大庆长垣外围特低渗透扶杨油层CO_2非混相驱油试验研究

大庆长垣外围有3×108t特低渗透的扶杨油层储量在注水开发条件下难以有效动用,为提高这部分储量的有效动用率,开展了CO2非混相驱油试验研究。PVT测试结果表明,扶杨油层原油较稠,体积系数小,膨胀性和收缩性小,溶解系数较低;CO2驱油细管实验最小混相压力为29 MPa,比原始地层压力高8.6 MPa,现场试验为非混相驱;长岩心实验CO2驱油采收率比注水高4~6个百分点。综合室内可行性评价实验结果看,大庆长垣外围扶杨油层开展CO2驱油试验是可行的,并于2003年初在宋芳屯油田南部开辟了注气试验区,有注气井1口,采出井5口。矿场试验结果表明,CO2驱油能够使特低渗透、裂缝不发育的扶杨油层建立起有效驱动体系,从根本上改善其开发效果,该技术有望成为特低渗透扶杨油层有效动用的可行技术。     

地电化学法寻找隐伏金矿的应用研究

通过对金的地电化学成晕机制的研究,利用地电化学法在东北大兴安岭森林覆盖区虎拉林金矿和澳大利亚第四纪厚层覆盖区Challenger金矿进行可行性找矿试验研究。试验结果在上述已知矿区的剖面上均测出了清晰的地电化学异常,表明利用地电化学法在上述地区寻找的隐伏金矿是有效的。在此基础上对两矿区外围及深部进行了找矿预测,发现4个有利的成矿靶区,经工程验证发现2个金矿体,取得了良好的经济和社会经济效益。     

小波技术在GPS基线解算数据预处理中的应用

采用小波技术对GPS观测数据进行处理。应用小波变换技术对GPS相位观测值进行周跳的探测和修复。GPS相位观测值可以作为时间序列来进行分析,作为时间函数,它所表现出来的是一条光滑度很好的曲线,一旦出现周跳,这种光滑性就被破坏,从发生周跳的历元开始,后继相位观测值序列发生等量阶跃,通过小波变换的信号特性检测原理,能够有效地探测出周跳的发生,这种方法对于缩小模糊度搜索空间及提高模糊度解的有效性有明显的作用,从而提高基线解算的精度。     

准噶尔盆地中拐地区下侏罗统层序地层特征与聚煤控制因素分析

在分析前人对准噶尔盆地层序地层学研究成果的基础上,综合应用岩心、测井和地震资料,对准噶尔盆地西北缘中拐地区下侏罗统进行层序地层划分,总结了层序和体系域界面的识别标志,将下侏罗统划分为4个三级层序和7个体系域,同时叙述了各三级层序的结构特征。通过对层序内含煤岩系的发育特点分析,发现其主力煤层主要发育在JSQI和JSQ3湖侵体系域中,本文作者认为研究区内湖侵时期为有利的聚煤时期,聚煤作用主要受构造沉降、物源供给、气候和沉积环境等因素的控制。     

黑龙江省东部桦南隆起美作花岗岩的锆石U-Pb定年及其地质意义

为查明马家街群发生接触变质作用的时代及其构造背景,对出露于黑龙江省东部桦南隆起的美作花岗岩体进行了锆石LA-ICP-MS U-Pb定年研究.结果显示:锆石具有清晰的生长振荡环带,其Th/U比值为0.12～1.04,属于典型的岩浆成因锆石;获得的206Pb/238U加权平均年龄为(259.0±3.6) Ma(n=14,MSWD=5.9),代表了岩体结晶年龄.美作岩体与佳木斯地块南部的青山、楚山和柴河岩体形成时代一致,其轻稀土富集、重稀土亏损型式和Eu负异常以及明显的Nb、Ta、Sr、Ti亏损的特点显示为壳源成因的火山弧花岗岩;它们的形成可能与晚古生代古亚洲洋的消减作用有关,该期花岗岩的就位导致马家街群发生了接触变质作用.美作花岗岩体形成时代的厘定,不仅限定了马家街群的变质时代为晚二叠世,同时为进一步探讨佳木斯地块晚古生代构造演化提供了新证据.     

大连滨海湿地景观格局变化及其驱动机制

以2000年和2006年TM卫星影像为主要数据源,配合其它非遥感数据,在遥感与地理信息系统技术支持下,运用景观生态学原理,选取反映景观空间结构和景观异质性的指数,对大连地区湿地的整体景观格局和类型景观格局及其动态变化进行定量分析.结果表明:6年间,大连湿地面积减少了97.62 km2;整体景观多样性指数和均匀度指数降低,优势度指数增加;各类景观格局时间序列上也存在明显差异性变化.湿地景观格局指数的变化, 反映了移山填海工业园区的扩大及养殖业的大力发展等人为活动对景观格局的深刻影响.人为活动已成为大连市湿地景观格局变化的主要驱动因子.     

地壳运动速度场插值方法研究

分析了构建速度场的统计模型和函数模型法,提出利用两种模型逼近原始观测速度的综合逼近法,以减少剩余误差.计算和比较了各种方法,结果显示,综合法优于单独利用统计模型和函数模型法.     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

Intrinsic sample methods for mineral exploration and resource assessment

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.     

流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。