安徽省大别山南部宿松杂岩变质作用研究

宿松杂岩的变质作用可分为３个阶段：早期、主期和晚期阶段。主期阶段的矿物组合在云母片岩中为石榴石＋多硅白云母＋石英＋磁铁矿±钠云母±绿帘石／黝帘石;在白云母钠长（二长）片岩和片麻岩中为石榴石＋多硅白云母＋钠长石＋石英＋绿帘石／黝帘石±冻蓝闪石;在石榴石钠长角闪岩中为石榴石＋冻蓝闪石＋钠长石＋黝帘石＋石英±钠云母±金红石／磁铁矿。根据多种地质温压计和变质反应可以推测主期变质条件为：Ｔ＝５２０℃～５８０℃,Ｐ＝１．２～１．４ＧＰａ,地热梯度为１２℃／ｋｍ,相当于高压过渡型。晚期阶段变质条件为：Ｔ＝４６０℃～４８０℃,Ｐ＝０．６～０．７ＧＰａ,为中压绿帘角闪岩相。宿松杂岩的变质条件介于其南部的蓝闪绿片岩相和北部的榴辉岩相之间,三者是扬子板块向华北板块之下俯冲到不同深度的产物。     

川西拗陷上三叠统气田水化学形成演化的重溯

本文在研究区沉积演化、构造演化和上三叠统含水系统、水文地质期定位的基础上,论证了T_3x~2水起源于35 g/kg的海相同生沉积盐水,经历了沉积、沉压埋藏、构造热液3个"期"的浓缩盐化正向变质,演化成为最高浓度160 g/kg的海相后生沉积孔隙裂隙卤水、浓卤水;T_3x~4、T_3x~6水均起源于陆相同生沉积淡水,T_3x~4经历了沉积、沉压埋藏-淋滤、沉压埋藏、构造热液4个"期".主要是高度浓缩盐化正向深变质,演化成为最高浓度100 g/kg的后生沉积孔隙裂隙盐卤水;T_3x~6与T_3x~2经历的期相同,经高度浓缩盐化正向深变质,演化成为最高浓度84 g/kg的后生沉积孔隙裂隙盐卤水.     

频率域航空电磁系统一次磁场自动补偿技术

为了提高三频航空电磁系统(FAEM)测量的自动化程度,设计实现了基于模糊控制和线性增量控制方法相结合的电磁补偿系统,来完成高精度、高稳定性、大动态范围的电磁补偿.以航空电磁接收机输出的电磁场实、虚分量值为控制的输入参量,以补偿线圈内的补偿电流为控制对象,80C52单片机为控制芯片,采用FFSI法推理程序实现补偿量的模糊控制,从而实现一次场和涡流场的实时程控补偿.航空电磁系统实验飞行数据表明,该控制系统可以快速实现一次磁场的实时高精度补偿,稳定性和补偿噪声水平能满足系统设计要求.     

Results for Rarely Determined Elements in MPI-DING, USGS and NIST SRM Glasses Using Laser Ablation ICP-MS

New analytical results are reported for rarely determined elements Be, B, Ge, As, Mo, Rh, Pd, Ag, Cd, In, Sn, Sb, W, Re, Ir, Pt, Au, Tl and Bi in MPI‐DING and USGS (BCR‐2G, BHVO‐2G, BIR‐1G) silicate glasses and the NIST SRM 610‐614 synthetic soda‐lime glasses using 193 nm ArF excimer laser ablation and quadrupole ICP‐MS. The method used involved external calibration against GOR132‐G for Ir and NIST SRM 610 for other elements, internal standardisation using Ca, and ablation with a crater diameter of 160 μm and a pulsed laser repetition rate of 10 Hz. Small amounts of nitrogen (5 ml min^?1) were added to the central channel gas of the plasma to improve the limits of detection for most of these elements by a factor of 1.2–2.5 and to reduce the oxide interference level to 0.02% (ThO⁺/Th⁺). Under these conditions, the LODs for most of these rarely determined elements were within the range 0.1 to 10 ng g^?1. The operating conditions that were required to minimise ICP‐induced fractionation (U⁺/Th⁺≈ 1) in the mode without nitrogen were accompanied by a 50–60% reduction in sensitivity for elements such as Ca, Au and Pt. In contrast, ICP‐induced fractionation could be minimised (U⁺/Th⁺≈ 1) with no loss of analyte sensitivity in the nitrogen mode. Interferences of CuAr⁺, ZnAr⁺, Cd⁺, Pb²⁺ and Sn⁺ on Pd⁺, Rh⁺, Cd⁺ and In⁺ were corrected. Oxide interferences were not considered due to their lower production rate. Analytical precision, as given by one relative standard deviation (% RSD) was less than 15% for most of the elements present at concentrations greater than 0.1 μg g^?1. A significant negative correlation was found between logarithmic concentration and logarithmic RSD, with a correlation coefficient of ?0.76. This trend indicates that possible chemical heterogeneities for most of these elements are smaller than the analytical uncertainty. Our results for Be, B, Ge, Sb and W are generally in good agreement with their reference values. In contrast, other elements in many of the reference glasses have only information values, upper limits or even no values, which restrict any detailed evaluation of the accuracy of the determined values. However, concentrations from multiple isotopes of one element analysed in this study showed excellent agreement, which guarantee the quality of our data to a certain extent.     

