磁铁矿的穆斯堡尔谱研究

我们对大冶、马坑、大顶、黄沙坪、鞍山五个矿区的七个铁矿石样品中的磁铁矿作了室温~(57)Fe和~(119)Sn穆斯堡尔谱测定,并根据穆斯堡尔数据和化学分析推算出磁铁矿的非理想配比的分子结构式. 初步研究表明,不同的成矿条件和Zn、Mg等二价阳离子的类质同像替代的多少,明显地影响晶胞参数和穆斯堡尔参数.文中讨论了它们的变化规律性.     

鄂西秭归盆地中三叠世-早侏罗世沉积记录及其对秦岭印支碰撞造山作用的启示

随着印支期南秦岭勉略洋盆闭合,华南和华北两大块体最终拼贴、构成中国大陆的基本轮廓。普遍认为这一洋陆转换、碰撞造山发生在三叠纪,但具体时间和空间过程仍存在较多争议。秭归盆地位于秦岭逆冲褶皱带东段南缘,是扬子北缘前陆盆地系统的重要组成,在沉积序列和碎屑来源上与秦岭印支期造山作用密切相关。该盆地经历早中三叠世滨-浅海相到晚三叠世-早侏罗世三角洲-河流相的沉积转变,中三叠统巴东组和上三叠统九里岗组之间发育平行不整合。不整合面之上的上三叠统-下侏罗统砂岩在碎屑组分上不仅含有泥岩、粉砂岩等沉积岩岩屑和千枚岩、板岩和片岩等中-低级变质岩岩屑,而且还见有中酸性火山岩岩屑。结合碎屑锆石颗粒U-Pb定年和古流向数据,这些火山岩岩屑揭示北部的秦岭造山带源区在晚三叠世(225~200Ma)存在火山活动,与同期的花岗质侵入岩一起反映秦岭印支期的同碰撞造山岩浆活动。     

In situ infiltration test using a reclaimed abandoned river bed: managed aquifer recharge in Shijiazhuang City,China

Managed aquifer recharge (MAR) is necessary for water resources management in arid and semiarid regions. Infiltration rate is often a decisive limiting factor in site selection for MAR. In order to avoid scale effects in the application of infiltration rate parameters, the largest in situ infiltration test in China was undertaken between August 19 and August 30, 2009 to measure the infiltration rate of the field selected for MAR in Shijiazhuang City, China. The in situ test lasted for 10 days, and about 1.82 × 10⁷ m³ of water was introduced into the infiltration field. Groundwater level variations were monitored during the test. Monitoring showed that the infiltration rate of surface water was 1.5 m/day, which means that about 10–15 × 10⁸ m³/a of water could be injected into the target aquifer. Also, groundwater level variations showed that the northern part of the infiltration field had a higher infiltration rate, as predicted, and the test result supplied a sound foundation for validation of the groundwater numerical simulation, which will be of benefit for future predictions of the response of the groundwater level to artificial recharge engineering. Finally, an artificial recharge plan was proposed based on the infiltration test results and the water source conditions, which would be useful for the development of MAR programs and management of local water resources.     

基于深反射地震剖面的沂沭断裂带岩石圈精细结构

为揭示沂沭断裂带深部结构及发生—发展过程,查清断裂切割深度及对岩石圈地幔的破坏,探讨沂沭断裂带的构造组合样式、运动方式、地壳稳定性及其对资源环境的约束作用,研究团队于2019年在沂沭断裂带南段沂南—莒县附近布设了一条长约60 km的深反射地震剖面,系统采集了沂沭断裂带和两侧地块的地震数据,对沂沭断裂带深部岩石圈精细结构进行了解剖.结果显示,该区岩石圈结构在横向上表现为以沂沭断裂带为界的块状结构特征,地壳厚度约30.8～39.5 km;莫霍面总体呈西浅东深态势,并被西倾的沂水—汤头断裂(F2)和昌邑—大店断裂(F4)错断,垂直落差达10.5 km.与浅部"两堑夹一垒"的构造组合样式不同的是,沂沭断裂带在深部剖面上表现为由沂水—汤头断裂(F2)和昌邑—大店断裂(F4)向上延伸与分叉散开的多条断裂组成"双枝状"构造组合样式.断裂带内被断层切割的界面反射波多呈向上的拱弧形,其构造形迹具有伸展、挤压和走滑并存的特征,推断这些界面为层间滑脱构造,它们指示了沂沭断裂带"多层滑移"构造运动方式.该断裂带不仅切穿了近地表、壳内地质界面,F2、F4断裂还向下切割莫霍面,深入岩石圈地幔,是深达地幔的深大断裂构造带,为地幔热物质的上涌提供了通道,对中生代的岩浆活动和内生成矿具有控制作用.地震剖面西端的铜井金矿成矿与沿F2断裂上侵的铜井杂岩体关系密切;剖面东端的火山机构保存完整,没有明显构造破坏痕迹,据此认为沂沭断裂带左行走滑主要发生在早白垩世青山期以前,其后水平滑移量应不大.从区域地质分布及地震反演结果看,昌邑—大店断裂(F4)明显将山东省分割为鲁西和鲁东两个地质构造单元,因此将其作为区域地质构造分界线是合理的.本项研究结果进一步加深了沂沭断裂带深、浅部结构的认识,为分析研究沂沭断裂带的深部过程和浅部构造响应及对资源环境的影响提供了资料约束.     

