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991.
992.
Bing Shen Shuhai Xiao Alan J. Kaufman Huiming Bao Chuanming Zhou Haifeng Wang 《Earth and Planetary Science Letters》2008,265(1-2):209-228
To improve our knowledge about the geochemical and environmental aftermath of Neoproterozoic global glaciations, we analyzed stable isotopes (δ13C, δ18O, δ34S) and elemental concentrations (Ca, Mg, S, Sr, Fe, and Mn) of the ~ 10-m-thick Zhamoketi cap dolostone atop the Tereeken diamictite in the Quruqtagh area, eastern Chinese Tianshan. Available chemostratigraphic data suggest that the Tereeken diamictite is probably equivalent to the Marinoan glaciation. Our new data indicate that organic and carbonate carbon isotopes of the Zhamoketi cap dolostone show little stratigraphic variations, averaging ? 28.2‰ and ? 4.6‰, respectively. In contrast, sulfur isotopes show significant stratigraphic variations. Carbonate associated sulfate (CAS) abundance decreases rapidly in the basal cap dolostone and δ34SCAS composition varies between + 9‰ and + 15‰ in the lower 2.5 m. In the overlying interval, CAS abundance remains low while δ34SCAS rises ~ 5‰ and varies more widely between + 10‰ and + 21‰. The range of δ34Spy of the cap dolostone overlaps with that of δ34SCAS, but direct comparison shows that δ34Spy is typically greater than δ34SCAS measured from the same samples. Hypotheses to explain the observations must account for both the remarkable sulfur isotope enrichment of pyrites and the inverse fractionation. We propose that CAS and pyrite were derived from two isotopically distinct reservoirs in a chemically stratified basin or a basin with a sulfate minimum zone. In this model, CAS was derived from shallow, oxic surface waters with moderate sulfate concentration and depleted in 34S due to the post-glacial influx of sulfur from continental weathering. In contrast, pyrite was derived from anoxic bottom waters (or a sulfate minimum zone) with low sulfate concentration and 34S enrichment due to long-term syn-glacial sulfate reduction. The rapid shift in CAS abundance and sulfur isotope composition within the cap dolostone is interpreted to reflect the mixing of the two reservoirs after initial deglaciation. Comparison with other post-Marinoan cap carbonates shows significant spatial heterogeneity in δ34SCAS, which together with strong temporal variation in δ34SCAS, points to generally low sulfate concentrations in post-Marinoan oceans. 相似文献
993.
994.
995.
Dong Yinfeng Li Yingmin Xiao Mingkui Lai Ming 《Soil Dynamics and Earthquake Engineering》2008,28(1):7-19
Some limitations of the Hilbert–Huang transform (HHT) for nonlinear and nonstationary signal processing are remarked. As an enhancement to the HHT, a time varying vector autoregressive moving average (VARMA) model based method is proposed to calculate the instantaneous frequencies of the intrinsic mode functions (IMFs) obtained from the empirical mode decomposition (EMD) of a signal. By representing the IMFs as time varying VARMA model and using the Kalman filter to estimate the time varying model parameters, the instantaneous frequencies are calculated according to the time varying parameters, then the instantaneous frequencies and the envelopes derived from the cubic spline interpolation of the maxima of IMFs are used to yield the Hilbert spectrum. The analysis of the length of day dataset and the ground motion record El Centro (1940, N–S) shows that the proposed method offers advantages in frequency resolution, and produces more physically meaningful and readable Hilbert spectrum than the original HHT method, short-time Fourier transform (STFT) and wavelet transform (WT). The analysis of the seismic response of a building during the 1994 Northridge earthquake shows that the proposed method is a powerful tool for structural damage detection, which is expected as the promising area for future research. 相似文献
996.
Well Yingnan 2, an important exploratory well in the east of Tarim Basin, yields high commercial oil and gas flow in Jurassic. Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas. Because this region presents many suits of hydrocarbon source rocks, there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present. By using the kinetics of hydrocarbon generation and carbon isotope, natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas, about 72%, it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir. The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2, so the gas reservoir belongs to late accumulation and continuous filling type. 相似文献
997.
Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened. 相似文献
998.
The effect of extraordinary degradation of phenol organics on the SnO2‐Sb2O3/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO2/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO2‐Sb2O3/Ti was superior to that of the PbO2/Ti electrode. At the same time, the SnO2‐Sb2O3/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb2O3 layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO2 part. 相似文献
999.
More than 240 items of historical records containing climatic information were retrieved from official historical books, local
chronicles, annals and regional meteorological disaster yearbooks. By using moisture index and flood/drought (F/D) index obtained
from the above information, the historical climate change, namely wet-dry conditions in borderland of Shaanxi Province, Gansu
Province and Ningxia Hui Autonomous Region (BSGN, mainly included Ningxialu, Hezhoulu, Gongchanglu, Fengyuanlu and Yan’anlu
in the Yuan Dynasty) was studied. The results showed that the climate of the region was generally dry and the ratio between
drought and flood disasters was 85/38 during the period of 1208–1369. According to the frequencies of drought-flood disasters,
the whole period could be divided into three phases. (1) 1208–1240: drought dominated the phase with occasional flood disasters.
(2) 1240–1320: long-time drought disasters and extreme drought events happened frequently. (3) 1320–1369: drought disasters
were less severe when flood and drought disasters happened alternately. Besides, the reconstructed wet-dry change curve revealed
obvious transition and periodicity in the Mongol-Yuan Period. The transitions occurred in 1230 and 1325. The wet-dry change
revealed 10- and 23-year quasi-periods which were consistent with solar cycles, indicating that solar activity had affected
the wet-dry conditions of the study region in the Mongol-Yuan Period. The reconstructed results were consistent with two other
study results reconstructed from natural evidences, and were similar to another study results from historical documents. All
the above results showed that the climate in BSGN was characterized by long-time dry condition with frequent severe drought
disasters during 1258 to 1308. Thus, these aspects of climatic changes might have profound impacts on local vegetation and
socio-economic system. 相似文献
1000.
Adsorption kinetics, isotherm, and thermodynamic studies of adsorption of pollutant from aqueous solutions onto humic acid 总被引:1,自引:0,他引:1
In the present study,humic acid was used as an adsorbent for the investigation of the adsorption kinetics,isotherms,and thermo-dynamic parameters of hexavalent chromium from aqueous solution at varying pH,temperatures,and concentrations.Adsorption isotherms and equilibrium adsorption capacities were determined by the fittings of the experimental data to three well-known iso-therm models:Langmuir,Freundlich,and Redlich-Peterson.The results showed that the Langmuir and Redlich-Peterson models appear to fit the adsorption better than did the Freundlich adsorption model for the adsorption of chromium onto humic acid.The equilibrium constants were used to calculate thermodynamic parameters such as the change of free energy,enthalpy,and entropy.The derived adsorption constants (logaL) and their temperature dependencies from Langmuir isotherm have been used to calculate the corresponding thermodynamic quantities such as the free energy of adsorption,heat,and entropy of adsorption.The thermo-dynamic data indicate that Cr (VI) adsorption onto humic acid is entropically driven and characterized by physical adsorption. 相似文献