Petrogenesis and metallogenic potential of the Jurassic porphyries in the northwest Zhejiang Province,South China: insights from SHRIMP zircon geochronology,geochemistry, and Sr–Nd–Hf isotopes of the Huangbaikeng ore-bearing porphyries

The northwest Zhejiang Province is a key domain for providing deep insight into the crust–mantle interaction and tectonic evolution of the South China block. In this paper, we collect geochemical, geochronological, and isotopic data of the Jurassic porphyries in this region, and investigated the Huangbaikeng ore-bearing porphyry in the Tongcun Mo–Cu deposit, using it as an example to uncover the porphyry petrogenesis and evaluate their metallogenic potential. Two varieties of the Huangbaikeng porphyry were distinguished: the medium- to coarse-grained type and medium- to fine-grained type. Zircon Sensitive High-Resolution Ion Microprobe U–Pb dating indicates that they were emplaced at 161.8 ± 2.8 and 162.7 ± 3.5 Ma, respectively, which are consistent with the molybdenite Re–Os ages of 163.9–161.8 Ma. The inherited zircons age spectrum significantly recorded a series of geological events, for example, assembly and breakup of the Columbia and Rodinia supercontinent, and the Triassic collision of Yangtze and North China blocks. Whole rock Sr–Nd and Jurassic zircon Hf isotopic data yield mostly negative ε_Hf(t) values (0.5 to ?8.4) and ε_Nd(t) values (?0.79 to ?4.82). Besides the Huangbaikeng porphyry, all the Jurassic porphyries in the northwest Zhejiang Province have a wide range of SiO₂ contents (76.78–60.91 wt.%). They do not contain typical aluminous minerals (e.g. cordierite and garnet), and are mainly metaluminous to weakly peraluminous with high Na₂O, low FeO^T/MgO, and Zr + Nb + Ce + Y concentrations in composition. They thus fit the I-type granite definition. Some major and trace elements show strong correlations with SiO₂, possibly indicating extensive fractional crystallization during their magma evolution. Tectonic discriminations imply that these plutons were likely formed in a volcanic arc regime possibly related to subduction of the Palaeo-Pacific plate. Sr–Nd–Hf isotopic data suggest a mixed source of the Mesoproterozoic crust and 30–50% mantle components. Compared with the adjacent Dexing Cu-bearing porphyies, which have more positive ε_Hf(t) and ε_Nd(t) values with more significant mantle components (55–70%), the Jurassic porphyries in the northwest Zhejiang Province probably lack metallogenic potential to form a giant porphyry copper deposit as Dexing.     

Temporal and spatial characteristics of dissolved organic carbon in the Wujiang River,Southwest China

River systems play an important role in the global carbon cycle. Rivers transport carbon to the ocean and also affect the carbon cycle in the coastal ocean. The flux from land to the ocean is thought to be a very important part of the land carbon budget. To investigate the effect of dam-building on dissolved organic carbon (DOC) in rivers, three reservoirs of different trophic states in the Wujiang basin, Guizhou Province, were sampled twice per month between May 2011 and May 2012. Temporal and spatial distributions of DOC in the reservoirs and their released waters were studied. It was found that different factors controlled DOC in river water, reservoir water, and released water. DOC in the rivers tended to be affected by primary production. For reservoirs, the main controlling factors of DOC concentration varied by trophic state. For the mesotrophic Hongjiadu Reservoir, the effect of primary production on DOC concentration was obvious. For the eutrophic Dongfengdu Reservoir and the hypereutrophic Wujiangdu Reservoir, primary production was not significant and DOC came instead from soil and plant litter.     

个旧锡矿东区黄铁矿成分标型特征研究

黄铁矿是个旧锡矿最常见的硫化物之一,但对其相关研究比较匮乏。本文通过对个旧锡矿东区不同类型矿体中黄铁矿的主微量元素特征研究获取黄铁矿成分的标型特征。个旧锡矿东区其矿体分为层间氧化残余硫化矿、接触带矽卡岩矿体、脉状矿、变基性火山岩矿体四类,不同类型黄铁矿产出特征各异,如层间氧化矿残余硫化矿中黄铁矿具有典型的残余结构,矽卡岩矿体中黄铁矿具有压碎结构、骸晶结构等。研究数据表明,黄铁矿总体表现亏铁、富硫,富集Pb、Zn、Cu、Cd、In、As、Sb、Bi、Sn、Ag、Au、W等元素,贫Co、Ni、Cr、Te、Se元素,Co/Ni较大。层间氧化矿残余硫化矿与变基性火山岩两类产于层间的矿体成矿环境硫逸度较高,矽卡岩矿体中黄铁矿高温元素含量较高,脉状矿中黄铁矿微量元素总量较高。硫逸度越大,温度越低,越有利于As进入黄铁矿晶格。成矿元素物源丰富,As、Ag、Au很可能来源于地层,Pb则来源于岩浆,Bi可能大部分来源于酸性岩浆。温度和共生矿物是影响黄铁矿中微量元素富集的重要因素,共生黄铁矿-黄铜矿可以指示形成时的温压条件。本区黄铁矿属中低温成矿,从高到低依次为矽卡岩矿—层间氧化矿残余硫化矿—变基性火山岩矿—脉状矿。来自岩浆的成矿物源较丰富,以及产于岩体边缘蚀变岩型矿体的发现,可推测岩体内部矿产资源丰富。     

