A study on sample pretreatment of analysis of Cd, Pb and Zn in seawater by IDMS

Isotope dilution mass spectrometry (IDMS) and ultra-clean room approach are successfully used in the determination of Cd, Pb and Zn in seawater and the sample pretreatment of analysis. The precision in the determination of Cd, Pb and Zn in seawater is better than±3% and the limits of detection are 6×10-12, 6×10-11 and 2.4×10-10 respectively. The effects of sample pretreatment such as filtration and acidification on the results of determination of Cd- Pb and Zn in seawater are disscussed.     

Microbial Diversity in Nankai Trough Sediments at a Depth of 3,843 m

Dense populations of bivalves, primarily Calyptogena sp., were observed at cold seeps of the Nankai Trough. Bacterial input to the sediment was estimated through determination of phospholipid ester-linked fatty acid (PLFA) and DNA profiles. Results indicated a bacterial biomass of 10⁹ cells (g dry wt)^-1 while individual fatty acid profiles revealed a predominance of monounsaturated fatty acids, mainly 18:1 isomers. The presence of these fatty acids can be interpreted to reflect a response to low temperature and a predominance of psychrophilic bacteria. DNA fragments encoding bacterial ribosomal RNA small-subunit sequences (16S rDNA) were amplified by the polymerase chain reaction method using DNA extracted directly from the sediment samples. From the sequencing results, at least 19 kinds of bacterial 16S rDNAs related to mostly the Proteobacteria and a few gram-positive bacteria were identified. These results suggest that the bacterial community in the Nankai Trough sediments consists of mainly bacteria belonging to the Proteobacteria , , and subdivisions. Bacteria belonging to the and subdivisions, which are known to include epibiont and sulfate reducing bacteria, respectively, were mostly detected in the sediment obtained from inside the area of the Calyptogena community, and the -Proteobacteria may function to supply reduced sulfur to bacterial endosymbionts of Calyptogena.     

Rock magnetic properties and palaeomagnetic results of sediments from a stone implement layer in the Bose Basin,Guangxi

Directional samples were taken to study rock magnetism and palaeomagnetic records from the Dong- sheng profile, which is 5 m thick and on the northwest edge of the Bose Basin. Mineralogy and rock magnetism of typical samples indicate that coarse granular titanomagnetite, and fine-grained hematite, superparamagnetic maghemite formed by pedogenesis are in the sediment, which has undergone many transformative processes during different stages of pedogenesis. Parallel samples were taken for thermal demagnetization (TH) (0 to 680℃) and alternating field (AF) demagnetization (0 to 80 mT) respectively. Experimental results of these two kinds of demagnetization illustrate that there are two or more magnetic components in the samples. Intensity of NRM decreases by almost 60% to 90% rapidly when the temperature ranges from 100℃ to 350℃, with a steady magnetic component. It is impossible to analyze the magnetic components at high temperature because those fluctuate widely when the temperature is higher than 400℃. Steady magnetic components from 100℃ to 350℃ indicate that the remanence was mainly carried by fine-grained hematite formed by pedogenesis, reflecting a change in the geomagnetic field while the magnetite was being oxidized into hematite by chemical weathering after deposition. The formative age of the sediments cannot be obtained by magnetic methods in this profile.     

Mid-Late Neoproterozoic rift-related volcanic rocks in China: Geological records of rifting and break-up of Rodinia

Early Cambrian and Mid-Late Neoproterozoic volcanic rocks in China are widespread on several Precambrian continental blocks,which had aggregated to form part of the Rodinia supercontinent by ca.900 Ma....     

An Improved Approach for Parameterizing Surface-Layer Turbulent Transfer Coefficients in Numerical Models

Based on classic iterative computation results, new equations to calculate the surface turbulent transfer coefficients are proposed, which allow for large ratios of the momentum and heat roughness lengths. Compared to the Launiainen scheme, our proposed scheme generates results closer to classical iterative computations. Under unstable stratification, the relative error in the Launiainen scheme increases linearly with increasing instability, even exceeding 15%, while the relative error of the present scheme is always less than 8.5%. Under stable stratification, the Launiainen scheme uses two equations, one for 0 < Ri _B ≤ 0.08 and another for 0.08 < Ri _B ≤ 0.2, and does not consider the condition that Ri _B > 0.2, while its relative errors in the region 0 < Ri _B ≤ 0.2 exceed 31 and 24% for momentum and heat transfer coefficients, respectively. In contrast, the present scheme uses only one equation for 0 < Ri _B ≤ 0.2 and another equation for Ri _B > 0.2, and the relative error of the present scheme is always less than 14%.     

