Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

横断山脉地区大气环流演变特征分析

应用Lamb-Jenkinson大气环流分型方法对横断山脉地区的8个经度×10个纬度范围内1948-2012年逐日平均的海平面气压场进行环流分型,由日平均海平面气压场算出6个环流指数（u、v、V、ξu、ξv、ξ）,并由此划分出27种不同的环流型。分型结果表明：横断山脉地区主要环流分型为E型、NE型、SE型、N型和C型,其频率分别为：21.4%、14.6%、13.7%、9.8%和9.5%;E和NE型环流频率逐渐增加,C型环流型频率逐渐减少。春季横断山脉地区主导环流比较繁琐;NE、N型为夏季的主要环流型,但E型环流在夏季的频率也相当大;秋季和冬季横断山脉地区的主导环流型都为E型和SE型。夏季主导环流型持续时间较长,冬季也是主导环流持续的时间较长,个别年份主导环流型持续时间超过了一个月,这主要与横断山脉地区复杂的地形有联系。     

积极推动“数字海南”建设

海南省具有得天独厚的发展优势,“数字地球”是实现整体可持续发展的重要保障,将有力推进全省信息化的进程,促进经济发展。     

Test method for single interior right angle in a corner cube prism

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Bayesian maximum entropy approach and its applications: a review

The present paper reviews the conceptual framework and development of the Bayesian Maximum Entropy (BME) approach. BME has been considered as a significant breakthrough and contribution to applied stochastics by introducing an improved, knowledge-based modeling framework for spatial and spatiotemporal information. In this work, one objective is the overview of distinct BME features. By offering a foundation free of restrictive assumptions that limit comparable techniques, an ability to integrate a variety of prior knowledge bases, and rigorous accounting for both exact and uncertain data, the BME approach was coined as introducing modern spatiotemporal geostatistics. A second objective is to illustrate BME applications and adoption within numerous different scientific disciplines. We summarize examples and real-world studies that encompass the perspective of science of the total environment, including atmosphere, lithosphere, hydrosphere, and ecosphere, while also noting applications that extend beyond these fields. The broad-ranging application track suggests BME as an established, valuable tool for predictive spatial and space–time analysis and mapping. This review concludes with the present status of BME, and tentative paths for future methodological research, enhancements, and extensions.     

莺歌海盆地中央泥底辟带气田水地球化学特征及其油气地质意义

以莺歌海盆地东方区和乐东区气田水样品水化学常规分析为切入点,利用气田水矿化度、水型、钠氯系数(变质系数)、脱硫系数,氯镁系数等参数,深入分析了两区气田水地球化学特征及水化学组合参数特征,并判识对比了两区气藏封闭程度及其保存条件。在此基础上,结合莺歌海盆地天然气成藏地质条件,重点剖析了两区气田水分布规律及成因控制因素,探讨了两区气田水与天然气运聚成藏之间的成因联系。强调指出,两区气田水具有相似的形成演化特征,天然气保存条件好,但对比两区气田水的水化学组合参数,乐东区天然气保存条件稍差于东方区;东方区气田水以NaHCO3水型占绝对优势,其分布规律与断裂系统存在密切联系。该区水文地质开启程度差,气藏盖层封闭性好,有利于天然气富集成藏。乐东区气田水类型多样,成因复杂,天然气保存条件较好但相对东方区稍差。两区气田水具分区分块分布规律,莺歌海盆地泥底辟及其伴生热流体活动对气田水成因及分布规律与天然气运聚成藏等均具有重要控制作用和影响。     

Characteristics of China’s oil and gas pool formation in latest geological history

The structural activities took place extensively in the Asia continent during the Cenozoic era owing to the strong continent-to-continent collision and continuous compression between the India Plate and the Eurasia Plate. Huang Jiqing called such structural activities Himalayan movement. China’s sedimentary basins developed and took shape mainly during the Himalayan movement period. It is also the main period for formation and development of the oil and gas reservoirs. Of 366 large and medium-sized oil and gas fields currently found in China, 212 reservoirs were formed in the Neogene-Quaternary period. The proportion is as high as 68.2%. The oil and gas migration and accumulation in the latest geological period, which were controlled by the times, properties, styles and strength of the Himalayan movement, took place mainly in eight regions, such as the low uplift area of Bohai Sea, the onshore faulted sag area of Bohai Bay, anticlinorium zone in Daqing, the foreland fold-and-thrust belt in West China, the tilted structural zone in West China, the cratonic palaeohigh in the Tarim Basin, the zone of fault and fold belt in the East Sichuan Basin, and the biological gas zone in the East Qaidam Basin. The oil and gas pool formations in those regions have their own characteristics. With the great potential and broad prospect, those regions are the main exploration areas in China in the future.     

Whether human-induced activities could change the gradient pattern of coastal land use along the sea-land direction: a case study in Manila Bay,Philippines

Increasing intense human activities have largely changed the coastal landscape and caused many environmental issues. However, whether human-induced activities could change the coastal land use gradient pattern, an important coastal zonal characteristic along the sea–land direction, remains unclear. Manila Bay was selected as the study area in this work. According to the distance of the land use and land cover(LULC) to the coastline, we clustered the typical coastal land use sequence patterns(CLU...     

山东省栖霞牙山花岗闪长岩岩石地球化学特征及成因探讨

栖霞牙山地区地处华北地台东部,对该区的似斑状花岗闪长岩体所作的岩石地球化学研究表明,该区岩石为钙碱性偏铝质岩石;微量元素MORB标准化蛛网图显示富集大离子亲石元素Ba、Sr,亏损高场强元素Nb、Ta、Hf、Y;K/Rb比值为295.34~388.88,Rb/Sr比值为0.21~0.29;稀土元素蛛网图表现为较平滑的具微弱负Eu异常向右陡倾的稀土元素配分模式曲线,∑LREE/∑HREE为9.14~12.22,显示轻重稀土元素分异较好。结合构造背景分析,认为牙山花岗闪长岩体为早白垩世太平洋板块向欧亚板块俯冲诱发的地幔柱活动,造成地幔底辟,引起地壳部分熔融,形成壳幔混合岩浆并进一步侵入形成。     

关于二阶伴随模型的理论研究

Hesse矩阵-目标函数关于控制变量的二阶偏导数形成的矩阵,在变分数据同化过程中以及敏感性分析等方面起着重要的作用;它可以通过建立数学模型的一阶和二阶伴随模型求得.以浅水方程模型为例,利用泛函的Gâteaux微分和Hilbert空间上伴随算子的概念,导出了一阶和二阶伴随模型并由此得到Hesse矩阵.改进了Zhi Wang等(1992)建立的二阶伴随模型理论.