The sulfurization recorded in tridymite in the monomict eucrite Northwest Africa 11591

Some of the tridymite in the monomict Northwest Africa (NWA) 11591 eucrite are found to have sulfide‐rich replacement textures (SRTs) to varying degrees. The SRTs of tridymite in NWA 11591 are characterized by the distribution of loose porous regions with aggregates of quartz and minor troilite grains along the rims and fractures of the tridymite, and we propose a new mechanism for the origin of this texture. According to the volume and density conversion relationship, the quartz in the SRT of tridymite with a hackle fracture pattern was transformed from tridymite. We suggest that the primary tridymite grains are affected by the S‐rich vapors along the rims and fractures, leading to the transformation of tridymite into quartz. In addition, the S‐rich vapors reacted with Fe²⁺, which was transported from the relict tridymite and/or the adjacent Fe‐rich minerals, and/or the S‐rich vapors react with the exotic metallic Fe to form troilite grains. The sulfurization in NWA 11591 most likely occurred during the prolonged subsolidus thermal metamorphism in the shallow crust of Vesta and might be an open, relatively high temperature (>800 °C) process. Sulfur would be an important component of the metasomatic fluid on Vesta.     

Tide-induced Lagrangian residual velocity and dynamic analysis based on field observations in the inner Xiangshan Bay,China

In the Xiangshan Bay at the east coast of China, coastal marine pollution is conspicuous and severe in recent years. As transport of the pollutants is closely related to the coastal circulation, there is a great practical significance to investigate the circulation in this area. In this work, the surface pattern and vertical profiles of Lagrangian residual velocity (LRV) were studied based on field observation data from the inner Xiangshan Bay. By tracking GPS-GPRS drifters’ trajectories, the surface LRV pattern is going out in the central deep trough and flowing inwards near the shoreside. Combined with data from two mooring stations, vertical profiles of LRV is flowing out at surface and flowing in at the bottom, consistent with the gravitational circulation induced by baroclinic effects at the estuary. However, according to the diagnostic analysis, the main mechanism driving the residual current is barotropic rather than baroclinic. The LRV equation is controlled by the tidally-averaged barotropic pressure gradient force, tidal body force and tidally-averaged turbulent stress, while the tidally-averaged baroclinic pressure gradient force is one order of magnitude less than other forces. Additionally, the tidally mean eddy viscosity coefficient which is used in the expression of tidally-averaged turbulent stress might be not adequate and requires further studies.     

地理国情监测水面数据时空一致性优化方法

地理国情监测利用遥感、地理信息等技术,动态获取地表覆盖等多样化的地理要素,经统计、分析、评价和应用,服务于政治、经济、文化、资源、环境等多个领域,为政府提供全面、准确、基础的地理信息情报。针对地理国情监测在全国范围基于多时相遥感影像采集水面信息存在时空不一致性的现状,提出一种基于精细DEM的水面数据时空一致性优化方法。利用栅格图形区域生长算法,采用8邻域算子,对水面种子点进行迭代生长计算,得出基于精细DEM的区域生长结果;通过与地理国情监测水面数据对比分析,实现空间化结果的修正,从而达到时空一致性优化的目的。分析了典型研究区水面数据特征,利用该方法进行了优化处理,结果显示：研究区水面数据空间范围相对于时点监测修正了7.99%,满足了地理国情监测时点一致性需求。研究表明：该方法的应用,能够使得在全国尺度上统计的水面数据反映同一季节或可接受时段内的状况,避免或缩小了由于影像数据源的差异造成的时间和空间上的不一致性带来的误差,满足了地理国情监测时点一致性需求,能够在地理国情监测等地表覆盖水面信息提取、优化中推广应用,为政府有效决策提供客观、准确和基础的水面信息。     

boldmath Investigation of inter-molecular hydrogen bonding in the binary mixture (acetone + water) by concentration dependent Raman study and ab initio calculations

This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding.     

Single electron loss in the collisions of C3 + and atomic hydrogen

This paper studies the projectile electron loss cross sections of C^{3 +} colliding with atomic hydrogen in the frame work of extended over-barrier model at intermediate velocities (25 keV/u--600 keV/u). The electron loss is calculated in terms of the interaction between the screened target nucleus and the active projectile electron and of the interaction between projectile electron and target electron. Compared with the convergent close-coupling calculations, screening and anti-screening calculations, this model satisfactorily reproduces the experimentally obtained energy dependence of the electron-impact ionisation cross sections and the single electron loss cross sections over the energy range investigated here.     

