利用催化动力学原理测定化探样中微量碘的含量

在HAc-NaAc形成的中性缓冲溶液体系中,利用碘的催化动力学原理,使N-N-四甲基-4-4-二氨基二苯甲烷与氯胺T的氧化反应,生成蓝色络合物来测定地探样中微量碘的含量。通过实验,最佳试剂加入量为8%的HAc溶液5mL,8%的Na2CO3溶液3mL,0.1%的N-N-四甲基-4-4-二氨基二苯甲烷溶液5mL所组成的溶液体系中,在加入0.1%的氯胺T1mL显色后,其测定结果准确度、精密度高,检出限低,测定化探样中微量碘时该方法可以推广应用。     

浙江花岗岩类地球化学与地壳演化——Ⅱ.元古宙花岗岩类

浙江元古宙花岗岩类包括神功期（1．8－1．9Ga）和晋宁晚期（0．6—0．9Ga）。研究了浙江元古宙花岗岩类的主元素、微量元素、稀土元素和Rb、Sr同位素组成特征及岩石成因，探讨了浙江地壳的演化。浙江地壳形成于太古亩和元古宙，地壳增生的时期为2．6－2．7、0．8-1．1和0.1－0.12Ga。随时间演化浙江地壳组成有变化，但分异演化不明显。沿江-绍断裂分布的晋宁晚期慢源和壳幔混合中酸性岩是普宁期俯冲碰撞的证据。加里乐和印支期是两次规模不大的构造运动。     

Variational Bayesian independent component analysis for spectral unmixing in remote sensing image

Spectral unmixing is a key technology of optical remote sensing image analysis; it not only influences the accuracy of the extraction of land cover information and automatic classification of topographical objects, but also greatly hinders the development of quantitative remote sensing. Independent component analysis (ICA) is a statistical method which is recently developed to extract the independent linear components, and which can realize the extraction of endmembers as well as fractional abundances with little a priori knowledge. However, ICA still cannot process the correlations among the various components. To overcome this problem, variational Bayesian independent component analysis (VBICA) has been proposed to process optical remote sensing images. In the Bayesian framework, the separation of independent components of remote sensing image has finally been achieved with conditional independence standards of Bayesian network and approximate variational algorithm. In the simulative image and real AVIRIS hyperspectral remote sensing image, the VBICA algorithm demonstrates its better performance. The experiment’s results indicate that the proposed VBICA algorithm is feasible, which has obvious advantages and a good application prospect. The reason is that it can effectively overcome the correlations between the various components in remote sensing images and break through the limitations of traditional remote sensing images analysis. Last but not least, the VBICA algorithm is applied in the classification of the TM multispectral remote sensing images. Compared to basic maximum likelihood classification, principal component analysis and FastICA algorithms, VBICA improves the classification accuracy of remote sensing images, and contributes to the further extension of the application of ICA in remote sensing image analysis.     

核电事故分析及思考

目前,世界核电已经历了半个多世纪的发展历程,已经有了非常丰富的核电发展经验,事实证明了核能是一种安全、清洁、高效的能源。但从核电发展初到现在,也出现了不少核电事故。为了让核电工作者更清楚地了解历史核电事故概况,了解核电事故产生的影响以及正确看待核电事故、核电发展,通过调研,收集大量资料,详细统计了历史上发生的主要核电事故,对其事故原因及对核电发展影响进行简略分析。研究指出历史核电事故主要原因是因人失误,但早期事故和核电设计也有关;另外,核电事故给世界带来了巨大的负面影响,但同时也是推动核电安全发展的重要推手,每次核电事故发生后都是核电安全提升一个新台阶的开始,最终促使核电趋向越来越安全。     

Numerical Simulation of 3D Borehole‐to‐Surface Electrical Method

The anomaly response characteristics of the vertical line‐source 3D borehole‐to‐surface model are simulated by an adaptive finite element method. The calculation shows that the anomaly in the radial direction is pressed and the closer to the source, the more pronounced, the anomaly is stretched in the direction perpendicular to the radius. Adding a B pole in the Y direction can offset the effect of stretching to some extent. The anomaly that is closer to the source of the profile is clearer than the anomaly that is far from the source. The research results are of great significance for guiding the practical application of the borehole‐to‐surface electrical method.     

