Interference Testing for Atmospheric HOx Measurements by Laser-induced Fluorescence

Accurate OH and HO₂ (collectively called HO_x) measurements by laser-induced fluorescence (LIF) may be contaminated by spurious signals from interfering atmospheric chemicals or from the instrument itself. Interference tests must be conducted to ensure that observed OH signal originates solely from ambient OH and is not due to instrument artifacts. Several tests were performed on the Penn State LIF HO_x instrument, both in the laboratory and in the field. Theseincluded measurements of the instrument's zero signal by using either zero air or perfluoropropylene to remove OH, examination of spectral interferences from naphthalene, sulfur dioxide, and formaldehyde, and tests of interferences by addition of suspected interfering atmospheric chemicals, including ozone, hydrogen peroxide, nitrous acid, formaldehyde, nitric acid, acetone, and organic peroxy radicals (RO₂). All tests lacked evidence ofsignificant interferences for measurements in the atmosphere, including highly polluted urban environments.     

论产业部门内经济结构的调整和优化

剖析了我国产业部门经济结构和运行机制存在的问题及形成这些问题的原因,并对产业部门经济结构的调整和优化组合的途径进行了探讨。     

南海北部陆坡沉积记录的全新世早期夏季风极强事件

在AMS14C精确定年的基础上,通过南海北部MD05-2905站高分辨率的氧同位素、粒度、元素分析,其结果显示所有指标均在11.2～8.5kaB.P.期间发生异常,根据夏季风指标认为这是夏季风极强事件。将本站位相同纬度（20°N）的夏季平均日辐射量与季风指标进行对比,发现全新世早期（11.2～8.5kaB.P.）东亚夏季风极强事件对应着夏季太阳辐射量最大值和热带辐合带（ITCZ）的位置向北移动,说明全新世早期夏季风突然增强可能是在岁差周期控制下,较高的太阳辐射量驱动了热带辐合带（ITCZ）及其有关的雨场向北移动,在南海北部产生了大量的降水,导致氧同位素偏负、碳酸盐的含量较低以及线性沉积速率较高。这与前人对相邻地区湖光岩玛珥湖的孢粉研究、江西南岭地区泥炭的记录以及中国南方石笋记录的研究结果相吻合。该季风最强事件与阿拉伯海发现的早全新世季风最强事件以及根据格陵兰冰芯记录的早全新世甲烷最大值推测低纬地区湿地扩张相一致,这反映了南海北部全新世早期与全球低纬地区早全新世气候变化格局一致。     

国家屏障区生态系统服务权衡与协同

对不同服务间存在的此消彼长的权衡关系和相互增益的协同关系的正确认知,是开展多种生态系统服务可持续管理决策的前提。2018年国家重点专项“典型脆弱生态修复与保护研究”中明确指出要优化“两屏三带”生态系统服务格局,而服务的优化离不开对权衡与协同关系的准确认知。因此,在国家尺度上开展国家屏障区生态系统服务权衡与协同研究具有重要性和迫切性。本文采用RUSLE模型、CASA模型和InVEST产水模型分别评估国家屏障区2000—2015年土壤保持、固碳和产水服务的空间分布格局,并分析三种服务的变化趋势,采用相关分析法和均方根偏差法量化不同服务在各子屏障带整体和空间上的权衡与协同关系。结论如下：① 国家屏障区的三项服务在空间上均呈现由东南向西北减少的格局, 而在时间上,土壤保持与产水显著增加(p<0.05),增加量分别为 20.64 t/(km ²·a)和4.13mm/a,而固碳呈现微弱的上升趋势(p=0.96),服务的提升有利于保障国家生态安全。② 在各子屏障带整体上,土壤保持、固碳及产水间相关系数基本大于0（p<0.05）,表明三者以协同为主;而在空间上,两两服务间的权衡与协同关系存在着极强的空间异质性,如东北森林带固碳与产水、固碳与土壤保持的权衡关系像元比例分别达49%和27%,且均集中在北部。因此,在进行生态环境建设时,需要同时考虑到整体与局部空间的服务权衡与协同关系的不同,以制定更为合理的生态保护政策。     

植硅体记录的敦化北部山地近2 ka泥炭沼泽演化气候背景

对敦化北部山地205 cm深泥炭剖面中的植硅体进行提取、鉴定和分析,结合AMS¹⁴C测年,重建研究区近2 ka的古气候环境过程,探讨其变化规律及影响因素。植硅体组合、有序聚类和植硅体指数变化趋势显示,研究区泥炭沼泽经历了4个显著阶段：即45-680 A.D.暖湿阶段;680-1340 A.D.温暖偏干阶段;1340-1870 A.D.由干转湿的寒冷阶段;1870-2017 A.D.转暖、干湿波动阶段。其中,680-1225 A.D.对应中世纪暖期（MWP）,1340-1870 A.D.对应小冰期（LIA）。在此气候变化背景下,泥炭沼泽发展经历了由缓慢逐渐加快的过程。对比太阳辐射和太阳活动的变化、石笋δ¹⁸O序列、重建的东北地区古温度以及Niño3.4重建曲线,泥炭剖面的植硅体分析显示MWP和LIA期间的古气候过程受到太阳活动、太阳辐射、季风环流和ENSO（El Niño-Southern Oscillation）的控制。     

