硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

论江西双桥山群的底界问题

１∶５万庐山地区区域地质调查和专题研究,在星子县黄岭一带发现一套巨厚层状复成分的变质砾岩。根据该变质砾岩的砾石成分、变形组构及区域分布特点,以及上部（双桥山群）与下部（星子岩群）地层在变质与变形方面存在明显差别,认为变质砾岩应属于双桥山群的底部层位,是中元古界双桥山群与下伏下元古界星子岩群不整合关系的佐证。由于受后期构造叠加改造的影响,现今二者呈断层或隐蔽不整合接触关系。     

A New Approach for Studying Hubble Diagrams of Quasars

In this paper, a new approach for studying Hubble diagrams of quasars is introduced. The purpose is to reduce the well-known very large scatter in the diagram. We believe that the scatter is mainly caused by the wide spread of luminosity distribution of quasars. Based on a large number of quasars having been discovered, we introduce a new quantity, the collective apparent magnitude of certain amount of quasars in a corresponding redshift interval, and make a plot of the collective apparent magnitude versus redshift with the data published by Hewitt and Burbidge (1993). The quantity is contributed by individual apparent luminosities as well as the luminosity distribution of quasars. Scatter is expected to be largely reduced in the corresponding diagram, and this is indeed true as shown by the figures. By discussing several possible effects and from the figures, we find that the assumption that redshifts of quasars are distance indicators is confirmed, and the standard cosmological model is supported. This revised version was published online in July 2006 with corrections to the Cover Date.     

岩石水压致裂和诱发地震的实验研究

用7种岩石各制备了几类不同预裂纹的系列试件，并在不同围压下进行水压致裂强度实验。结合典型的水库诱发地震的实际资料和现今构造应力场的实验结果，以及应用岩石强度理论和岩石断裂力学的一些原理、方法，进行岩石孔隙水压诱发地震的探讨。初步结果为：(1)若岩体内构造应力很小，一定大小的孔隙水压力σp，可直接使岩体内的薄弱面致裂并发生小地震。(2)若构造应力较大，存在两类诱发地震的可能：①对岩体浅部一些走向与构造应力的主压应力σ1方向相近的薄弱面，σp可促使其发生张性破裂并诱发小地震。②当构造应力接近于断裂的抗剪强度时，因σp，降低了断裂面上的正应力σn，使原处于稳定状态的断裂失稳，发生滑移破裂并诱发出地震。σp导致断裂的破裂深度增大，使诱发地震的震级大于原潜在的地震震级。(3)各种岩体均存在着一个极限深度，此深度后不再有诱发地震。     

Reservoir characteristics and main controlling factors of oil sand in Houba area,northwestern Sichuan Basin,China

Houba oil sand in frontier Longmenshan Mountain is one of the most typically important unconventional resources. The basic reservoir characteristics of oil sand and the main factors affecting reservoir quality were examined in this article based on porosity, permeability, and mercury porosimetry measurements; thin section analyses; SEM observation; and X-ray diffraction analysis. This study shows that the oil-bearing sandstone reservoir is mainly medium?coarse-grained sublitharenite and litharenite. The main pore type is intergranular pores, including residual primary intergranular pores, dissolved intergranular pores, and dissolved intragranular pores; fractures are common in this study area. The quality of sandstone reservoir is of high porosity and high permeability with a high oil saturation of 89.84 %. It is indicated that the main controlling factors of the reservoir in the study area include deposition, diagenesis, and tectonism. Deposition laid a foundation to porosity evolution, and channel sand is the most favorable depositional facies for the reservoir. Diagenetic alterations are the keys to reservoir evolution; dissolution and chlorite coatings cementation play an effective role in the generation and preservation of pores. Compaction, carbonate cementation, and quartz overgrowth cause many damages to the reservoir porosity. Fractures caused by structural breakages can improve the reservoir permeability and they also can provide fluid migration pathways to the late corrosion, which formed a lot of corroded fissures as reservoir and percolation spaces.     

文安5.1级地震的一些异常特征

对文安5.1级地震的一些异常进行了分析和总结,认为地震逆时针方向迁移可能是地震空间活动的一个基本特征,其可作为背景异常。震前,地磁交汇法出现的异常,再次显示出该方法对地点预测的最大优势,交汇点附近即是未来震中区。这些异常特征对我们认识地震和预测地震都具有一定意义。     

池沼公鱼耳石日轮的观察研究

于1989年3－8月，从辽阳汤河水库捕取成熟的池沼公鱼，获得人工授精卵。用压片法光镜下连续观察胚胎发育后期和前仔鱼期耳石轮纹的形成，并采集已知月龄的幼、成鱼耳石，制片镜检轮纹数量和排列。结果表明，仔鱼在印黄接近吸收完并开始摄食外界食物时，即孵出后第6d至第7d形成第1个轮纹，之后每天一轮，这些轮纹就是日轮；日轮间距呈规律性变化，这些变化与鱼体生长发育及生态条件密切相关。     

北京西山地区岩溶发育史及岩溶环境变迁

根据地壳运动所遗留的地貌形态,本区可划分为古生代和新生代二个岩溶发育期。由于本区新构造运动的特点决定了岩溶发育既具有阶段性又具有继承性。据此,新生代岩溶发育期又可划分为三个亚期:早第三纪岩溶发育亚期、晚第三纪岩溶发育亚期、第四纪岩溶发育亚期。本文根据不同时期形成的岩溶形态组合特征、洞穴化学沉积物和碎屑沉积物及具有代表性的洞外沉积物的性状、所含化石、孢粉组合、粘土矿物和重矿物组合及其化学成分和扫描电镜分析、稳定同位素和古地磁测定以及大量的测年资料,综合研究了本区晚第三纪以来的岩溶形成环境及其历史变迁。      

Global characteristics of ambient seismic noise

Journal of Seismology - Ambient seismic noise becomes more and more important and helpful on assisting velocity model inversion, earthquake detection, and ground motion prediction. Based on the...