汶川8.0级地震前BSQ型数字垂直摆倾斜仪观测到的地形变异常现象

地倾斜连续观测是地壳形变观测研究中重要内容。汶川8.0级地震前,布设在四川德阳金河测点的新型BSQ型数字垂直摆倾斜仪观测到了明显的地形变异常现象。分析其观测结果可知,汶川8.0级地震前约半月时间内德阳金河测点的地倾斜运动速度较过去的平均运动水平提高了数十倍,且震前地表快速倾斜的方向在N25°W左右。除此之外,德阳金河BSQ型数字垂直摆倾斜仪测点还观测到较为完整的,对应于可以反映地表应力集中、释放过程的震前地表破裂过程。上述现象为今后研究强震孕育机理提供了重要的信息。介绍与分析了布设在龙门山断裂带附近的其它类型地倾斜仪在震前的观测结果。事实证明,BSQ型数字垂直摆倾斜仪在强震前的浅表过程监测中具有重要意义,值得在今后的地震前兆台网工作中进行推广。     

自调节趋势分析法

自调节趋势分析法的特点是:能自动消除局部成分对计算拟合区域成分的多项式的系数的影响,并能确定多项式的阶次,因而在地学数据处理及预测中有广泛的应用。     

Geology and Lead–Sulphur Isotope Compositions of the Tongyu Volcanic-Hosted Massive Sulphide Copper Deposit in the Western Part of the North Qinling Orogen, China

The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide(VHMS) deposits with industrial value and is also a typical example of mineralization related to the subduction and metallogenesis during the Caledonian orogeny. We conducted systematic lead-sulphur isotope geochemical analyses of the Tongyu deposit to understand the possible ore-forming material sources and tectonic settings. Twenty-six sulphide samples yielded clustered δ~(34)S_(CDT) values of 1.13‰-3.36‰, average 2.22‰, and show a tower-type distribution,implying that the sulphur of the Tongyu copper deposit mainly originated from a mantle source. The Pb isotope compositions of sulphides(~(206)Pb/~(204)Pb = 17.59225-18.56354, average 18.32020; ~(207)Pb/~(204)Pb =15.51770-15.69381, average 15.66217; ~(208)Pb/~(204)Pb= 37.99969-39.06953, average 38.52722) are close to the values of the volcanic host rocks(~(206)Pb/~(204)Pb= 18.10678-18.26293, average 18.21158; ~(207)Pb/~(204)Pb =15.63196-15.68188, average 15.65345; ~(208)Pb/~(204)Pb= 38.43676-38.56360, average 38.49171), thus consistent with the Pb in ores and volcanic host rocks having been derived from a common source that was island-arc Pb related to oceanic crust subduction. The northward subduction of the Palaeo-Qinling oceanic crust triggered dehydration of the slab, which generated a large amount of high-oxygen-fugacity aqueous hydrothermal fluid. The fluid rose into the mantle wedge, activated and extracted metallogenic material and promoted partial melting of the mantle wedge. The magma and ore-forming fluid welled up and precipitated, finally forming the Tongyu VHMS copper deposit.     

黄铁矿热电性研究在庞家河金矿评价中的应用

庞家河金矿载金矿物黄铁矿的热电性测量结果为：热电系数（α）均为正值，平均223．075μv／℃，属空穴型（P型）导电。根据热电系数数值求得的热电性参数数位集中在（50～70）之间，反映庞家河金矿矿体剥蚀程度不大，属中上部出露；相对矿化总长度的剥蚀百分比为30％～35％，并根据热电性参数求得矿体的总延伸深度L＝1204m，矿体的尖灭深度L0＝805m。该计算结果与后来进行的矿床勘探结果基本吻合。