新疆金窝子片麻状花岗岩锆石U-Pb 年代学、 地球化学特征及其地质意义

[摘 要]金窝子金矿是新疆东部重要的金矿床之一,其赋矿围岩为上泥盆统金窝子组火山碎屑岩-沉积岩和金窝子片麻状花岗岩。前人研究显示金窝子片麻状花岗岩形成时代为356～392Ma,变化范围较大,且与金窝子组底部有片麻状花岗岩砾石的地质事实不符,在一定程度上制约着金矿床成矿作用和成矿地质背景的研究。金窝子片麻状花岗岩准确时代的确定,是研究该金矿成矿规律和构造岩浆演化的基础和关键。因此,本文采用高精度LA-ICP-MS 方法对金窝子片麻状花岗岩进行锆石U-Pb 定年和Hf 同位素研究。研究结果表明,片麻状花岗岩岩浆结晶时代为429.1±2.7Ma,形成于中志留世,结合野外观察认为岩体时代应早于金窝子组地层,两者为不整合关系。锆石的ε_HF(t)值和Hf 同位素两阶段模式年龄分别介于-3. 5～+1.2 和2545Ma～3072Ma 之间。地球化学资料显示,片麻状花岗岩轻稀土(LREE)和大离子亲石元素( Rb、Th 和K) 相对富集,Nb、Ta 和Ti 等高场强元素相对亏损,A/ CNK 在1.13～1.14之间,具有高K 钙碱性系列岩石的特征和岛弧钙碱性岩浆活动的特征,该岩体的形成与南天山洋早古生代晚期的闭合以及后来塔里木板块和哈萨克斯坦板块的碰撞密切相关。     

Compositional fractionation of polyaromatic hydrocarbons in the karst soils, South China

This study aims to explore the condensation and fractionation trends of persistent organic pollutants (POPs) in the karst soils. The tiankeng is a karst surface expression that can act as a focal point for introduction of contaminants to a karst aquifer, which may serve both as condenser for vapor phase POPs and as barrier/sink for particulate associated less volatile POPs. The fractionation of POPs in soils from the upper rim and floor of tiankeng is of interest in understanding the role of tiankeng in the long-distance transport of POPs. In the present study, polycyclic aromatic hydrocarbons (PAHs) in the surface soils from the upper rim and floor of Dashiwei tiankeng in Southern China were analyzed. The total PAH concentrations in soils were 23.40–190 ng g⁻¹, with phenanthrene being the most abundant. The distribution patterns of PAH compounds in the soil samples matched well with their properties. It indicated the heavy PAHs were susceptible to retention by the floor soils of tiankeng than light PAHs. A plot of Cfloor/Crim against PAH molecular weight gave a good positive relationship in the molecular weight range of 152–276. It is suggested that the floor soils can be focal points of more concentrated PAH and deserve attention. The concentrations of total PAHs in the floor soils (43.40–190 ng g⁻¹, mean 87.76 ng g⁻¹) were higher than those in the upper rim (23.40–88.94 ng g⁻¹, mean 57.74 ng g⁻¹). In addition, there was a shift in compound pattern with an increase in the proportion of light PAHs (2–3 rings), a decrease in heavy PAHs (5–6 rings) and a relatively stable content of 4-ring PAHs. A combination of particulate scavenging and cold condensation is proposed as the major mechanism for the compositional fractionation of PAHs in the soils from the upper rim and floor of tiankeng.     

冰川/积雪-大气相互作用研究进展

冰川和积雪是冰冻圈的重要组成部分,在全球或区域气候系统中起着极其重要的作用.开展冰川/积雪-大气相互作用研究,是研究冰冻圈物理过程及其对气候系统反馈作用的必然需求,也是研究冰川/积雪对气候变化响应的有效手段,同时还可为全球(区域)气候和水文模式提供冰川/积雪面的地表特征参数.近一个世纪以来,在冰川/积雪面辐射特征、能量通量计算方法和平衡特征等方面开展了许多观测试验和理论研究,并取得了卓有成效的研究结果.但是在准确获取辐射通量、研发普适性较强的反照率参数化方案、复杂地形条件下能量通量的计算,以及发展分布式能量平衡模式等方面尚存在许多不确定性,仍面临许多技术难点,也是未来的研究重点.     

基于MAPGIS的地质矿产勘查项目信息管理系统

以MapGIS为平台,二次开发实现了地质矿产勘查项目信息管理系统,并建立了重庆市矿产地和勘查项目库。该系统利用GIS技术合理规划矿产资源勘查,信息化管理矿产开发项目,为制定可持续发展的矿产资源开发利用方案提供辅助决策。     

三种仿寿山“坑头冻”印材的宝石矿物学特征

为研究缅甸翡翠中的哪些部位适合做烧红处理以及该部位能被烧红的原因,采用加热实验、偏光显微镜、红外光谱及差热分析方法对缅甸翡翠样品的原生部位、雾部位的加热前、后的特征进行了测试与分析。结果显示,翡翠中的蓝雾部位及黄雾部位适合做烧红处理,原生部位不适合烧红处理,蓝雾部位可以被烧成黄色及红色,黄雾部位可以被烧成红色。雾部位适合用来做烧红处理的原因在于,在低温的加热条件下,蓝雾部位中的大量的Fe2＋发生价态变化,实现由绿泥石向针铁矿的转变所导致,该过程由表及里逐步进行。原生部位的主要矿物硬玉需被加热更高的温度,在破坏其晶格的情况下,才可以呈现出红色,且该红色不具有褐色调。     