利用全方位P波属性进行裂缝检测的地震方法

胜利油田存在着一种特殊的裂隙性油气藏,即泥岩裂隙油气藏。由于该类裂隙储层的孔隙度很小,岩石物性参数变化不灵敏,并表现出很强的各向异性,因此,其勘探难度很大。到目前为止,国内外还没有一套成熟的地质、物探、测井及钻井等资料综合分析的裂隙方位、分布、密度的识别方法。本文在研究国外裂缝检测方法的基础上,提出了波阻抗随方位变化(IPVA)的新方法,结合罗家地区的泥岩裂隙地震地质特征,研究了利用多方位 P 波资料检测定向垂直裂缝的地震采集、处理和识别方法,对不同共中心点 CMP 位置的全方位 P 波资料在速度随方位变化(VVA)及振幅随方位角变化(RVA)研究的基础上,进行波阻抗随方位变化(IPVA)的研究,用于识别裂缝的分布、走向及密度。经罗家地区实际资料的应用,见到了初步的效果,证明该方法是潜力较大的高角度裂隙的定量检测方法。     

A study of transport and impact strength of Fukushima nuclear pollutants in the north pacific surface

Based on the statistics of surface drifter data of 1979–2011 and the simulation of nuclear pollutant particulate movements simulated using high quality ocean reanalysis surface current dataset, the transport pathways and impact strength of Fukushima nuclear pollutants in the North Pacific have been estimated. The particulates are used to increase the sampling size and enhance the representativeness of statistical results. The trajectories of the drifters and particulates are first examined to identify typical drifting pathways. The results show that there are three types of transport paths for nuclear pollutants at the surface: 1) most pollutant particles move eastward and are carried by the Kuroshio and Kuroshio-extension currents and reach the east side of the North Pacific after about 3.2–3.9 years; 2) some particles travel with the subtropical circulation branch and reach the east coast of China after about 1.6 years according to one drifter trajectory and about 3.6 years according to particulate trajectories; 3) a little of them travel with local, small scale circulations and reach the east coast of China after about 1.3–1.8 years. Based on the particulates, the impact strength of nuclear pollutants at these time scales can be estimated according to the temporal variations of relative concentration combined with the radioactive decay rate. For example, Cesium-137, carried by the strong North Pacific current, mainly accumulates in the eastern North Pacific and its impact strength is 4% of the initial level at the originating Fukushima area after 4 years. Due to local eddies, Cesium-137 in the western North Pacific is 1% of the initial pollutant level after 1.5 years and continuously increases to 3% after 4 years. The vertical movement of radioactive pollutants is not taken into account in the present study, and the estimation accuracy would be improved by considering three-dimensional flows.     

广义极值分布的适线法应用

广义极值分布频率曲线,也可采用均值、变差系数和偏态系数等三个统计参数来进行计算。通过建立离均系数表,可以方便地进行频率分析计算。现以澧水某站年最大流量系列为例,采用广义极值分布的适线法进行频率分析计算,成果表明广义极值分布具有一定适应性。     

土壤斥水性及其生态水文效应研究进展

土壤斥水性是指水分不能或很难湿润土壤颗粒表面的物理现象。土壤斥水性是一个全球性现象,可以出现在各种气候背景、土壤类型和植被覆盖条件下,并且影响到地表水文过程的诸多重要环节,因此受到广泛关注。有关土壤斥水性的研究是表面科学、生物学、土壤学以及物理学等学科交叉的前沿研究领域,已成为国际生态水文学研究的重要核心科学问题。复杂...     

A global ocean reanalysis product in the China Ocean Reanalysis (CORA) project

The first version of a global ocean reanalysis over multiple decades (1979–2008) has been completed by the National Marine Data and Information Service within the China Ocean Reanalysis (CORA) project. The global ocean model employed is based upon the ocean general circulation model of the Massachusetts Institute of Technology. A sequential data assimilation scheme within the framework of 3D variational (3DVar) analysis, called multi-grid 3DVar, is implemented in 3D space for retrieving multiple-scale observational information. Assimilated oceanic observations include sea level anomalies (SLAs) from multi-altimeters, sea surface temperatures (SSTs) from remote sensing satellites, and in-situ temperature/salinity profiles. Evaluation showed that compared to the model simulation, the annual mean heat content of the global reanalysis is significantly approaching that of World Ocean Atlas 2009 (WOA09) data. The quality of the global temperature climatology was found to be comparable with the product of Simple Ocean Data Assimilation (SODA), and the major ENSO events were reconstructed. The global and Atlantic meridional overturning circulations showed some similarity as SODA, although significant differences were found to exist. The analysis of temperature and salinity in the current version has relatively larger errors at high latitudes and improvements are ongoing in an updated version. CORA was found to provide a simulation of the subsurface current in the equatorial Pacific with a correlation coefficient beyond about 0.6 compared with the Tropical Atmosphere Ocean (TAO) mooring data. The mean difference of SLAs between altimetry data and CORA was less than 0.1 m in most years.