潘谢矿区石盒子组煤系页岩有机质特征及其对含气量的影响

潘谢矿区是安徽省淮南煤田重要的深部煤炭生产矿区,其石炭-二叠系煤系地层具有丰富的天然气资源。应用有机碳、热解、显微组分定量、等温吸附等实验分析数据,对潘谢矿区石盒子组煤系页岩有机质特征与含气量进行研究,并利用梯度下降算法建立了含气量与有机碳含量(TOC)和有机质成熟度(Ro)的多元线性模型。结果表明:潘谢矿区石盒子组煤系页岩TOC较高(平均为1.20%),有机质类型为Ⅲ型,成熟度Ro为0.75%~1.12%,处于成熟阶段,页岩含气量较高(平均为1.93 m 3/t)。多元线性模型表明,煤系页岩TOC和Ro的增加会有利于页岩气生成,但Ro对含气量的影响更为明显。     

Concurrence, tangle and fully entangled fraction

We show that although we cannot distil a singlet from many pairs of bound entangled states, the concurrence and the tangle of two entangled quantum states are always strictly larger than those of one of them, even both entangled quantum states are bound entangled. We present a relation between the concurrence and the fidelity of optimal teleportation. We also give new upper and lower bounds for concurrence and tangle.     

马尾藻的营养成分分析和营养学评价

对南海６种不同种类或不同生长海域的马尾藻进行营养成分分析，然后与海带和紫菜比较，进行营养学评价。结果表明，马尾藻含有丰富的膳食纤维、褐藻淀粉、矿物质和维生素以及优质的高度不饱和脂肪酸和合理的必需氨基酸组成，其中必需氨基酸的化学评分为８０～８８之间，远高于海带和紫菜，其余成分与海带、紫菜接近，可作为保健食品和药物的优质原料     

The modeling of carbon isotope kinetics and its application to the evaluation of natural gas

The modeling of carbon isotope kinetics of natural gas is an issue driving pioneering research in the oil and gas geochemistry in China and internationally. Combined with the sedimentary burial history and basin geothermal history, the modeling of carbon isotope kinetics provides a new and effective means for the determination of the origin and accumulation history of natural gas pools. In this paper, we introduce themodeling of carbon isotope kinetics of natural gas formation and its applications to the assessment of natural gas maturity, the determination of the gas source, the history of gas accumulation, and the oil-gas ratio. It is shown that this approach is of great value for these applications. The carbon isotopic characteristics of natural gas are not only affected by the gas source and maturity of the source rock, but also are related to the accumulation condition and geothermal gradient in a basin. There are obvious differences in the characteristics of carbon isotope ratios between instantaneous gas and cumulative gas. Different basins have different kinetic models of carbon isotope fractionation, which depends on the gas source condition, the accumulation history and the sedimentary-tectonic history. Since the origin of natural gas in the superimposed basin in China is very complicated, and the natural gas pool is characterized by multiphase and variable gas-sources, this paper may provide a new perspective on the study and evaluation of natural gas.     

库车坳陷克深大气田白垩系致密砂岩储层古流体地球化学特征研究

采用包裹体岩相学、均一温度、盐度、含油包裹体丰度、储层颗粒荧光定量实验分析方法,对库车坳陷克深大气田白垩系巴什基奇克组储层致密砂岩样品进行测试,剖析克深大气田深层致密砂岩储层古流体地球化学特征与油气充注。结果表明,克深大气田发育两期油气包裹体,分别为发亮蓝色荧光的轻质油包裹体与灰黑色的气态烃包裹体。克深大气田包裹体均一温度分布存在130~140 ℃与150~160 ℃两个主峰值,相应的古盐度值为16%~10%与12%~4%,表明有两期烃类流体充注,其中天然气高强度充注发生在2.5 Ma以来。含油包裹体丰度分布在2.1%~13.4%之间,QGF指数为2.2~9.6,QGF-E强度为20~38 pc,揭示克深大气田形成过程中曾经存在强度较弱的轻质油充注。     

测定煤矿区土壤中元素含量的火焰原子吸收法

火焰原子吸收法虽已应用于各个行业领域,但该法存在样品称样量大、加酸后消解时间长、实验干扰较多等问题,其实际应用受到局限。针对这一情况,考虑到煤矿区土壤样品的特点,经过反复摸索,建立了用火焰原子吸收分光光度计测定硝酸-高氯酸消解后的土壤样品中Zn、Cu、Fe、Mg、Ca、K和Na 7种元素含量的新方法。该方法简单、快速,灵敏度和准确度较高,相对标准偏差在2.9%以下,加标回收率在97.3%~112.5%,并应用于淮南煤矿区土壤样品,取得了令人满意的效果。      

Lipid oxidation and fatty acid composition in salt-dried yellow croaker (<Emphasis Type="Italic">Pseudosciaena polyactis</Emphasis>) during processing