Primary dolostone related to the Cretaceous lacustrine hydrothermal sedimentation in Qingxi sag, Jiuquan Basin on the northern Tibetan Plateau

Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1–1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values (δ¹⁸O_PDB) range from 5.89‰ to 14.15‰ with an average of 9.69‰. The ratio of ⁸⁷Sr/⁸⁶Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca²⁺, Mg²⁺ and Fe²⁺. Under the driving flow power of magmatic heat, gravity and compaction, the hydrothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered “hydroexplosion breccias”. In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hydrotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.     

Phase Equilibria Constraints on Relations of Ore-bearing Intrusionswith Flood Basalts in the Panxi Region, Southwestern China

There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small uitramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-PI-OI-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and iow-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limabe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basaits. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.     

中国古代牧业社会骨制品的初步考察:以新疆巴里坤石人子沟遗址为例

考古遗址出土骨制品的研究对于揭示古代社会的动物资源获取和利用、手工业生产、社会组织结构等问题具有重要意义。国内骨制品研究目前多集中在农业区域,这些研究为探讨新石器时代至青铜时代的动物使用及其与社会发展、早期国家形成的关系等问题作出了重要贡献。然而,针对牧业社会骨制品的考察十分缺乏。新疆哈密地区巴里坤草原分布有大量古代牧业文化遗址,石人子沟遗址（43°31'12.8"~43°34'28.9"N,93°13'44.8"~93°16'49.1"E）是其中一处青铜时代晚期至铁器时代早期的大型聚落。本文从动物考古学视角研究该遗址2006年至2011年发掘出土的426件骨制品。结果显示,石人子沟遗址骨制品的原料主要为以羊（Ovis aries/Capra hircus）、马（Equus caballus）为主的家养动物和以鹿（Cervidae）为主的野生动物,其中羊的比例最高（69.7%）,鹿（13.8%）、马（2.3%）次之,这与中原地区青铜时代农业文化遗址的骨制品多以牛为原料的情况明显不同。羊在骨制品原料中占绝对多数且大量使用羊距骨制品的现象是对石人子沟遗址以牧业为主的生业经济方式的直接反映。石人子沟遗址不同类型骨制品的制作各具特点,但整体表现出"省时省力"的特点,即对使用部位细致打磨,对非使用部位仅做简单处理。与中原地区商周时期大型制骨作坊规范化、规模化、产业化的骨器生产不同,石人子沟遗址未见专门的制骨场所,骨制品生产的操作链条也并不完整。遗址的骨制品生产可能是以家庭为单元进行的,产品的专业化、精细化程度也相对较低。该研究填补了我国古代牧业文化遗址出土骨制品动物考古学专门研究的空白,为进一步探究我国古代不同区域、不同生业经济基础下的制骨手工业面貌提供了重要资料。

     

基于“DEM-NDVI-土地覆盖分类”的天山博格达自然遗产地山地垂直带提取与变化分析

本文基于Landsat影像数据获取天山博格达自然遗产地土地覆盖分类,结合归一化植被指数（NDVI）和数字高程模型（DEM）构建“DEM-NDVI-土地覆盖分类”散点图分析研究区植被受海拔和坡向的水热空间变化影响的分布特征,通过概率统计分析提取博格达遗产地山地垂直带,并结合研究区的气温、降水数据和NDVI变化特征分析垂直带变化的原因。研究结果表明：① 本文利用“DEM-NDVI-土地覆盖分类”散点图,揭示了研究区1989年和2016年的NDVI值和分类类别随着海拔上升的变化特征,其中NDVI值随着海拔上升呈现“倒U形”变化,而不同分类类别在一定的海拔区间内呈现出聚集效应,且不同分类类别有明显的高程界限。② 1989年和2016年博格达遗产地山地垂直带分带上限分别为：1278 m和1185 m（温带荒漠草原带）、1784 m和1759 m（山地草原带）、2706 m和2730 m（山地针叶林带）、3272 m和3293 m（高山草甸带）、3636 m和3690 m（高山垫状植被带）。③ 博格达遗产地1989年和2016年山地垂直带受区域气温升高和降雨增加的影响有较为明显的改变,其中温带荒漠草原带最为敏感,其上限变化最大,向下收缩93 m;山地针叶林带的分布范围则向两侧扩张49 m;山地草甸带带宽基本保持不变,但整体上移了约20 m;冰雪带则受到全球气候变暖的影响向上退缩54 m。     

被动陆缘盆地陆隆斜坡对盐构造形成的影响 ——来自物理模拟实验的启示

被动陆缘盆地盐构造形成的影响因素及时空演化分析受到了国内外学者的高度重视.丰富的油气资源促进了被动陆缘盆地地震资料品质的不断提升,高精度地震数据的解译结果表明,被动陆缘盆地盐层下的地形往往具有大型的起伏特征,而前人在基底构造形态对盐构造形成影响方面的研究并未取得共识,仍需要深入研究和探讨.为此,本文基于前人的研究认识,...