从典型矿(床)点分析全椒大庙山式金矿 控矿条件及找矿方向

从典型矿床点分析大庙山含金角砾岩工业矿体的控矿条件及找矿方向。     

城市暴雨内涝模拟模型优化与精度验证

本文采用“Vegetation-Impervious Surface-Soil”模型和线性光谱混合分解方法,获取像元中不透水面、植被、土壤覆盖信息,用于计算SCS模型产流参数综合CN（Curve Number）值;基于土地利用类型,采用经验值与数值实验逐步求精相结合的方法,确定水动力汇流模型参数曼宁系数,并用实测积水数据验证两次参数修正的模拟效果。以上海中心城区为例进行验证,研究结果表明：①将采用V-I-S模型得到的不透水面、植被、土壤信息设定CN值,能够降低积水分布的极值化现象,提高SCS产流模型产流量和产流分布精度;②采用经验法和数值模拟逐步求精法,按土地利用类型设定曼宁系数,使各时段最大积水深度高于原模型,说明曼宁系数是汇流模型的敏感参数。     

Potential water sources for Late Quaternary Megalake Jilantai-Hetao,China, inferred from mollusk shell <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr ratios

Lake Jilantai-Hetao, a megalake, was formed some time before 60–50 ka, along the Great North Bend of the Yellow River. The basin is now dry, with most of the area covered by aeolian sand. We are investigating this profound hydrologic change using a number of research approaches. Paleoshorelines of this megalake are best preserved in the Jilantai area in the southwestern portion of the megalake basin. We collected aquatic mollusk shells from littoral sediments at different altitudes around Jilantai and measured their strontium isotope compositions. ⁸⁷Sr/⁸⁶Sr ratios in shell carbonates are different between the high lake phase (~1,080–1,050 m altitude) and the low lake phase (~1,044–1,030 m altitude), with a small shift in average strontium ratios to more radiogenic values during the low lake phase. Based on regional hydrology and physical geography, we conclude that water from the Yellow River was the dominant water source supplying this megalake. ⁸⁷Sr/⁸⁶Sr ratios of modern water samples suggest the Yellow River was the dominant water source during the high lake phase, but that the relative contribution of Yellow River water to the megalake was reduced, and that the relative contributions of local precipitation and groundwater increased, during the low lake phase.     

山坡蓄量动力学理论及其在水文模拟中的应用前景

山坡地貌特征,即山坡地形曲率的敛散、凹凸等性质,是影响土壤含水量、产流面积空间分布的重要地形控制因子.山坡蓄量动力学理论(Hillslope-storage dynamics)是一种融合地貌特征的山坡水文模拟方法.其引入宽度函数和土壤厚度函数的概念,建立基于土壤蓄水能力的一维山坡蓄量动力学方程,这是采用低维方法描述山坡复杂三维结构的水文响应的一种简化方法,大大降低了模型的复杂程度.该理论解决流域水文模拟的尺度和参数化问题的潜力已经得到重视,但仍需开展尺度效应研究,通过野外观测事实和大量理论分析成果为此项研究提供支撑.     

地震废墟中人体心脏电场信号的提取

基于人体心脏电场信号的生命探测仪是目前最先进的生命探测仪,其困难之处在于从地震废墟中提取微弱的心脏电场信号。本文主要分析地震废墟中可能出现的对人体电场有干扰的信号情况,提出如何接收废墟中微弱的超低频心脏电场信号,并根据人体心脏电场的特征设计特殊滤波器滤除干扰信号,只保留因人体心脏跳动而产生的360度扩展的超低频非均匀电场。     

采用体波谱振幅相关系数方法研究地震集中区震源机制变化过程

同一震源区两次地震到达某台站的直达P波、S波零频观测谱值之比与其辐射图型因子之比线性相关,而后者取决于震源机制的几何特性。用波形记录计算谱振幅相关系数,认为该系数是震源机制异同的归一化数值描述。据此对2003年青岛序列及冀鲁豫交界地区小震集中区地震事件进行聚类分组,给出序列事件的滑动平均相关系数的时序曲线。研究结果表明:青岛序列的滑动平均相关系数时序曲线存在由一致到发散的变化过程,即震源区应力场强度由相对集中向逐步分散过度;冀鲁豫交界地区小震集中区谱振幅相关系数较低,震源机制各不相同,区域应力积累没有形成任何一个优势方向。     

南黄海中古生代残留沉积地层的地震成像

文中展示了南黄海中古生代沉积地层的成像结果,显示南黄海隆起区存在较稳定的中古生代沉积地层残留区.南黄海中古生代残留沉积地层的成像问题一直是地震资料处理的难点,主要原因是以海底鸣震为主的层间多次波和与中古生界顶界面相关的长程多次波非常发育,致使有效反射波无法准确识别.本文利用平面波域层间多次波的可预测性,对地震数据平面波分解之后进行预测反褶积,较好地消除了层间多次波.利用速度差异分离长程多次波,在有效波速度无法确定的条件下,先从低速的、可以确认的多次波开始进行分离,逐步确认并分离多次波,同时逐步进行有效波的确认和成像速度的尝试,最终得到合适的成像速度场和多次波被充分分离的数据.成像结果对南黄海残留盆地研究有一定借鉴意义.