湍流度随高度的变化及其对城市宏观地形的依赖

分别构建广州主建成区垂直比例尺为1﹕2 000、1﹕1 000和1﹕500的3个建筑物模型,利用大型边界层风洞,在西北和东南两风向下,基于中性流模拟分析了复杂城市地形下湍流度随高度的变化及其对宏观地形的依赖。结果表明：风廓线指数α与不同高度的湍流度之间的关系密切,利用现有模型,根据4类粗糙度边界层和不同垂直比例尺,可确定相应的湍流度随高度变化模型的主要系数,预测精度高。城市地形下最大湍流度面发育在0~0.2 h之间狭窄的范围内。用湍流度形态指数β来表征湍流度随高度的变化,无论城市屋脊还是平坦地形,随着风程区的延伸,廓线的指数α升高,湍流度形态指数β降低。表明同一高度湍流度值具有由迎风区、丘顶区向背风区增高,沿风程逐渐增大的规律,对地形部位和风程的依赖性强,与来流翻越简单地形时的特征一致。     

Comparisons of several evaporation/precipitation datasets for the Bohai Sea based on salinity simulation

Evaporation (E) rate and precipitation (P) rate are two significant meteorological elements required in the ocean baroclinic modeling as external forcings. However, there are some uncertainties in the currently used E/P rates datasets, especially in terms of the data quality. In this study, we collected E/P rates data from ERA-40, NCEP/NCAR Reanalysis, HOAPS for the Bohai Sea and nine routine stations around Laizhou Bay, and made comparisons among them. It was found that the differences in E/P rates between land and sea are remarkable, which was due to the difference in underlying surfaces. Therefore, the traditional way of using E/P rates acquired on land directly at sea is not correct. Since no final conclusion has been reached concerning the net water transport between the Bohai Sea and the Yellow Sea, it is unfeasible to judge the adequacy of the four kinds of data by using the water budget equation. However, the E/P rates at ERA-40 sea points were considered to be the optimal in terms of temporal/spatial coverage and resolution for the hindcast of salinity variation in the Bohai Sea. Besides, using the 3-D hydrodynamic model HAMSOM (HAMburg Shelf Ocean Model), we performed numerical experiments with different E/P datasets and found that the E/P rates at sea points from ERA-40 dataset are better than those from NCEP/NCAR Reanalysis dataset. If NCEP/NCAR Reanalysis E/P rates are to be used, they need to be adjusted and tested prior to simulation so that more close-to-reality salinity values can be reproduced.     

新疆少数民族文字地图的编制方法研究

介绍少数民族文字(维吾尔文)在地图编制中的应用。从编制方法及少数民族文字(维吾尔文)处理技巧等方面,阐述该技术在地图编制中的实现。     

改革开放以来广东省区域差异的发展变化

本文主要研究改革开放以来广东省区域差异发展变化的趋势及特点。在确定了研究的方法,采用的指标后,文章从三个方面,及全省区域差异的总体状况;省内各区之间的差异;省内各区内部的差异,分析了广东省1980—1990年区域差异的发展变化。研究表明自改革开放以来广东省的区域差异迅速扩大,且主要体现在珠江三角洲与全省其余各地差异的扩大;虽然在改革开放的初期三角洲内部的差异就比较明显,但1980年以来三角洲呈现出很强的均衡发展的特点;区域差异发展的特点与广东改革开放以来实行的一系列政策有明显的因果关系。最后,文章探讨了缩小广东省区域差异的措施。     

A Preliminary Study on Dust Grains in the Stratosphere

Collected by means of a high-altitude scientific balloon and a self-made automatic sample collector,a total of 276 dust grains were selected for the study of shape,grain size and optical property.Some of the grains were examined by X-ray diffraction and electrom microprobe techniques,The stratospheric dust grains can be classified as 6 types:cosmic dusts,cosmic dusts(?),microtektite,natural pollutants,artificial pollutants and the unknown substances.The different types of dust grains have different characters and distinguishing symbols.Widespread in the space of the solar system,cosmic dusts are the initial substances of the solar system and ,to some degree,have recorded a great wealth of information on the early history of the solar system.So they have become one of the important objects in the field of cosmochemistry at present time,Since the 1960‘s,scholars of many countries have collected cosmic dusts both in the space near the earth(using rock ets,space probes and space shuttles)and in the stratosphere (using high-altitude balloons or U-2air planes).According to the shape(the scanning electron microimage),element composition(the energy-dispersive X-ray spectrum)and optical properties of dust grains,the substances in the stratosphere can be classified as 5 types:cosmic dusts,alumina spheroids,terrestrial artificial pollutants,terrestrial natural pollutants and unknown substances(CDPET,1982).