Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer

The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions.     

对羟基苯甲酸异丙酯合成的研究

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。     

空间信息网格中动态复制策略的研究

空间信息网格项目数据量大，用户遍及各地，对数据文件的请求延时大、占大量带宽。复制可以节省带宽、减少时延、均衡负载、改善系统可靠性。采用动态复制技术可以使用户有效地获得所需的数据。详细地论述了动态复制策略以及空间信息网格中的复制管理机制、复制服务流程和具体实施。     

蓟县铁岭组底部硅质褐铁矿屑砂岩的地质意义

华北蓟县系上部洪水庄组和铁岭组之间长期以来一直被认为是整合接触。近期在蓟县小岭子剖面发现洪水庄组顶部发育铁质风化壳，铁岭组底部有硅质褐铁矿屑砂岩，从而证明洪水庄组与铁岭组之间存在一次强烈的风化剥蚀，二者之间是假整合接触关系。     

湖南宝山矿床花岗岩类硫-铅同位素和流体包裹体研究及其成因意义

宝山铜铅锌多金属矿床是湖南重要的铅锌生产基地。矿床内矽卡岩型铜(钼)矿化受侏罗纪花岗闪长斑岩的控制,而主要的铅锌矿体则产于远离岩体的碳酸盐地层中,且缺乏可靠的矿化年龄限制。为了查明宝山铅锌矿体与花岗闪长斑岩之间的成因关系,文章对宝山花岗岩类中浸染状黄铁矿的硫同位素和钾长石的铅同位素,以及铅锌矿石萤石脉石的流体包裹体进行了测试和研究,并与前人报道的铅锌硫化物矿石的硫、铅同位素进行了对比,尝试为宝山铅锌矿化的物质来源及成因提供依据。研究表明,花岗闪长斑岩中浸染状黄铁矿的δ34S值为+1.5‰~+3.5‰,与铅锌矿石硫化物(方铅矿、闪锌矿及黄铁矿)相一致;同时,花岗岩类中钾长石的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.4789~18.7668、15.6835~15.7220和38.7903~39.1035,具有壳源的特征,且与铅锌矿石硫化物的铅同位素分布范围相吻合。宝山矿床的硫、铅同位素特征表明,花岗闪长斑岩应是铅锌矿化的主要硫源及金属来源。宝山矿床铅锌矿石萤石中的流体包裹体具有低温(130~150℃)、低盐度(8%)的特征,可能是岩浆热液演化到晚期的产物。结合已有的有关资料加以对比和分析,研究认为,宝山铅锌矿床的成矿物质应来源于花岗闪长岩的岩浆期后热液,在热液演化晚期迁移到远端地层中沉淀,形成了宝山的主要铅锌矿体。     

遥感数据在线信息分析服务技术研究

遥感数据的在线信息分析服务技术是基于在线处理技术,整合各种遥感信息和技术资源,通过标准Web Service调用方式以按需共享的方式提供遥感应用服务。本文就高分遥感数据产品的在线信息分析技术框架及信息分析结果的在线可视化系统实现展开研究,通过整合遥感数据处理算法及处理工具资源进行系统集成,并利用标准Web Service调用的方式为用户统一提供在线数据分析服务,使用户无须安装复杂处理软件就能在线对数据进行处理分析。试验结果表明,在线信息分析服务系统能稳定高效地为3—5级高分影像数据产品提供在线的数据分析功能,能有效降低行业应用高分遥感影像的难度,进一步增强了对高分遥感影像数据的应用能力。     

语义感知的地理视频大数据自适应关联组织方法

正地理视频是智慧城市和城市安全领域的重要战略资源。复杂城市环境中公共安全事件大范围流动、多阶段演化及多因素并发等新特征,使现有基于摄像机位置分布存储与分区管理的地理视频组织产生涉案数据检索中迅速扩大的虚警输出规模与急剧降低的涉案信息价值密度。发展支持涉案数据快速整合和案件知识高效理解的数据组织新机制成为发挥地理视频安防价值的重要科学内容。     

全球气候数据集生成及气候变化应用研究

科技部在"十三五"期间部署的国家重点研发计划"全球变化及应对"专项资助了"全球气候数据集生成及气候变化关键过程和要素监测"研究项目。项目围绕由全球气候观测系统提出的基本气候变量,完善地空天基观测体系,生成中国首套以遥感数据为主体的涵盖大气、海洋和陆表长时间序列、高精度、高时空一致性的产品,即气候数据集,动态监测全球变化关键过程和要素。     

一种改进的基于 BDS 三频非差观测的周跳实时探测与修复模型

BDS三频观测条件下可以组合得到具有优良特性的虚拟载波观测量,有利于改善非差观测数据的周跳实时探测与修复。文中提出一种基于BDS三频非差数据的周跳实时探测与修复模型:首先,采用消电离层无几何HMW组合观测量探测和修复EWL周跳;然后,将经过修复的EWL观测量与WL组合消除几何相关项,忽略电离层延迟残差进而确定WL周跳;最后采用经过修复的WL观测量与NL组合形成无几何观测量,并通过优化载波相位组合确定电离层延迟的变化量以探测和计算NL周跳,并通过简单变换得到原始载波观测量的周跳值。通过实测BDS三频数据对模型可行性进行验证分析,结果表明,即使在30s的采样率以及电离层活动活跃条件下,该模型都可有效实时探测和修复各类周跳。     

基于三维激光扫描的雕像建模与贴图

在完成雕像三维建模的基础上,提出了一种结合CG动画软件ZBrush完成模型后期贴图的制作,实现了CG动画和传统三维建模的结合,最终得到了较好的效果。解决了Geomagic和3ds Max主流贴图软件对于不规则模型可能出现的贴图接缝问题,并指出了相关的注意事项,为三维激光扫描技术在三维建模及古物重建等方面的应用提供了案例参考。