地下卤水体系中水活度的计算方法评定

在温度 1 2 .1～ 60 .5℃范围内测定了地下卤水体系的饱和蒸汽压 ,并采用Clausius -Clapeyron方程进行关联 ,计算水活度 ;比较强电解质混合体系水活度的理论计算模型 ,探索计算地下卤水体系水活度的最佳方法     

Stratification and mixing of a post-glacial Neoproterozoic ocean: Evidence from carbon and sulfur isotopes in a cap dolostone from northwest China

To improve our knowledge about the geochemical and environmental aftermath of Neoproterozoic global glaciations, we analyzed stable isotopes (δ¹³C, δ¹⁸O, δ³⁴S) and elemental concentrations (Ca, Mg, S, Sr, Fe, and Mn) of the ～ 10-m-thick Zhamoketi cap dolostone atop the Tereeken diamictite in the Quruqtagh area, eastern Chinese Tianshan. Available chemostratigraphic data suggest that the Tereeken diamictite is probably equivalent to the Marinoan glaciation. Our new data indicate that organic and carbonate carbon isotopes of the Zhamoketi cap dolostone show little stratigraphic variations, averaging ? 28.2‰ and ? 4.6‰, respectively. In contrast, sulfur isotopes show significant stratigraphic variations. Carbonate associated sulfate (CAS) abundance decreases rapidly in the basal cap dolostone and δ³⁴S_CAS composition varies between + 9‰ and + 15‰ in the lower 2.5 m. In the overlying interval, CAS abundance remains low while δ³⁴S_CAS rises ～ 5‰ and varies more widely between + 10‰ and + 21‰. The range of δ³⁴S_py of the cap dolostone overlaps with that of δ³⁴S_CAS, but direct comparison shows that δ³⁴S_py is typically greater than δ³⁴S_CAS measured from the same samples. Hypotheses to explain the observations must account for both the remarkable sulfur isotope enrichment of pyrites and the inverse fractionation. We propose that CAS and pyrite were derived from two isotopically distinct reservoirs in a chemically stratified basin or a basin with a sulfate minimum zone. In this model, CAS was derived from shallow, oxic surface waters with moderate sulfate concentration and depleted in ³⁴S due to the post-glacial influx of sulfur from continental weathering. In contrast, pyrite was derived from anoxic bottom waters (or a sulfate minimum zone) with low sulfate concentration and ³⁴S enrichment due to long-term syn-glacial sulfate reduction. The rapid shift in CAS abundance and sulfur isotope composition within the cap dolostone is interpreted to reflect the mixing of the two reservoirs after initial deglaciation. Comparison with other post-Marinoan cap carbonates shows significant spatial heterogeneity in δ³⁴S_CAS, which together with strong temporal variation in δ³⁴S_CAS, points to generally low sulfate concentrations in post-Marinoan oceans.     

2003年民乐-山丹6．1、5、8级地震序列精确定位

利用遗传算法对2003年10月25日甘肃民乐-山丹6.1、5.8级地震及其余震进行了精确定位,并在此基础上结合地质资料讨论了此次地震的发震构造.定位结果表明:地震序列分布集中,两次主震主要沿着民乐-永昌隐伏断裂分布;震源深度主要分布在10～15 km范围内,平均深度为12.1 km;此次地震序列的发震构造为民乐-永昌隐伏断裂与童子坝河隐伏断裂所组成的大黄山隆起区前缘逆冲断裂,其中民乐-永昌隐伏断裂西段的NWW向局部断裂起主要作用.     

2004年6月甘肃临泽震群地震精确定位

利用"双差地震定位法"对2004年6月甘肃临泽发生的地震震群进行了精确定位,结合地质构造资料讨论了本次震群的发震构造.结果表明:该震群震中沿着榆木山北缘断裂呈NNW向分布,震源深度优势分布于10～25 km,平均深度为16.3 km;发震断裂为榆木山北缘断裂东段局部断裂,走向NNW,倾向SW,倾角约为60°.     