Physical properties of ultrahigh-pressure metamorphic rocks from the Sulu terrain, eastern central China: implications for the seismic structure at the Donghai (CCSD) drilling site

About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm³. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.     

地质工程专业发展战略研究

从地质工程人才培养角度,重点分析了地质工程专业教育的现状,根据社会对人才的需求、科技进步和地质工程所面临的发展实际,从可持续发展战略的高度阐述了地质工程素质人才教育所需要采取的对策.     

Study on Strength Influence Mechanism of Fiber-Reinforced Expansive Soil Using Jute

This study was undertaken to research the effects of jute fiber content, fiber length, water content and dry density of reinforced and unreinforced soil on the strength influence mechanism by implementing a series of laboratory tests and analysis. The most efficient fiber reinforcement effects was achieved by means of adding jute fiber with content of 0.6 % and length of 6 mm into expansive soil specimen prepared at maximum dry density and optimum moisture content. The cohesion of reinforced specimens increased first with increasing fiber content and fiber length and then decreased with further increase in fiber content and fiber length. The internal friction angle of reinforced specimens were not affected significantly by fiber content and fiber length. Higher water content reduces the fiber reinforcement effects by means of acting as lubricant in the interface of fiber and soil particles. Fiber reinforcement effects is more prominent for specimens prepared at higher dry density by increasing the effective contact area of fiber/soil. The application prospect of soil reinforcement using natural fiber is impeded by the hydrophilic nature and biodegradability of natural fiber, thus, studies on using chemical additive to do surface treatment for natural fiber are needed to improve the interfacial interaction of fiber/soil so as to widen the application of natural fiber.     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

太行山东麓断裂带板内构造地貌反转与机制

华北克拉通前寒武纪基底可划分为东部地块、中部带和西部地块。中生代以来,华北克拉通发生减薄破坏,其破坏中心位于东部地块,而西部地块与中部带基本保持完整,其过渡带就是太行山东侧。太行山地区近乎平行发育着两条重要的断裂：太行山大断裂和太行山山前断裂,统称为太行山东麓断裂带。通过研究发现,太行山山前断裂是继承早前寒武纪构造带形成的断裂,控制着太行山与东部地块前寒武纪基底的差异,古新世以来发生板内构造地貌的负反转,构成渤海湾盆地的西界断裂。太行山大断裂则在燕山期时为重要的逆冲断裂,对太行山的隆起起着重要作用;中新世以来,伴随着山西地堑系的形成,太行山大断裂发生构造负反转,控制着一系列山间地堑的发育。新生代以来,该区构造演化特征整体表现为向西构造迁移的特点,是区域走滑伸展背景下的一种新的板内盆山关系。     

The origin and response of zircon in eclogite to metamorphism during the multi-stage evolution of the Huwan Shear Zone,China: Insights from Lu–Hf and U–Pb isotopic and trace element geochemistry

The Huwan Shear Zone (HSZ) is an eclogite bearing transpressive wrench zone located along the Shangdan Suture that juxtaposes the Paleozoic Qinling and Mesozoic Hong'an–Dabie orogenic terrains. The region preserves a complex history that bridges the gap between adjacent orogenic terrains. Simultaneous in-situ trace element, U–Th–Pb and Lu–Hf‐isotope analysis of zircon grains from samples of the Xiongdian and Sujiahe eclogite identify a late Carboniferous to early Permian period of high pressure metamorphism, ca. 283 to 306 Ma. Zircon grains are observed to respond to metamorphic overprint via a two stage process: (1) An initial prograde stage of fluid catalyzed interface coupled dissolution–reprecipitation, involving exsolution of a non-ideal solid solution thorite (ThSiO₄) end member and loss of highly incompatible components (LREE and Pb), (2) A second stage of coupled zircon dissolution, coarsening, and new rim growth in equilibrium with garnet at high pressure conditions.We identify Proterozoic whole rock Sm–Nd and zircon grain Lu–Hf isotopic evidence which challenges the traditional interpretation that the Xiongdian and Sujiahe eclogite formed in response to early Paleozoic mantle melting and oceanic crust generation. We argue the Huwan Shear Zone contains no conclusive evidence of early/middle Paleozoic oceanic crust, but rather Proterozoic crustal components analogous to those found in the Northern Qinling Terrain and associated with formation of the Shangdan Suture. We present a simpler geodynamic model involving continuous convergence and accretion of terrains onto the southern margin of the North China Block during the Paleozoic Qinling and Mesozoic Dabie orogenies.