具有一定的空间集聚特征,其热点地区为北京、天津、上海和江苏等沿海省市,冷点地区集中分布在广大的西部地区和黑龙江省。2005~2015年,高级职称人才的空间集聚程度有所减弱,而中初级职称科研人才的空间集聚程度有所加强;③人才政策、高等教育规模和层次、公共服务水平和信息化水平是所有高校科研人才空间分布的主要影响因素。从职称差异的角度来看,薪酬和失业率等经济因素仅对初级职称科研人才的分布有影响,医疗、文化公共服务水平和人才政策仅对中高级职称科研人才的分布有影响,高等教育的规模与层次对各种职称人才的分布均有影响;从地区差异的角度来看,西部地区高校科研人才受到经济因素影响更为明显,而中东部高校科研人才受到公共服务水平影响的更为明显。     

A novel set pair analysis method based on variable weights for liquefaction evaluation

To ensure the safety of structures, high-speed railway and highway founded on liquefiable soils, liquefaction evaluation is a primary task. Herein, a dynamic set pair analysis method based on variable weights is introduced to assess liquefaction. A concept of connection degree of set pair consisting of the evaluation sample and the classification standard was described to interpret the uncertainty of liquefaction and relationship. Moreover, based on reward and penalty mechanism, state variable vectors were presented to assign composite weights of evaluation indicators in order to take into account impacts of indicator variation. And the integrated connection degree to each grade was calculated to evaluate liquefaction of the evaluated cases. Results from practical example and comparison with field investigation and extension method indicated that this proposed model used to evaluate liquefaction is feasible and effective. In addition, it can quantitatively describe liquefaction hierarchy of evaluated samples.     

春季季风间期赤道东印度洋浮游植物光合生理特征

Phytoplankton physiologies are dynamic and have sensitive responses to the ambient environment. In this paper,we examine photosynthetic physiologies of phytoplankton communities with Phyto-PAM in the eastern equatorial Indian Ocean during the spring inter-monsoon. Environmental parameters were measured to investigate the coupling between phytoplankton photosynthetic physiologies and their habitats. During the cruise, the water column was highly stratified. The mixed layer extended to about 75 m and was characterized by high temperature(28°C) and low nutrient level. The F_v/F_m values and chlorophyll a(Chl a) concentrations were lower at the surface, as consequences of nutrient depletion and photo-inhibition. Subsurface Chl a maximum(SCM) occurred between 75 and 100 m, and had the highest F_v/F_m values. The formation of SCM was a balance between nutrient availability and light limitation. The SCM may contribute significantly to pelagic food web and primary production in the water column. Phytoplankton in different layers encountered different light, trophic and hydrographic dynamics and evolved distinct photosynthetic characteristics. Despite of co-limitation of nutrient limitation and photo-inhibition, phytoplankton in the surface layer showed their acclimation to high irradiance, had lower light utilization efficiencies(α: 0.061±0.032) and could exploit a wide range of light irradiance. Whereas, phytoplankton in the SCM layers presented the highest light utilization efficiencies(α:0.146±0.48), which guaranteed higher photosynthetic capacities under low light level. These results provide insights into phytoplankton photo-adaption strategies in this less explored region.     

东海沉积物中轻矿物的研究

本文对东海大陆架、冲绳海槽及长江表层沉积物中的轻矿物进行了研究。调查区范围为121°-129°E,32°-26°30′N。长江采样区段为芜湖——长江口。共分析了124个样品,其中长江样品11个,东海大陆架样品100个,冲绳海槽样品13个。使用的样品粒级为0.1-0.25毫米。     

南黄海表层沉积物天然湿容重和含水量的分布及其与粒度之间的关系

本文论述了南黄海表层沉积物天然湿容重和含水量的分布,并利用回归分析的方法讨论了容重和含水量与粒度之间的关系。结果表明,容重和含水量与粘土粒级相关性最好,容重与粘土粒级含量(相似文献   

细基江蓠脂肪酸组成研究

研究表明,南海细基江蓠Gracilaria tenuistipitata中主要含有C_9—C_(30)一元饱和脂肪酸,其中n-十六酸含量占脂肪酸组分的40％以上。单烯和二烯酸的含量较低,缺乏多烯酸及前列腺素类化合物。此外,还含有少量二元酸类、4-及5-羰基羧酸,其中后两者是首次在红藻中发现。南海细基江蓠的脂肪酸组成特征与南海海域水质较清、光照充足及水温较高等环境因素有关。