异常压力与油气分布

随着油气勘探活动的不断加深，国内外相继发现了许多异常高压油气田。据不完全统计，全世界已发现超压盆地１８０多个，其中１６０多个为富含油气盆地。异常高压油气田约占全球油气田３０％左右，因此，对异常压力的研究，具有举足轻重的意义。本文介绍了异常地层压力的概念、特征及分类；详细论述了异常压力的成因，即烃类生成作用、欠压实作用、液态烃类的裂解作用、粘土矿物的后生成岩作用、构造作用、温度变化等；系统阐述了世界典型含油气盆地的超压形成机制、超压体系中油气初次运移机理以及超压与油气分布关系；并在此基础上，归纳总结出了五种超压油气藏成藏模式，即：（１）位于超压体系中的低渗超压油气藏；（２）位于超压层系中，以礁灰岩（或浊积砂岩）为储层的高压油气藏；（３）位于超压带上倾方向，以退覆三角洲平原和分流河道砂岩为储层的常压或过渡带超压油气藏；（４）位于超压带上、下部的超压油气藏；（５）位于远离超压体系的泄压区常压油气藏，本文对指导、加深新老油气区勘探具有实际应用价值。     

黔中开阳磷矿沉积区震旦纪陡山沱期定量岩相古地理重建*

磷矿的沉积和成矿与成磷期的古地理环境密切相关。本文首次将“单因素分析多因素综合作图法”运用于开阳地区震旦纪陡山沱期沉积型磷矿床的成矿分析和找矿预测上。通过选取陡山沱组及其各岩性段的地层厚度及磷矿层品位作为单因素,确定开阳地区古地理格局;结合地层岩性组合、沉积特征等多因素综合分析,恢复开阳地区成矿期沉积环境,编制陡山沱早期、中期和晚期岩相古地理图。根据定量岩相古地理重建结果,认为开阳地区陡山沱期整体处于南靠黔中古陆、地势南高北低、局部地形复杂的滨岸海滩沉积环境,其中临滨带为最有利成矿带,局部地形变化也会造成矿层厚度、品位的差异;矿层受到的水流冲蚀、暴露、淋滤及再沉积作用是导致矿石品位显著提升的关键因素。通过定量岩相古地理学精确还原成矿期古地理环境、解析多期次沉积成矿过程,对于确定磷矿控矿因素、构建找矿预测模型和预测矿体空间位置具有重要意义。     

Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

珠江口盆地珠一坳陷古近系“源-汇”系统分类及石油地质意义

珠一坳陷深层古近系两套优质生烃层系内发育的储层具有近源成藏的优势,但其非均质性强、低孔渗的特点制约了油气勘探,研究与此直接相关的“源-汇”系统,对于寻找富烃优储耦合的有利区意义重大.以构造运动和盆山地貌为基础,结合断陷湖盆以半地堑为基本单元的结构特点,划分了盆地级、半地堑级和区带级的三级“源-汇”系统.盆地级分为外源、内源型两类,可用来宏观分析优质烃源岩分布;半地堑级分为陡坡、缓坡和长轴型3类,对于定性评价储层优劣具有较大意义;区带级分为迁移型、转换型、稳定型3类,为有利区目标评价和井点选择提供参考.研究认为迁移型和转换型“源-汇”系统可形成良好的生储盖配置,是最为有利的油气富集区,应作为古近系重点勘探对象.      

叠前时间偏移方法在煤田勘探中的应用

根据克希霍夫积分法的原理,介绍了叠前时间偏移的方法特点,实现过程,以及对地震资料的要求,依托国家重大产业技术专项“西部煤炭资源高精度三维地震勘探”工程,对“青海省鱼卡煤田四井田高精度三维地震勘探”资料进行叠前时间偏移,结果表明其能较好地解决成像质量差、能量聚焦不明显、绕射波收敛不理想等方面的难题。通过与叠后时间偏移对比,对于大倾角地层、断块小且多的破碎带、陡倾角不对称向斜等地质问题,其叠前时间偏移剖面成像质量都有明显的提高,反映的构造关系更加清晰,同相轴连续性增强。总结该方法在多个矿区的推广经验．认为合理的观测系统、较高的资料信噪比,准确的测量资料及较高的中表层速度调查精度是做好叠前时间偏移的前提。     

文章已录用：阴山晚中生代板内造山特征及其动力机制-以内蒙古大青山为例

内蒙古大青山属我国典型的板内造山带阴山山脉的南部山系,其西段缺少大型低角度推覆构造及大型深成岩对前期演化历史的干扰,是研究阴山板内造山特点及过程的理想区域。通过对大青山西段的构造进行几何学和运动学的分析表明,古老结晶基底以逆冲推覆及基底褶皱的形式广泛的巻入中生代构造变形,以及先存构造样式的广泛复活并对后期地层沉积和断层发育的控制作用是内蒙古大青山地区中生代板内造山的两个基本特征。这些变形特征反映了阴山带板内造山过程中,是以结晶基底为受力层,并控制上覆盖层进行构造变形的,进而表明板内造山主要是由水平挤压应力造成的。结合研究区构造变形特点及邻区中生代构造地质情况的分析认为,晚侏罗世时期之所以在阴山带形成强烈的板内造山运动,是由其北部西伯利亚板块与蒙古褶皱带碰撞产生的板缘应力的远程传递,以及其南侧强硬的鄂尔多斯地块的阻挡共同作用而形成的。