Analysis of earthquake ground motions using an improved Hilbert–Huang transform

Some limitations of the Hilbert–Huang transform (HHT) for nonlinear and nonstationary signal processing are remarked. As an enhancement to the HHT, a time varying vector autoregressive moving average (VARMA) model based method is proposed to calculate the instantaneous frequencies of the intrinsic mode functions (IMFs) obtained from the empirical mode decomposition (EMD) of a signal. By representing the IMFs as time varying VARMA model and using the Kalman filter to estimate the time varying model parameters, the instantaneous frequencies are calculated according to the time varying parameters, then the instantaneous frequencies and the envelopes derived from the cubic spline interpolation of the maxima of IMFs are used to yield the Hilbert spectrum. The analysis of the length of day dataset and the ground motion record El Centro (1940, N–S) shows that the proposed method offers advantages in frequency resolution, and produces more physically meaningful and readable Hilbert spectrum than the original HHT method, short-time Fourier transform (STFT) and wavelet transform (WT). The analysis of the seismic response of a building during the 1994 Northridge earthquake shows that the proposed method is a powerful tool for structural damage detection, which is expected as the promising area for future research.     

Kinetics of hydrocarbon generation for Well Yingnan 2 gas reservoir,Tarim Basin,China

Well Yingnan 2, an important exploratory well in the east of Tarim Basin, yields high commercial oil and gas flow in Jurassic. Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas. Because this region presents many suits of hydrocarbon source rocks, there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present. By using the kinetics of hydrocarbon generation and carbon isotope, natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas, about 72%, it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir. The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2, so the gas reservoir belongs to late accumulation and continuous filling type.     

Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.     

Electro‐Catalytic Degradation of Phenol Organics with SnO2‐Sb2O3/Ti Electrodes

The effect of extraordinary degradation of phenol organics on the SnO₂‐Sb₂O₃/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm^–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO₂/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO₂‐Sb₂O₃/Ti was superior to that of the PbO₂/Ti electrode. At the same time, the SnO₂‐Sb₂O₃/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb₂O₃ layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO₂ part.     

1208-1369年陕甘宁交界地区干湿变化

More than 240 items of historical records containing climatic information were retrieved from official historical books, local chronicles, annals and regional meteorological disaster yearbooks. By using moisture index and flood/drought (F/D) index obtained from the above information, the historical climate change, namely wet-dry conditions in borderland of Shaanxi Province, Gansu Province and Ningxia Hui Autonomous Region (BSGN, mainly included Ningxialu, Hezhoulu, Gongchanglu, Fengyuanlu and Yan’anlu in the Yuan Dynasty) was studied. The results showed that the climate of the region was generally dry and the ratio between drought and flood disasters was 85/38 during the period of 1208–1369. According to the frequencies of drought-flood disasters, the whole period could be divided into three phases. (1) 1208–1240: drought dominated the phase with occasional flood disasters. (2) 1240–1320: long-time drought disasters and extreme drought events happened frequently. (3) 1320–1369: drought disasters were less severe when flood and drought disasters happened alternately. Besides, the reconstructed wet-dry change curve revealed obvious transition and periodicity in the Mongol-Yuan Period. The transitions occurred in 1230 and 1325. The wet-dry change revealed 10- and 23-year quasi-periods which were consistent with solar cycles, indicating that solar activity had affected the wet-dry conditions of the study region in the Mongol-Yuan Period. The reconstructed results were consistent with two other study results reconstructed from natural evidences, and were similar to another study results from historical documents. All the above results showed that the climate in BSGN was characterized by long-time dry condition with frequent severe drought disasters during 1258 to 1308. Thus, these aspects of climatic changes might have profound impacts on local vegetation and socio-economic system.     

Adsorption kinetics, isotherm, and thermodynamic studies of adsorption of pollutant from aqueous solutions onto humic acid

In the present study,humic acid was used as an adsorbent for the investigation of the adsorption kinetics,isotherms,and thermo-dynamic parameters of hexavalent chromium from aqueous solution at varying pH,temperatures,and concentrations.Adsorption isotherms and equilibrium adsorption capacities were determined by the fittings of the experimental data to three well-known iso-therm models:Langmuir,Freundlich,and Redlich-Peterson.The results showed that the Langmuir and Redlich-Peterson models appear to fit the adsorption better than did the Freundlich adsorption model for the adsorption of chromium onto humic acid.The equilibrium constants were used to calculate thermodynamic parameters such as the change of free energy,enthalpy,and entropy.The derived adsorption constants (logaL) and their temperature dependencies from Langmuir isotherm have been used to calculate the corresponding thermodynamic quantities such as the free energy of adsorption,heat,and entropy of adsorption.The thermo-dynamic data indicate that Cr (VI) adsorption onto humic acid is entropically driven and characterized by physical adsorption.