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981.
Luis O'Dogherty Agustín Martín-Algarra Hans-Jürgen Gursky Roque Aguado 《International Journal of Earth Sciences》2001,90(4):831-846
Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps. 相似文献
982.
High-temperature creep behavior in Ni2GeO4 spinel was investigated using synthetic polycrystalline aggregates with average grain sizes ranging from submicron to 7.4
microns. Cylindrical samples were deformed at constant load in a gas-medium apparatus at temperatures ranging from 1223 to
1523 K and stresses ranging from 40 to 320 MPa. Two deformation mechanisms were identified, characterized by the following
flow laws:
where σ is in MPa, d is in μm and T is in Kelvin. These flow laws suggest that deformation was accommodated by dislocation creep and grain-boundary diffusion
(Coble) creep, respectively. A comparison with other spinels shows that an isomechanical group can be defined for spinels
although some differences between normal and inverse spinels can be identified. When creep data for olivine and spinel are
normalized and extrapolated to Earth-like conditions, spinel (ringwoodite) has a strength similar to olivine in the dislocation
creep regime and is considerably stronger than olivine in the diffusion creep regime at coarse grain size. However, when grain-size
reduction occurs, spinel can become weaker than olivine due to its high grain-size sensitivity (Coble creep behavior). Analysis
of normalized diffusion creep data for olivine and spinel indicate that spinel is weaker than olivine at grain sizes less
than 2 μm.
Received: 18 June 2000 / Accepted: 3 April 2001 相似文献
983.
In this paper, numerical methods for flow simulation in the well vicinity are discussed. Flux truncation errors are analyzed on gridblocks near the well. Due to the singularity of the well, standard numerical schemes are not efficient for near well flow simulations. To improve simulation accuracy, a new methodology, using a change of coordinates to make near well pressure linear, is presented for the singularity modelling. Based on this new approach, two numerical schemes, a two-point flux approximation scheme and a multi-point one, are proposed. These schemes are accurate for the near well modelling and are suitable for any kinds of gridblocks. 相似文献
984.
K. Kusaka K. Hagiya M. Ohmasa Y. Okano M. Mukai K. Iishi N. Haga 《Physics and Chemistry of Minerals》2001,28(3):150-166
The structures of Ca2CoSi2O7, Ca2MgSi2O7, and Ca2(Mg0.55Fe0.45)Si2O7 have been determined in the temperature range between 297 and 773 K with arbitrary intervals. The structures of the incommensurate
phase of the three compounds are characterized by the presence of the six-, seven-, and eight-coordinated Ca–O polyhedra and
of the bundles along the c-axes consisting of four arrays of the six-coordinated Ca–O polyhedra and an array of T1O4 (T1: Co, Mg, or Mg–Fe) tetrahedra in the structures. The number of bundles in each material decreases at elevated temperatures.
The incommensurate phase undergoes a phase transition into the normal phase at 493 K in Ca2CoSi2O7, at 360 K in Ca2MgSi2O7, and at 510 K in Ca2(Mg0.55Fe0.45)Si2O7. The features of the structures of the normal phase are almost the same as those found in the basic structures (the averaged
structures of the incommensurate structures), and this fact implies that the characteristics of the structures, such as the
six-coordinated Ca–O polyhedra or fragments of the bundles, should be partially preserved at higher temperatures both in the
incommensurate structures and also in the structures of the normal phase. Analyses of anisotropic displacement parameters
clarified that disorder of the modulation waves is developed in the structures at higher temperatures. The evolution of a
disorder in the structures was ascertained by observation of the circular diffuse streaks in the vicinity of the transition
temperature between the incommensurate and normal phases.
Received: 3 July 2000 / Accepted: 26 October 2000 相似文献
985.
The incorporation of hydrogen (deuterium) into the coesite structure was investigated at pressures from 3.1 to 7.5 GPa and
temperatures of 700, 800, and 1100 °C. Hydrogen could only be incorporated into the coesite structure at pressures greater
5.0 GPa and 1100 °C . No correlation between the concentration of trace elements such as Al and B and the hydrogen content
was observed based on ion probe analysis (1335 ± 16 H ppm and 17 ± 1 Al ppm at 7.5 GPa, 1100 °C). The FTIR spectra show three
relatively intense bands at 3575, 3516, and 3459 cm−1 (ν1 to ν3, respectively) and two very weak bands at 3296 and 3210 cm−1 (ν4 and ν5, respectively). The band at 3516 cm−1 is strongly asymmetric and can be resolved into two bands, 3528 (ν2a) and 3508 (ν2b) cm−1, with nearly identical areas. Polarized infrared absorption spectra of coesite single-crystal slabs, cut parallel to (0 1
0) and (1 0 0), were collected to locate the OH dipoles in the structure and to calibrate the IR spectroscopy for quantitative
analysis of OH in coesite (ɛ
i
,tot=190 000 ± 30 000 l mol−1
H2O cm−2). The polarized spectra revealed a strong pleochroism of the OH bands. High-pressure FTIR spectra at pressures up to 8 GPa
were performed in a diamond-anvil cell to gain further insight into incorporation mechanism of OH in coesite. The peak positions
of the ν1, ν2, and ν3 bands decrease linearly with pressure. The mode Grüneisen parameters for ν1, ν2, and ν3 are −0.074, −0.144 and −0.398, respectively. There is a linear increase of the pressure derivatives with band position which
follows the trend proposed by Hofmeister et al. (1999). The full widths at half maximum (FWHM) of the ν1, ν2, and ν3 bands increase from 35, 21, and 28 cm−1 in the spectra at ambient conditions to 71, 68, and 105 in the 8 GPa spectra, respectively. On the basis of these results,
a model for the incorporation of hydrogen in coesite was developed: the OH defects are introduced into the structure by the
substitution Si4+(Si2)+4O2−= [4]□(Si2) + 4OH−, which gives rise to four vibrations, ν1, ν2a, ν2b, and ν3. Because the OH(D)-bearing samples do contain traces of Al and B, the bands ν4 and ν5 may be coupled to Al and/or B substitution.