鄱阳湖流域抚河径流特征及变化趋势分析

抚河是鄱阳湖流域第二大河流,其径流变化研究对揭示鄱阳湖水文情势演变规律和鄱阳湖生态环境保护具有重要的科学意义。本文采用鄱阳湖流域抚河上、中、下游8个主要水文站的实测资料,分析了抚河径流年内分配特征及变化规律;应用Mann-Kendall非参数检验与回归分析等方法,研究了近几十年内抚河年、月径流变化规律及与降雨的关系。结果表明:(1)抚河径流年内分配不均,但不均匀性在流域内空间差异较小;(2)受水利工程调蓄影响,径流年内分配越来越均匀;(3)不同年代年径流特性存在差异,20世纪70年代至90年代初,径流相对稳定,90年代中期到2002年,呈较明显上升趋势,2002年后,表现为下降趋势;(4)月径流变化有增有减,基本规律为枯水期(11月~次年3月)月径流量基本呈上升趋势,洪水期(4~6月)月径流基本呈下降趋势;(5)抚河的年降水量在2002年附近发生突变减少,与年径流量突变时间基本吻合,说明气候变化降雨量减少对近10年鄱阳湖流域抚河入湖径流的减少影响显著。     

鄱阳湖组(第四系)的修订及特征

根据对鄱阳湖地区 Zk0 1钻孔柱状剖面的研究 ,对鄱阳湖组的定义进行修订、补充 ,认为鄱阳湖组为一套以青灰色淤泥质粘土、黄褐色粘土、粉质粉土为主夹少量粉砂或细砂的湖泊—河口三角洲相沉积。年代地层为第四系全新统 ,底界年龄约 6 2 10± 12 5 a B.P.,开阔湖泊沉积始于 32 4 0± 180 a B.P.,且由北向南时代渐新 ,具有明显的穿时性     

Geochemical, Sr–Nd and zircon U–Pb–Hf isotopic studies of Late Carboniferous magmatism in the West Junggar, Xinjiang: Implications for ridge subduction?

Voluminous granitic intrusions are distributed in the West Junggar, NW China, and they can be classified as the dioritic rocks, charnockite and alkali-feldspar granite groups. The dioritic rocks (SiO₂ = 50.4–63.8 wt.%) are calc-alkaline and Mg enriched (average MgO = 4.54 wt.%, Mg^# = 0.39–0.64), with high Sr/Y ratios (average = 21.2), weak negative Eu (average Eu/Eu = 0.80) and pronounced negative Nb–Ta anomalies. Their Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7035–0.7042, ε_Nd(t) = 4.5–7.9, ε_Hf(t) = 14.1–14.5) show a depleted mantle-like signature. These features are compatible with adakites derived from partial melting of subducted oceanic crust that interacted with mantle materials. The charnockites (SiO₂ = 60.0–65.3 wt.%) show transitional geochemical characteristics from calc-alkaline to alkaline, with weak negative Eu (average Eu/Eu = 0.75) but pronounced negative Nb–Ta anomalies. Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7037–0.7039, ε_Nd(t) = 5.2–8.0, ε_Hf(t) = 13.9–14.7) also indicate a depleted source, suggesting melts from a hot, juvenile lower crust. Alkali-feldspar granites (SiO₂ = 70.0–78.4 wt.%) are alkali and Fe-enriched, and have distinct negative Eu and Nb–Ta anomalies (average Eu/Eu = 0.26), low Sr/Y ratios (average = 2.11), and depleted Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7024–0.7045, ε_Nd(t) = 5.1–8.9, ε_Hf(t) = 13.7–14.2). These characteristics are also comparable with those of rocks derived from juvenile lower crust. Despite of the differences in petrology, geochemistry and possibly different origins, zircon ages indicate that these three groups of rocks were coevally emplaced at ~ 305 Ma.A ridge subduction model can account for the geochemical characteristics of these granitoids and coeval mafic rocks. As the “slab window” opened, upwelling asthenosphere provided enhanced heat flux and triggered voluminous magmatisms: partial melting of the subducting slab formed the dioritic rocks; partial melting of the hot juvenile lower crust produced charnockite and alkali-feldspar granite, and partial melting in the mantle wedge generated mafic rocks in the region. These results suggest that subduction was ongoing in the Late Carboniferous and, thus support that the accretion and collision in the Central Asian Orogenic Belt took place in North Xinjiang after 305 Ma, and possibly in the Permian.     

农牧交错带典型区农业与牧业用地互动关系研究

利用1989年和2000年的两期Landsat-TM数据和相关的统计资料以及气候数据，应用转移距阵和多元回归分析等研究方法，对地处典型农牧交错带地区的兴和县土地利用变化进行研究，结果表明：农田和草地是研究区域中最主要的土地利用类型，Landsat-TM卫星影像数据和统计数据比较一致地反映农田和草地面积的变化；农田和草地的相互转换率在各种用地相互转化中非常剧烈；农业与牧业用地的互动特征具有明显的区域差异；农业和牧业用地的互动特点是自然因素和社会经济因素同时影响的结果。     

城市土地利用对植被特征影响的研究

城市土地利用对植被的影响是城市生态学中研究的重要问题。简单综述了国内外在该领域中的研究现状。通过在北京市进行的研究，对城市植被的特点及其与土地利用的关系进行了分析，结论为：①藜科（Chenpodiac eae）和蓼科（Polygonac eae）植物种类数量相对增加，归化植物占的比例大是城市植物区系的特征；②与非城市区域相比，生活型谱中一二年生植物比例增高，属的区系地理成分构成中世界分布属所占比例也明显提高；③城市土地利用类型对生境和植物群落特征的影响明显；④生境多样化对维持城市植物物种多样性而言，比面积大小具有更为显著的作用。