浙江雷甸淡水无光珠中球文石的首次确认

球文石（Vaterite)是CaCO3很不稳定的同质多象变体，在自然界里很少出现，通过光学显微镜在淡水无光珠中发现球文石尚属首次，本文研究了淡水无光珠内球文石的显微特征、X射线粉晶衍射特征及显微红外光谱特征，研究结果表明淡水无光珍珠内球文石粉晶衍射由强至弱五个强峰的d值为0.3266,0.2723,0.3553,0.1811,0.2057nm；其红外光谱特征波数为1489，1450,1420,1087,1050,876,830,762,743cm^-1。球文石的存在是影响淡水珍珠品质的主要内在因素之一。     

Duobaoshan Porphyry Copper Deposit and Its Associated Components

Duobaoshan porphyry copper deposit,situated in Nen-jiang County of Heilongjiang Province,Northeast China,liestectonically in the Mongolian-Okhotsk geosyncline.Duobaoshan porphyry copper ore field consisting ofDuobaoshan copper deposit and Tongshan copper deposit con-tains rich copper associated with molybdenum,gold,silverand osmium (Os1 87) . In this sense,this porphyry copper orefield will turn into a large industrial base of copper,gold,sil-ver and osmium.At present,in Duobaoshan porphy…     

枝万线选线中的主要工程地质问题研究

枝万铁路工程地质条件极为复杂, 控制线路方案的选择. 所进行的研究为工程前期工作的技术储备. 通过对区域地质背景的分析, 在总结工程地质和水文地质特征和规律的基础上, 找出控制线路方案的关键工程地质问题, 经充分研究, 确定选线原则, 指导线路方案的综合比选.      

岩溶水流方式与成矿作用关系探讨

本文通过论述管道流与扩散流两种主要岩溶水流方式的水动力、水化学特征与成矿的关系,论证水流方式在岩溶成矿作用中的重要作用。此外,通过分析两种水流的运移特点与矿床特征的关系,指出具浸染状、脉状的矿石结构构造和呈似层状、透镜状、脉状产出的矿体多与扩散流有关,具含砾纹层状、角砾状的矿石结构构造、和呈不规则状、囊状产出的矿体多与管道流有关;具不同形态矿体和不同结构构造矿石共存的矿体,则可由不同岩溶水流方式共同作用造成。      

广东河台整装勘查区百旁金矿成矿规律

百旁金矿是广东地质五队近年来新发现的一处中型蚀变糜棱岩型金矿。百旁金矿地处粤西—桂东成矿带东段NE向罗定—广宁断裂带北东端部位,矿体受糜棱岩带内面理、裂隙带控制;金矿化具明显的以硅化、硫化物为中心的对称性分布特征,金矿体具有平行斜列、侧伏的分布规律,表现为向NE向侧伏;区内金矿化富集主要与热液活动有关,燕山期的重熔花岗岩侵入的同时伴随有富含硫化物的含金热液充填在糜棱岩、断裂带内而成矿。     

底水油层水平井产液剖面均衡性评价

胜利油田开采底水特征高含水油层的水平井数量多,其中油层向水平井非均衡供液现象普遍。为评价此类水平井产液剖面均衡性,量化其生产动态改善潜力,定义了产液剖面基尼系数GN,并结合现场案例介绍其计算方法,随后统计胜利油田60口样本井,分析GN对见水时间tRL和底水突破前累积产油量QRL的影响,最后据此对GN分级。计算和分析结果表明:GN可以整体表征实际非均衡产液剖面偏离理想均衡产液剖面的程度,通常取值0~1之间,数值越大,均衡性越差;划分GN0.1为产液剖面不均衡,其样本井数54口,占比90%,以理想均衡产液状态为基准,tRL和QRL分别至少有100%和69.5%的提升潜力。     

Geochemistry of rare-earth elements in shallow groundwater,northeastern Guangdong Province,China

Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+.     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.