Lipid oxidation in salt-dried yellow croaker (Pseudosciaena polyactis) was evaluated during processing with commonly used analytical indices, such as the peroxide value (POV), the thiobarbituric acid reactive substances (TBARS) value, and oxidative-relative lipoxygenase (LOX) activity. Additionally, fatty acids were analyzed using gas chromatography-mass spectrometry. Both POV and TBARS increased significantly (P < 0.05) at the rinsing stage. POV reached its peak value of 3.63 meq O₂ per kg sample at the drying stage, whereas TBARS constantly increased from 0.05 to 0.20 mg MDA per kg sample. Processing of salt-dried yellow croaker had an extremely significant (P < 0.01) effect on LOX activity. Twenty-six fatty acids were identified. Combined eicosapentaenoic acid (EPA; C20:5n3) and docosahexaenoic acid (DHA; C22:6n3) content varied between (19.20 ± 0.37) mg g^?1 and (23.45 ± 1.05) mg g^?1. The polyunsaturated fatty acid/saturated fatty acid (PUFA/SFA) ratio in yellow croaker was 0.73–1.10, and the n-6/n-3 PUFA ratio was approximately 0.13–0.20. The contents of most fatty acids varied significantly (P < 0.05) during the different processing stages, and these differences were caused by lipid oxidation. C18:0, C16:1n7, C19:0, and C22:6n3 showed clear changes in principle component one of a principle components analysis. These fatty acids are potential markers for evaluating lipid oxidation in fish muscle because there was a significant correlation between these markers and TBARS and LOX activity (P < 0.05) with Pearson’s coefficients > 0.931.     

秦祁昆结合部晚三叠世OIB型玄武岩岩石学、地球化学及SHRIMP锆石U-Pb年代学研究

秦祁昆结合部夏河县八角城作海枕状玄武岩,不整合于中二叠统大关山组生物灰岩之上。枕状构造保存完好,气孔、杏仁构造发育,具斑状结构。斑晶主要为橄榄石,其次为斜长石和辉石;基质由板条状斜长石微晶、粒状辉石、橄榄石及钛铁矿等矿物组成。橄榄石斑晶发生伊丁石化、滑石化和绿泥石化,部分橄榄石完全被伊丁石化。TiO2质量分数为1.99%~2.24%,Mg#值为58~64,∑REE为（106~119）×10-6,LaN/YbN为5.6~7.1,富集Nb、Ta、Zr,以及Rb、Ba、Th、U、K等元素,高Nb/Y低Zr/Ti,并且呈现出与夏威夷、土耳其等地区OIB型碱性玄武岩相一致的稀土、微量元素配分模式曲线。橄榄石斑晶Fo值为82.73~84.57,w(CaO)均大于0.1%;斜长石斑晶An为64.72%~70.39%,基质中斜长石An为58.88%~61.53%,且斜长石斑晶较基质中斜长石呈现出低Si、Fe、Na、K、Ti和高Al、Ca特征。这些事实表明,形成该套岩石组合的原始岩浆曾经经历了橄榄石和斜长石等矿物的结晶分异作用。SHRIMP锆石U Pb测年结果表明,八角城作海玄武岩形成时代为晚三叠世Norian期（（220.5±4.2） Ma）。结合区域地质资料,在秦祁昆结合部古特提斯洋于晚三叠世俯冲消减结束并进入陆陆碰撞造山作用阶段,该时期陆陆碰撞作用引发的岩石圈拆沉作用导致岩石圈的减薄,进而形成八角城作海OIB型枕状玄武岩。     

青海南山“金水口岩群”的时代与构造属性研究

在青海南山出露一套变质程度达角闪岩相的变沉积岩组合,被认为可与东昆仑造山带中的金水口岩群相对应,其形成时代和构造属性仍存争议。本文对该套组合中的矽线石云母石英片岩和花岗伟晶岩侵入体进行了LA-ICP-MS锆石U-Pb测年和Lu-Hf同位素分析,结果表明矽线石云母石英片岩碎屑锆石U-Pb年龄峰值为779Ma,明显年轻于东昆仑造山带金水口岩群物源区最小年龄峰值(1.9(Ga);对应的ε_(Hf)(t)值主要为负值(-23.7~-11.8),T_(DM2)年龄为2436~3172Ma,来自于再循环的古元古代—太古代地壳物质,少量碎屑锆石年龄为1744~2819Ma。这些特征与南祁连构造带党河南山和化隆地区元古宙变沉积岩相一致,完全不同于东昆仑造山带中的金水口群。~779Ma碎屑锆石与中祁连和南祁连构造带中新元古代岩浆岩时代相近。花岗伟晶岩形成于439±2Ma,相对应的ε_(Hf)(t)和T_(DM2)分别为-14.2~-7.7Ma和1909~2316Ma,可能为形成于俯冲相关环境下古元古代地壳物质再循环形成的S型花岗岩;775Ma继承性锆石与矽线石云母石英片岩碎屑锆石年龄峰值一致,表明矽线石云母石英片岩为花岗伟晶岩的形成提供了部分物质来源。这些事实表明,青海南山所谓"金水口岩群"的形成时间应不早于779Ma,但不晚于439Ma,其沉积物源区应为~779Ma岩浆岩,在空间上与南祁连构造带党河南山地区以及拉脊山南侧化隆地区的同时期变沉积岩具有相似的沉积物源区和构造属性。