Received: 19 December 2000 / Accepted: 23 April 2001 相似文献
986.
An experimental study of the effect of iron on magnesiochloritoid-talc-clinochlore-kyanite stability
The influence of Fe on the reaction clinochlore+kyanite&ding3F;magnesiochloritoid+talc (1) was determined experimentally as a function of pressure (1.6-2.6 GPa) and composition at 600 and 540 °C. Analytical electron microscopy (AEM) was used to determine the compositions of the coexisting phases in these complex multiphase run products. Within the compositional range studied (xFebulk=0.12-0.34), chlorite solid solutions were always richer in magnesium than the coexisting chloritoid solid solutions. Fractionation of Fe into the chloritoid extends the stability field of the assemblage chloritoid plus talc towards lower pressures. However, the extent of the stability field for increasing xFe is less than one would expect for ideal mixing behaviour in chloritoid and chlorite, and indicates a moderate positive deviation from ideality for chloritoid solid solutions. The thermodynamic data for magnesiochloritoid given in two earlier studies are in good agreement with the present experiments, those of a third study yield pressures which are much too high, at least compared with the experiments at 600 °C. 相似文献
987.
An 18-yr chlorophyll time series for Narragansett Bay based on weekly samples collected without regard to tidal phase revealed a long-term decrease in mean annual levels. The potential influence of neglecting tidal phase in the sampling strategy on measured chlorophyll and its apparent long-term decrease is evaluated. A two year data set (1995–1996) is used as a proxy for the 1973–1990 time series together with an observed relationship between continuous measurements of in situ chlorophyll fluorescence and accompanying tidal phase. The deviations in chlorophyll from long-term means relative to deviations from mean low water at the time of sample collection are also analyzed, as is the potential influence of tidally-induced advective increases or dilution on measured chlorophyll levels. The analyses, which compare the magnitude and trends in tidally adjusted and directly measured chlorophyll, indicate that semi-diurnal intratidal variations in chlorophyll had little apparent effect on the long-term and seasonal patterns and trends deduced from the chlorophyll measurements. Neither tidal advection of the chlorophyll gradient, nor bloom magnitude appear to compromise application of the model. The 18-yr decline in annual mean chlorophyll observed between 1973–1990 in narragansett Bay is considered to be a bonafide portrayal of actual events, and not an artifact of failure to consider tidal phase in the weekly sampling strategy. The results also suggest that intratidal variability in chlorophyll does not seriously confound its meaningful measurement and usefulness as a representative index of phytoplankton abundance at the permanent monitoring station established for Narragansett Bay. Nonetheless, there is need to refine and to incorporate temporal sampling strategies more closely attuned to the tempo of growth, grazing, and nutrient recycling which accompany estuarine phytoplankton dynamics. 相似文献
988.
989.
C.Y. Ji 《ISPRS Journal of Photogrammetry and Remote Sensing》1996,51(6):268-283
Agricultural field boundary information is important in the study of agricultural crops by remote sensing. In this paper, the dyadic wavelet transform is adopted to extract field boundaries directly from TM imagery. A field boundary is a set of locally connected pixels characterized by their abrupt spectral intensity variation (singularity) on the image. Preliminary extraction is made on the near-infrared Band 4 (0.76–0.90 μm) image. It is found that most of the boundaries are well characterized by the wavelet modulus maxima curves, particularly for fully vegetated fields, while better results are obtained from the NDVI image for cropped field boundaries. To extract additional boundaries while suppressing unwanted noisy edges, the wavelet transform is then applied to the Wetness image calculated by the Tasselled Cap Transform. A technique is implemented to integrate the edges extracted from each source. The combined results show that the majority of the field boundaries are delineated. The use of a single date image fails to delineate some of the fallow field boundaries and boundaries between two cropped fields with similar spectral properties. Although techniques have been applied to reduce noise, still great difficulties are encountered when trying to delineate edges that are field boundaries from all the detected singularities. Manual editing is still required to trace the remaining boundaries to obtain a complete boundary map. It is recommended that a multi-temporal data set be used to obtain a complete delineation with a fully automated algorithm. 相似文献
990.
大气臭氧与气溶胶垂直分布的高空气球探测 总被引:17,自引:2,他引:17
本文给出了1993年9月12日利用高空科学气球在河北省香河地区探测到的大气臭氧和气溶胶的垂直分布。结果发现:(1) 大气臭氧的数密度在整个对流层较低(~10[12]mol/cm3),并从地面到对流层顶略有下降;对流层顶以上开始快速增加,极值层高度在~24 km,其值为4.78×10[12]mol/cm3;臭氧分压有类似的分布特征,极值146×10[-4]Pa,位于同一高度;(2) 在平流层低层,臭氧分压有一个次极值62×10[-4]Pa,位于15~16 km;(3) 0~30 km大气气溶胶数密度呈现出三个峰值:143,8和1.1 个/cm[3],分别位于近地面、5 km和21 km;(4)气溶胶的数密度谱在对流层为双模态;在平流层,次峰消失。同时,我们还与其他观测结果作了比较分析。 相似文献