激光囚禁放射性氪同位素技术测量地下水年代

地下水年代测定对于了解地下水循环具有十分重要的意义。放射性氪同位素⁸⁵Kr（半衰期10.8a）、⁸¹Kr（半衰期0.23Ma）具有十分理想的地球物理化学特性,十分适于对溶解了大气的水或冰样品进行绝对年代测定。由于样品中的放射性氪原子量极少,利用⁸¹Kr含量进行地下水测年时需要数吨水样品才能完成(Earth and Planetary Science Letters,2000,182：103～113;Geophysical Research Letters,2004,31: L05503)。本文主要介绍我们在中国科学技术大学建立的激光冷却氪原子测量装置,该系统已经成功地对氪原子进行了激光冷却和囚禁,实现了单个放射性氪原子⁸¹Kr和⁸⁵Kr的计数测量。氪原子的冷却捕获速率被大幅提高,预计测年应用中所需样品量可减小一个量级以上,这将使得我们可以开展新的地下水年代测定应用。     

激发极化法在四川红层地区水资源勘察中的应用

阐述了激发极化法的基本原理和技术方法,利用激发极化法的极化率、电阻率、衰减度半衰时、充电率等极化参数在四川红层地区寻找地下水,并探讨了红层地区的含水层位,以及含水层位的确定。该方法受地形影响小,曲线反映异常直观,能有效解决红层地区的找水任务。     

一种测定非饱和土-水力学参数的方法

详细介绍了非饱和土-水力学参数联合测试系统,该系统分别利用轴平移技术和达西定律测定非饱和土土-水特征曲线和水相渗透系数。通过试验结果对比可以发现,由联合测试系统确定土-水特征曲线与压力板仪溢出水校正称量法确定的土-水特征曲线接近,但由联合测试系统确定的试样残余含水率比使用压力板仪溢出水校正称量法确定的试样含水率要小;由联合测试系统确定的渗透函数,当饱和度较大时,实测值与模型预测值较为接近;当饱和度较小时,实测值与模型预测值相差较大。     

鉴定热处理琥珀的关键证据

在琥珀热处理实验研究的基础上,采用常规宝石学方法和红外光谱仪,测试并跟踪收集和对比分析了实验样品热处理前、后的宝石学参数和红外光谱的变化规律及琥珀内含物的演化、改造与破坏标识,并对获得的琥珀热处理效果进行了成因分析,从而总结出鉴定琥珀热处理的关键证据。研究结果表明：（1）折射率的增加、荧光的弱化或湮灭是热处理琥珀的重要佐证;（2）盘状裂隙、红色流纹、汽化纹、龟裂纹和氧化裂纹是热处理琥珀的重要标识;（3）FTIR光谱中I=2930cm-1/I=1735cm-1比值若≤1,可视为热处理琥珀的红外光谱指纹检测依据;（4）1735,1700cm-1处的羰基（C？O）伸缩振动与1260～1156cm-1处的C—O伸缩振动吸收强度的明显增强及多峰合并的趋势反映出热处理琥珀表面的热氧化反应;C？O浓度的增加可能是热处理琥珀红色的生色团,同时又是热处理琥珀荧光的淬灭剂。     

Speciation analysis of metals （Tl, Cd and Pb） in Tl-containing pyrite and its cinder from Yunfu Mine, China, by ICP-MS with sequential extraction

The speciation of heavy metals such as thallium, cadmium and lead existing in pyrite and pyrite cinder was analyzed by ICP-MS with a sequential extraction procedure. The distribution patterns of these metals including exchangeable, reducible, oxidizable and residual fractions were obtained. Tl, Cd and Pb in pyrite and pyrite cinder samples from each extraction step were determined by inductively coupled plasma mass spectrometry (ICP-MS). Under the optimized instrumental conditions, detection limits of Tl, Cd and Pb in different matrices were within the range of 0.006–0.07 μg/L, and the relative standard deviations ranged from 0.8% to 1.2%. The accuracy of Tl, Cd and Pb determination was checked by analyzing two certified reference materials. The results demonstrate that trace Tl, Cd and Pb in the samples can be accurately determined. The sequential extraction results revealed that the percent contents of Tl, Cd and Pb in exchangeable, reducible and oxidizable fractions in pyrite cinder are different from those in pyrite and in pyrite cinder. Tl, Cd and Pb mostly are distributed in residual fraction. Therefore, the mobility of metals in pyrite is higher than that in pyrite cinder. Although distributions of Tl, Cd and Pb in the non-residual fraction are not dominant in pyrite cinder, the total concentrations of them could not be ignored. Consequently, attention must be paid to the risk of potential pollution by pyrite cinder.     

工程桩静载试验确定PHC管桩承载力

以工程实例介绍静压管桩基础的设计承载力取值,采用先施工工程桩进行静载试验,以其结果反算单桩竖向承载力,结合桩的入土长度等给出应用于工程实际的单桩竖向承载力设计值(R)的方法,供同行借鉴。     

松辽盆地上白垩统青山口组介形虫群集性死亡事件成因

松辽盆地上白垩统青山口组发育含大量介形虫化石的介形虫层,介形虫层的单层厚约5～200cm。介形虫层具有低伽马、高电阻、低声波等测井响应特征。以测井资料识别介形虫层为基础,研究了介形虫层在平面上不同相带及其在纵向高频层序格架下的分布规律,探讨了介形虫群集性死亡的原因。介形虫层平面上主要分布在大庆、龙虎泡—红岗阶地、黑帝庙等环坳带,盆地东部相对不太发育,滨浅湖是介形虫生存的有利环境;纵向上主要分布在青一段上部及青二段。高频层序旋回控制了介形虫的繁殖与死亡,介形虫群集性死亡事件主要发生在基准面下降期间。介形虫的群集性死亡与湖泊面积扩大无关,更与海侵事件无关。基准面下降造成水体变浅、矿化度增高以及砂岩进入滨浅湖可能是导致介形虫群集性死亡的直接原因。     

Origin of the patchy emission pattern at the ZERT CO<Subscript>2</Subscript> release test

A numerical experiment was carried out to test whether the patchy CO₂ emission patterns observed at the Zero Emissions Research and Technology release facility are caused by the presence of packers that divide the horizontal injection well into six CO₂-injection zones. A three-dimensional model of the horizontal well and cobble–soil system was developed and simulations using TOUGH2/EOS7CA were carried out. Simulation results show patchy emissions for the seven-packer (six-injection-zone) configuration of the field test. Numerical experiments were then conducted for the cases of 24 packers (23 injection zones) and an effectively infinite number of packers. The time to surface breakthrough and the number of patches increased as the number of packers increased suggesting that packers and associated along-pipe flow are the origin of the patchy emissions. In addition, it was observed that early breakthrough occurs at locations where the horizontal well pipe is shallow and installed mostly in soil rather than the deeper cobble. In the cases where the pipe is installed at shallow depths and directly in the soil, higher pipe gas saturations occur than where the pipe is installed slightly deeper in the cobble. It is believed this is an effect mostly relevant to the model rather than the field system and arises through the influence of capillarity, permeability, and pipe elevation of the soil compared to the cobble adjacent to the pipe.     

河南水灾变化及典型水灾年大气环流异常特征分析

利用河南1950-2007年的逐年水灾统计数据,对水灾年的时间特征进行分析,并对典型水灾年大气环流的异常特征进行分析,结果表明:在1950-2007年的58 a中,河南年年都出现水灾,全省水灾受灾面积66.7万hm2的有28年;66.7万hm2的有30年,约2年一遇;受灾面积133.3万hm2的有17年,约4年一遇;333.3万hm2的有4年,约15年一遇。在河南的典型水灾年,中高纬度的长波和南支系统都有很强的稳定性;亚洲中高纬阻塞形势非常明显,在西西伯利亚上空出现了强烈的偏北风分量,因而冷空气暴发南下非常频繁;副热带高压脊线在24°N左右,584 dgpm线呈西南东北走向,将来自孟加拉湾和南海的充沛水汽带到内陆。河南省正处于来自北方的冷空气和南支系统带来的暖湿气流交汇的区域,这是造成河南省出现严重水灾的主要原因。